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Benzene, 2-methyl-1,3-dinitro-

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafsolid-55.2 ± 2.2kJ/molCcbBarakat and Finch, 1984see Finch and Payne, 1990; ALS
Deltafsolid-41.8kJ/molCcbMedard and Thomas, 1949Author's hf298_condensed=-13.4 kcal/mol; ALS
Quantity Value Units Method Reference Comment
Deltacsolid-3556.8 ± 1.0kJ/molCcbBarakat and Finch, 1984see Finch and Payne, 1990; ALS
Deltacsolid-3570.3kJ/molCcbMedard and Thomas, 1949Author's hf298_condensed=-13.4 kcal/mol; ALS
Deltacsolid-3560.9 ± 3.6kJ/molCcbBadoche, 1939Reanalyzed by Cox and Pilcher, 1970, Original value = -3563.9 kJ/mol; ALS
Deltacsolid-3574.kJ/molCcbGarner and Abernethy, 1921ALS

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
217.305.Finch and Payne, 1990T = 305 to 365 K. Unsmoothed experimental datum.; DH
224.305.Finch and Payne, 1990T = 305 to 365 K. Unsmoothed experimental datum.; DH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Barakat and Finch, 1984
Barakat, A.; Finch, A., Thermochemistry of 2,6-dinitrotoluene, Thermochim. Acta, 1984, 73, 205-208. [all data]

Finch and Payne, 1990
Finch, A.; Payne, J., Thermochemical study of 1,6-dinitrotoluene, Thermochim. Acta, 1990, 164, 55-63. [all data]

Medard and Thomas, 1949
Medard, L.; Thomas, M., Determinations calorimetriques concernant dix-huit derives nitres ou nitrates organiques., Mem. Poudres, 1949, 29, 173-195. [all data]

Badoche, 1939
Badoche, M.M., Determinations des chaleurs de combustion de derives nitres de la serie benzenique, Bull. Soc. Chim. France, 1939, 6, 570-579. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Garner and Abernethy, 1921
Garner, W.E.; Abernethy, C.L., Heats of combustion and formation of nitro-compounds. Part I. - Benzene, toluene, phenol and methylaniline series, Proc. Roy. Soc. London A, 1921, 213-235. [all data]


Notes

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