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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity determinations

EA (eV) Method Reference Comment
1.09997EndoRefaey, 1976I- + H2S ->. Computation at a variety of levels imply that the anion is not bound with repect to dissociatve attachment.
2.28841N/ACheck, Faust, et al., 2001H-; ; «DELTA»S(acid)=20.9; «DELTA»S(EA)=6.4

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Refaey, 1976
Refaey, K.M.A., Endoergic ion-molecule-collision processes of negative ions. II. Collisions of I- on H2S, CS2, and COS, J. Chem. Phys., 1976, 65, 2002. [all data]

Check, Faust, et al., 2001
Check, C.E.; Faust, T.O.; Bailey, J.M.; Wright, B.J.; Gilbert, T.M.; Sunderlin, L.S., Addition of Polarization and Diffuse Functions to the LANL2DZ Basis Set for P-Block Elements, J. Phys. Chem. A,, 2001, 105, 34, 8111, https://doi.org/10.1021/jp011945l . [all data]


Notes

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