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Oxazepam


Normal alkane RI, non-polar column, temperature ramp

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type PackedCapillaryCapillaryPackedCapillary
Active phase SE-30BP-1DB-5SE-30BP-1
Column length (m) 2. 15.2.12.
Carrier gas Nitrogen HeHeHe
Substrate Chromosorb G AW DMCS (80-100 mesh)  Chromosorb W(100-120 mesh) 
Column diameter (mm)   0.25 0.22
Phase thickness (mum)   0.25 0.25
Tstart (C) 100.100.150.200.120.
Tend (C) 300.300.260.285.280.
Heat rate (K/min)   10.4.8.
Initial hold (min)   1.2. 
Final hold (min)    10. 
I 2336.2374.2374.2354.2293.
ReferenceMHA, 9999MHA, 9999Zamechnik, Ethier, et al., 1989Chiarotti, de Giovanni, et al., 1986Stowell and Wilson, 1985
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryPackedPackedPackedPacked
Active phase BP-1OV-1SE-30SE-30SE-30
Column length (m) 12.2.2.2.2.
Carrier gas He  NitrogenN2
Substrate  Gas Chrom PGas Chrom PChromosorb W AW DMS (80-100 mesh)Chromosorb W AW DMS
Column diameter (mm) 0.22    
Phase thickness (mum) 0.25    
Tstart (C) 50.150.150.130.130.
Tend (C) 300.300.300.290.290.
Heat rate (K/min) 20.5.5.8.8.
Initial hold (min)    2.2.
Final hold (min)    8.8.
I 2294.2300.2325.2318.2318.
ReferenceStowell and Wilson, 1985Marozzi, Gambaro, et al., 1982Marozzi, Gambaro, et al., 1982Peel and Perrigo, 1976Peel and Perrigo, 1975
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI

References

Go To: Top, Normal alkane RI, non-polar column, temperature ramp, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

MHA, 9999
MHA, Directorate of ForensicScience., Forensic Toxicology, 9999. [all data]

Zamechnik, Ethier, et al., 1989
Zamechnik, J.; Ethier, J.-C.; Neville, G.A., Benzodiazepines- an extensive collection of mass spectra, J. Can. Soc. Forensic Sci., 1989, 22, 3, 233-259, https://doi.org/10.1080/00085030.1989.10757437 . [all data]

Chiarotti, de Giovanni, et al., 1986
Chiarotti, M.; de Giovanni, N.; Fiori, A., Analysis of Benzodiazepines. I. Chromatographic Identification, J. Chromatogr., 1986, 358, 169-178, https://doi.org/10.1016/S0021-9673(01)90326-7 . [all data]

Stowell and Wilson, 1985
Stowell, A.; Wilson, L., Use of retention indices in drug screening by capillary gas chromatography, Rep. # CD 2362, Department of Scientific and Industrial Reseach, Chemistry Division, Lower Hutt, NZ, 1985, 32. [all data]

Marozzi, Gambaro, et al., 1982
Marozzi, E.; Gambaro, V.; Saligari, E.; Mariani, R.; Lodi, F., Use of the retention index in gas chromatographic studies of drugs, J. Anal. Toxicol., 1982, 6, 4, 185-192, https://doi.org/10.1093/jat/6.4.185 . [all data]

Peel and Perrigo, 1976
Peel, H.W.; Perrigo, B., A practical gas chromatographic screening procedure for toxicological analysis, Can. Soc. Forens. Sci. J., 1976, 9, 2, 69-74, https://doi.org/10.1080/00085030.1976.10757247 . [all data]

Peel and Perrigo, 1975
Peel, H.W.; Perrigo, B., A practical gas chromatographic screening procedure for toxicological analysis, Can.Soc.Forens.Sci.J., 1975, 9, 2, 69-74, https://doi.org/10.1080/00085030.1976.10757247 . [all data]


Notes

Go To: Top, Normal alkane RI, non-polar column, temperature ramp, References