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Stibine, triphenyl-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões

Quantity Value Units Method Reference Comment
Tfus328.2KN/AForward, Bowden, et al., 1949Uncertainty assigned by TRC = 0.5 K; TRC
Tfus325.15KN/ASmith and Andrews, 1931Uncertainty assigned by TRC = 1.5 K; with Hg thermometer; TRC
Tfus321.15KN/ASmith and Andrews, 1931Uncertainty assigned by TRC = 1.5 K; with thermocouple; TRC
Quantity Value Units Method Reference Comment
Deltasub25.4 ± 2.0kcal/molN/APilcher and Skinner, 1983See also Birr, 1960.; AC
Deltasub25.4 ± 2.0kcal/molCC-SBSkinner H.A., 1964Please also see Forward, Bowden, et al., 1949, 2.; MS

Enthalpy of vaporization

DeltavapH (kcal/mol) Temperature (K) Method Reference Comment
19.9518.AStephenson and Malanowski, 1987Based on data from 503. - 553. K. See also Forward, Bowden, et al., 1949, 3.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Forward, Bowden, et al., 1949
Forward, M.V.; Bowden, S.T.; Jones, W.J., Physical Properties of Triphenyl Compounds of Group VB Elements, J. Chem. Soc., 1949, 1949, 121-6. [all data]

Smith and Andrews, 1931
Smith, R.H.; Andrews, D.H., Thermal Energy Studies II. Phenyl Derivatives of Metals, J. Am. Chem. Soc., 1931, 53, 3661-7. [all data]

Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A., Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2 . [all data]

Birr, 1960
Birr, Karl-Heinz, Bildungsw«65533»rmen von Triphenylphosphin und Triphenylstibin, Z. Anorg. Allg. Chem., 1960, 306, 1-2, 21-24, https://doi.org/10.1002/zaac.19603060104 . [all data]

Skinner H.A., 1964
Skinner H.A., In Advances in Organometallic Chemistry; Vol. 2, Academic Press, New York, 1964. [all data]

Forward, Bowden, et al., 1949, 2
Forward, M.V.; Bowden, S.T.; Jones, W.J., J. Chem. Soc., 1949, S121.. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Forward, Bowden, et al., 1949, 3
Forward, M.V.; Bowden, S.T.; Jones, W.J., S 26. Physical properties of triphenyl compounds of group V B elements, J. Chem. Soc., 1949, S121, https://doi.org/10.1039/jr949000s121 . [all data]


Notes

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