Quinoline, 8-methyl-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.

Quantity Value Units Method Reference Comment
Tboil520.7KN/AWeast and Grasselli, 1989BS
Tboil521.05KN/AZegalska, 1968Uncertainty assigned by TRC = 0.15 K; TRC
Tboil521.15KN/ACooper, Crowne, et al., 1967Uncertainty assigned by TRC = 0.7 K; TRC
Tboil519.KN/ACumper, Redford, et al., 1962Uncertainty assigned by TRC = 2. K; TRC
Tboil521.1KN/ARampolla and Smyth, 1958Uncertainty assigned by TRC = 0.3 K; TRC
Quantity Value Units Method Reference Comment
Tfus246.5KN/AZegalska, 1968Uncertainty assigned by TRC = 0.2 K; TRC
Quantity Value Units Method Reference Comment
Δvap62.1 ± 0.1kJ/molIP,EBChirico and Steele, 2005Based on data from 324. - 553. K.; AC
Δvap65.7 ± 1.9kJ/molCRibeiro da Silva, Matos, et al., 1995ALS
Δvap65.7kJ/molN/ARibeiro da Silva, Matos, et al., 1995DRB
Δvap65.7 ± 1.9kJ/molCRibeiro da Silva, 1995AC

Reduced pressure boiling point

Tboil (K) Pressure (bar) Reference Comment
416.20.045Weast and Grasselli, 1989BS

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
59.2 ± 0.1340.IP,EBChirico and Steele, 2005Based on data from 324. - 553. K.; AC
56.6 ± 0.1380.IP,EBChirico and Steele, 2005Based on data from 324. - 553. K.; AC
54.0 ± 0.1420.IP,EBChirico and Steele, 2005Based on data from 324. - 553. K.; AC
51.3 ± 0.1460.IP,EBChirico and Steele, 2005Based on data from 324. - 553. K.; AC
49.0 ± 0.2500.IP,EBChirico and Steele, 2005Based on data from 324. - 553. K.; AC
46.2 ± 0.3540.IP,EBChirico and Steele, 2005Based on data from 324. - 553. K.; AC
52.2508.A,EBStephenson and Malanowski, 1987Based on data from 493. - 523. K. See also Malanowski, 1961.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
500.48 - 521.304.385771921.712-82.303Malanowski, 1961, 2Coefficents calculated by NIST from author's data.

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Method Reference Comment
10.73246.9AC,DSCChirico and Steele, 2005AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Zegalska, 1968
Zegalska, B., Liquid-Solid Equilibria in Binary Systems Formed by Quinoline, Bull. Acad. Pol. Sci., Ser. Sci. Chim., 1968, 16, 335-41. [all data]

Cooper, Crowne, et al., 1967
Cooper, A.R.; Crowne, C.W.P.; Farrell, P.G., Gas-Liquid Chromatographic Studies of Electron-Donor-Acceptor Systems, Trans. Faraday Soc., 1967, 63, 447. [all data]

Cumper, Redford, et al., 1962
Cumper, C.W.N.; Redford, D.G.; Vogel, A.I., Physical properties and chemical constitution. The eletric dipole moments of methylquinolines, J. Chem. Soc., 1962, 1962, 1176. [all data]

Rampolla and Smyth, 1958
Rampolla, R.W.; Smyth, C.P., J. Am. Chem. Soc., 1958, 80, 1057. [all data]

Chirico and Steele, 2005
Chirico, R.D.; Steele, W.V., Thermodynamic Properties of 2-Methylquinoline and 8-Methylquinoline, J. Chem. Eng. Data, 2005, 50, 2, 697-708, https://doi.org/10.1021/je049595u . [all data]

Ribeiro da Silva, Matos, et al., 1995
Ribeiro da Silva, M.A.V.; Matos, M.A.R.; Amaral, L.M.P.F., Thermochemical study of 2-,4-,6-, and 8-methylquinoline, J. Chem. Thermodyn., 1995, 27, 565-574. [all data]

Ribeiro da Silva, 1995
Ribeiro da Silva, M., Thermochemical study of 2-, 4-, 6-, and 8-methylquinoline, The Journal of Chemical Thermodynamics, 1995, 27, 6, 565-574, https://doi.org/10.1006/jcht.1995.0058 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Malanowski, 1961
Malanowski, S., Bull. Acad. Pol. Sci. Ser. Sci. Chim., 1961, 9, 71. [all data]

Malanowski, 1961, 2
Malanowski, S., Vapour Pressures and Boiling Temperatures of Some Quinoline Bases, Bull. Acad. Pol. Sci. Ser. Sci. Chim., 1961, 9, 2, 71-76. [all data]


Notes

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