Galactitol

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfsolid-321.93kcal/molCcbMcClaine, 1947ALS
Δfsolid-321.90 ± 0.19kcal/molCcbParks, West, et al., 1946ALS
Quantity Value Units Method Reference Comment
Δcsolid-720.67kcal/molCcbStroh and Fincke, 1963hcomb by Parks and Manchester, 1952; Corresponding Δfsolid = -321.84 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Δcsolid-727.95kcal/molCmParks and Manchester, 1952From heat of solution; Corresponding Δfsolid = -314.56 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Δcsolid-720.6 ± 0.4kcal/molCcbMcClaine, 1947Corresponding Δfsolid = -321.9 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Δcsolid-720.63 ± 0.43kcal/molCcbParks, West, et al., 1946Corresponding Δfsolid = -321.88 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
solid,1 bar56.00cal/mol*KN/AParks, Kelley, et al., 1929Extrapolation below 90 K, 60.25 J/mol*K. Revision of previous data.; DH
solid,1 bar59.20cal/mol*KN/AParks and Huffman, 1926Extrapolation below 90 K, 73.35 J/mol*K.; DH

Constant pressure heat capacity of solid

Cp,solid (cal/mol*K) Temperature (K) Reference Comment
57.00292.8Parks and Huffman, 1926T = 88 to 293 K. Value is unsmoothed experimental datum.; DH

References

Go To: Top, Condensed phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

McClaine, 1947
McClaine, L.A., Thermodynamic data for some compounds containing carbon, hydrogen and oxygen, Ph.D. Thesis for Stanford University, 1947, 1-57. [all data]

Parks, West, et al., 1946
Parks, G.S.; West, T.J.; Naylor, B.F.; Fujii, P.S.; McClaine, L.A., Thermal data on organic compounds. XXIII. Modern combustion data for fourteen hydrocarbons and five polyhydroxy alcohols, J. Am. Chem. Soc., 1946, 68, 2524-2527. [all data]

Stroh and Fincke, 1963
Stroh, H.H.; Fincke, C.R., Beobachtung ciner unterschidlichen hydrierbarkeit von n-substituiertten aziridin-derivaten, Z. Chem., 1963, 3, 265-266. [all data]

Parks and Manchester, 1952
Parks, G.S.; Manchester, K.E., The heats of solution of erythritol, mannitol and dulcitol; combustion values for liquid polyhydroxy alcohols, J. Am. Chem. Soc., 1952, 74, 3435-34. [all data]

Parks, Kelley, et al., 1929
Parks, G.S.; Kelley, K.K.; Huffman, H.M., Thermal data on organic compounds. V. A revision of the entropies and free energies of nineteen organic compounds, J. Am. Chem. Soc., 1929, 51, 1969-1973. [all data]

Parks and Huffman, 1926
Parks, G.S.; Huffman, H.M., Thermal data on organic compounds. IV. The heat capacities, entropies and free energies of normal propyl alcohol, ethyl ether and dulcitol, J. Am. Chem. Soc., 1926, 48, 2788-2793. [all data]


Notes

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