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Bismuthine, triphenyl-

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafgas138.6 ± 4.5kcal/molReviewMartinho Simões 
Deltafgas143.5 ± 2.4kcal/molReviewMartinho SimõesSelected data
Deltafgas135.9 ± 2.7kcal/molReviewMartinho Simões 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafsolid112.1 ± 4.0kcal/molReviewMartinho SimõesMS
Deltafsolid117.0 ± 1.3kcal/molReviewMartinho SimõesSelected data; MS
Deltafsolid109.4 ± 1.9kcal/molReviewMartinho SimõesMS
Quantity Value Units Method Reference Comment
Deltacsolid-2390.9 ± 1.2kcal/molCC-RBSteele, 1979MS
Deltacsolid-2383.3 ± 1.8kcal/molCC-RBBirr, 1961MS
Deltacsolid-2386.0 ± 4.0kcal/molCC-SBBirr, 1960Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.; MS

Constant pressure heat capacity of solid

Cp,solid (cal/mol*K) Temperature (K) Reference Comment
78.92298.15Steele, 1979, 2DH
78.49298.5Smith and Andrews, 1931T = 102 to 323 K.; DH

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões

Quantity Value Units Method Reference Comment
Tfus351.5KN/AForward, Bowden, et al., 1949Uncertainty assigned by TRC = 0.5 K; TRC
Tfus350.15KN/ASmith and Andrews, 1931, 2Uncertainty assigned by TRC = 1. K; with Hg thermometer; TRC
Tfus346.65KN/ASmith and Andrews, 1931, 2Uncertainty assigned by TRC = 1. K; with thermocouple; TRC
Quantity Value Units Method Reference Comment
Deltasub26.5 ± 2.0kcal/molN/APilcher and Skinner, 1983See also Steele, 1979, 2.; AC
Deltasub26.5 ± 2.0kcal/molCC-SBSkinner H.A., 1964MS

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
7.45 ± 0.05PIPotapov, Rodionov, et al., 1974LLK
7.3 ± 0.1PIVilesov and Zaitsev, 1964RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C6H5Bi+7.8 ± 0.1?PIPotapov, Rodionov, et al., 1974LLK
C12H10Bi+7.9 ± 0.1?PIPotapov, Rodionov, et al., 1974LLK

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin B.ZEEH, TUBINGEN UNIVERSITY, TUBINGEN F.R.G.
NIST MS number 17609

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References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), NIST Free Links, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Steele, 1979
Steele, W.V., J. Chem. Thermodyn., 1979, 11, 187. [all data]

Birr, 1961
Birr, K.-H., Z. Anorg. Allg. Chem., 1961, 311, 92. [all data]

Birr, 1960
Birr, K.-H., Z. Anorg. Allg. Chem., 1960, 306, 21. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Steele, 1979, 2
Steele, W.V., The standard enthalpies of formation of the triphenyl compounds of the group V elements. 2. Triphenylbismuth and the Ph-Bi mean bond-dissociation energy, J. Chem. Thermodynam., 1979, 11, 187-192. [all data]

Smith and Andrews, 1931
Smith, R.H.; Andrews, D.H., Thermal energy studies. II. Phenyl derivatives of metals, J. Am. Chem. Soc., 1931, 53, 3661-3667. [all data]

Forward, Bowden, et al., 1949
Forward, M.V.; Bowden, S.T.; Jones, W.J., Physical Properties of Triphenyl Compounds of Group VB Elements, J. Chem. Soc., 1949, 1949, 121-6. [all data]

Smith and Andrews, 1931, 2
Smith, R.H.; Andrews, D.H., Thermal Energy Studies II. Phenyl Derivatives of Metals, J. Am. Chem. Soc., 1931, 53, 3661-7. [all data]

Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A., Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2 . [all data]

Skinner H.A., 1964
Skinner H.A., In Advances in Organometallic Chemistry; Vol. 2, Academic Press, New York, 1964. [all data]

Potapov, Rodionov, et al., 1974
Potapov, V.K.; Rodionov, A.N.; Evlasheva, T.I.; Rogozhin, K.L., Photoionization of triphenyl derivatives of elements in group VB of the periodic table, High Energy Chem., 1974, 8, 486, In original 559. [all data]

Vilesov and Zaitsev, 1964
Vilesov, F.I.; Zaitsev, V.M., Photoionization of phenyl derivatives of group 5 elements, Dokl. Akad. Nauk SSSR, 1964, 154, 886, In original 117. [all data]


Notes

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