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Stibine, triphenyl-

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Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafgas435. ± 19.kJ/molReviewMartinho Simões 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafsolid329. ± 17.kJ/molReviewMartinho Simões 
Quantity Value Units Method Reference Comment
Deltacsolid-10010. ± 17.kJ/molCC-SBBirr, 1960Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.

Phase change data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões

Quantity Value Units Method Reference Comment
Tfus328.2KN/AForward, Bowden, et al., 1949Uncertainty assigned by TRC = 0.5 K; TRC
Tfus325.15KN/ASmith and Andrews, 1931Uncertainty assigned by TRC = 1.5 K; with Hg thermometer; TRC
Tfus321.15KN/ASmith and Andrews, 1931Uncertainty assigned by TRC = 1.5 K; with thermocouple; TRC
Quantity Value Units Method Reference Comment
Deltasub106.3 ± 8.4kJ/molN/APilcher and Skinner, 1983See also Birr, 1960, 2.; AC
Deltasub106.3 ± 8.4kJ/molCC-SBSkinner H.A., 1964Please also see Forward, Bowden, et al., 1949, 2.; MS

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
83.3518.AStephenson and Malanowski, 1987Based on data from 503. - 553. K. See also Forward, Bowden, et al., 1949, 3.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Mass spectrum (electron ionization)

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Tony Mujsce, AT&T Bell Labs
NIST MS number 245770

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References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Birr, 1960
Birr, K.-H., Z. Anorg. Allg. Chem., 1960, 306, 21. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Forward, Bowden, et al., 1949
Forward, M.V.; Bowden, S.T.; Jones, W.J., Physical Properties of Triphenyl Compounds of Group VB Elements, J. Chem. Soc., 1949, 1949, 121-6. [all data]

Smith and Andrews, 1931
Smith, R.H.; Andrews, D.H., Thermal Energy Studies II. Phenyl Derivatives of Metals, J. Am. Chem. Soc., 1931, 53, 3661-7. [all data]

Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A., Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2 . [all data]

Birr, 1960, 2
Birr, Karl-Heinz, Bildungsw«65533»rmen von Triphenylphosphin und Triphenylstibin, Z. Anorg. Allg. Chem., 1960, 306, 1-2, 21-24, https://doi.org/10.1002/zaac.19603060104 . [all data]

Skinner H.A., 1964
Skinner H.A., In Advances in Organometallic Chemistry; Vol. 2, Academic Press, New York, 1964. [all data]

Forward, Bowden, et al., 1949, 2
Forward, M.V.; Bowden, S.T.; Jones, W.J., J. Chem. Soc., 1949, S121.. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Forward, Bowden, et al., 1949, 3
Forward, M.V.; Bowden, S.T.; Jones, W.J., S 26. Physical properties of triphenyl compounds of group V B elements, J. Chem. Soc., 1949, S121, https://doi.org/10.1039/jr949000s121 . [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), References