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Di-tert-Butyl ether

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-398.45 ± 0.72kJ/molCcrSteele, Chirico, et al., 1996ALS
Deltafliquid-399.6 ± 1.2kJ/molCcbFenwick, Harrop, et al., 1975ALS
Deltafliquid-402.kJ/molCcbSmutny and Bondi, 1961Heat of combustion corrected for pressure; ALS
Quantity Value Units Method Reference Comment
Deltacliquid-5322.10 ± 0.61kJ/molCcrSteele, Chirico, et al., 1996Corresponding «DELTA»fliquid = -398.45 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacliquid-5320.95kJ/molCcbFenwick, Harrop, et al., 1975Corresponding «DELTA»fliquid = -399.60 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacliquid-5318.3 ± 1.0kJ/molCcbSmutny and Bondi, 1961Heat of combustion corrected for pressure; Corresponding «DELTA»fliquid = -402. kJ/mol (simple calculation by NIST; no Washburn corrections); ALS

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
276.1298.15Fenwick, Harrop, et al., 1975, 2DH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Steele, Chirico, et al., 1996
Steele, W.V.; Chirico, R.D.; Knipmeyer, S.E.; Nguyen, A.; Smith, N.K., Thermodynamic properties and ideal-gas enthalpies of formation for butyl vinyl ether, 1,2-dimethoxyethane, methyl glycolate, bicyclo[2.2.1]hept-2-ene, 5-vinylbicyclo[2.2.1]hept-2-ene, trans-azobenzene, butyl acrylate, di-tert-butyl ether, and hexane-1,6-diol, J. Chem. Eng. Data, 1996, 41, 1285-1302. [all data]

Fenwick, Harrop, et al., 1975
Fenwick, J.O.; Harrop, D.; Head, A.J., Thermodynamic properties of organic oxygen compounds. 41. Enthalpies of formation of eight ethers, J. Chem. Thermodyn., 1975, 7, 943-954. [all data]

Smutny and Bondi, 1961
Smutny, E.J.; Bondi, A., Di-t-butyl ether: Strain energy and physical properties, J. Phys. Chem., 1961, 65, 546-550. [all data]

Fenwick, Harrop, et al., 1975, 2
Fenwick, J.O.; Harrop, D.; Head, A.J., Thermodynamic properties of organic oxygen compounds. 41. Enthalpies of formation of eight ethers, J. Chem. Thermodynam., 1975, 7, 944-954. [all data]


Notes

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