Tricyclo[5.4.0.0(2,8)]undec-9-ene, 2,6,6,9-tetramethyl-, (1R,2S,7R,8R)-
- Formula: C15H24
- Molecular weight: 204.3511
- IUPAC Standard InChI: InChI=1S/C15H24/c1-10-6-7-11-13-12(10)15(11,4)9-5-8-14(13,2)3/h6,11-13H,5,7-9H2,1-4H3
- IUPAC Standard InChIKey: HICYDYJTCDBHMZ-UHFFFAOYSA-N
- CAS Registry Number: 5989-08-2
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Species with the same structure:
- Stereoisomers:
- Other names: α-Longipinene; (+)-α-Longipinene; Longipinene; (1R,2S,7R,8R)-2,6,6,9-Tetramethyltricyclo[5.4.0.02,8]undec-9-ene; 142792-92-5; Tricyclo[5.4.0.0(2,8)]undec-9-ene, 2,6,6,9-tetramethyl-
- Information on this page:
- Other data available:
- Options:
Normal alkane RI, non-polar column, temperature ramp
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | HP-5 | DB-5 | RTX-1 | RTX-1 | HP-5 MS |
| Column length (m) | 30. | 30. | 60. | 60. | 30. |
| Carrier gas | Helium | Helium | Helium | Helium | |
| Substrate | |||||
| Column diameter (mm) | 0.32 | 0.25 | 0.22 | 0.22 | 0.25 |
| Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | |
| Tstart (C) | 60. | 40. | 60. | 60. | 60. |
| Tend (C) | 240. | 250. | 230. | 230. | 280. |
| Heat rate (K/min) | 3. | 10. | 2. | 2. | 3. |
| Initial hold (min) | 2. | 1. | |||
| Final hold (min) | 3. | 30. | 30. | ||
| I | 1353. | 1353. | 1350. | 1360. | 1350. |
| Reference | Kahriman, Tosun, et al., 2011 | Yang, Zhang, et al., 2010 | Museli, Pau, et al., 2009 | Museli, Pau, et al., 2009 | Baziou, Couladis, et al., 2008 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | HP-5 | VF-5MS | SLB-5 MS | ZB-1 | DB-5 MS |
| Column length (m) | 30. | 30. | 30. | 30. | 30. |
| Carrier gas | Helium | Helium | Helium | Nitrogen | Helium |
| Substrate | |||||
| Column diameter (mm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
| Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
| Tstart (C) | 50. | 240. | 50. | 45. | 50. |
| Tend (C) | 300. | 320. | 250. | 230. | 300. |
| Heat rate (K/min) | 3. | 20. | 3. | 3. | 5. |
| Initial hold (min) | 1. | 2. | 5. | ||
| Final hold (min) | 30. | 10. | 5. | ||
| I | 1351. | 1356. | 1353. | 1344. | 1354. |
| Reference | Isidorov, Lech, et al., 2008 | Kowalski, 2008 | Lo Presti, Sciarrone, et al., 2008 | Mierendorff, Stahl-Biskup, et al., 2008 | Noudogbessi, Yedomonhan, et al., 2008 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | HP-5 MS | HP-5 | CP Sil 5 CB | DB-5 | DB-5 |
| Column length (m) | 30. | 30. | 30. | 30. | 30. |
| Carrier gas | Helium | Helium | N2 | Hydrogen | He |
| Substrate | |||||
| Column diameter (mm) | 0.25 | 0.25 | 0.32 | 0.25 | 0.25 |
| Phase thickness (μm) | 0.25 | 0.32 | 0.25 | 0.25 | 0.25 |
| Tstart (C) | 50. | 60. | 60. | 50. | 60. |
| Tend (C) | 240. | 250. | 300. | 250. | 320. |
| Heat rate (K/min) | 3. | 5. | 4. | 4. | 10. |
| Initial hold (min) | 30. | ||||
| Final hold (min) | 4. | ||||
| I | 1352. | 1351. | 1355. | 1352. | 1355. |
| Reference | Sarikurkcu, Tepe, et al., 2008 | Yassa and Akhani, 2008 | Baran, von Reuss, et al., 2007 | Pontes, de Olivera, et al., 2007 | Smelcerovic, Spiteller, et al., 2007 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | HP-5 | DB-5 | DB-5 | ZB-5 | HP-1 |
| Column length (m) | 30. | 30. | 30. | 60. | 50. |
| Carrier gas | He | He | He | He | |
| Substrate | |||||
| Column diameter (mm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.2 |
| Phase thickness (μm) | 0.32 | 0.25 | 0.25 | 0.25 | 0.25 |
| Tstart (C) | 60. | 50. | 60. | 40. | 60. |
| Tend (C) | 250. | 250. | 200. | 250. | 250. |
| Heat rate (K/min) | 5. | 3. | 2. | 6. | 2. |
| Initial hold (min) | 30. | 7. | 60. | ||
| Final hold (min) | 10. | 60. | 1. | ||
| I | 1351. | 1347. | 1347. | 1377. | 1364. |
| Reference | Yassa and Akhani, 2007 | Havlik, Kokoska, et al., 2006 | Rout, Naik, et al., 2006 | Dötterl, Wolfe, et al., 2005 | Fernandez, Lizzani-Cuvelier, et al., 2005 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | HP-5 | HP-5MS | HP-5 | ZB-1 | HP-5 |
| Column length (m) | 30. | 30. | 30. | 30. | 30. |
| Carrier gas | Helium | He | He | N2 | He |
| Substrate | |||||
| Column diameter (mm) | 0.32 | 0.25 | 0.25 | 0.25 | 0.25 |
| Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.32 |
| Tstart (C) | 40. | 60. | 60. | 45. | 60. |
| Tend (C) | 300. | 275. | 275. | 230. | 250. |
| Heat rate (K/min) | 4. | 4. | 4. | 3. | 5. |
| Initial hold (min) | 30. | ||||
| Final hold (min) | 5. | ||||
| I | 1338. | 1348. | 1357. | 1347. | 1360. |
| Reference | Utsunomia, Kawata, et al., 2005 | Hajhashemi V., Ghannadi A., et al., 2004 | Ghannadi and Zolfaghari, 2003 | Mierendorff, Stahl-Biskup, et al., 2003 | Yassa, Akhani, et al., 2003 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | DB-5MS | DB-5 | DB-5 | RSL-200 | RSL-200 |
| Column length (m) | 30. | 25. | 30. | 30. | 60. |
| Carrier gas | He | He | He | H2 | H2 |
| Substrate | |||||
| Column diameter (mm) | 0.25 | 0.2 | 0.25 | 0.32 | 0.32 |
| Phase thickness (μm) | 0.25 | 0.25 | 0.25 | ||
| Tstart (C) | 50. | 60. | 60. | 40. | 40. |
| Tend (C) | 280. | 220. | 240. | 280. | 250. |
| Heat rate (K/min) | 15. | 3. | 3. | 6. | 6. |
| Initial hold (min) | 2. | 5. | |||
| Final hold (min) | 10. | 5. | |||
| I | 1368. | 1355. | 1353. | 1359. | 1360. |
| Reference | Damon, Hernández, et al., 2002 | Schwob, Bessière, et al., 2002 | Zoghbi, Andrade, et al., 2002 | Jirovetz L., Buchbauer G., et al., 2001 | Jirovetz, Puschmann, et al., 2000 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary |
|---|---|
| Active phase | DB-5 |
| Column length (m) | 30. |
| Carrier gas | He |
| Substrate | |
| Column diameter (mm) | 0.25 |
| Phase thickness (μm) | 0.25 |
| Tstart (C) | 65. |
| Tend (C) | 300. |
| Heat rate (K/min) | 4. |
| Initial hold (min) | 2. |
| Final hold (min) | |
| I | 1357. |
| Reference | Elias, Simoneit, et al., 1997 |
| Comment | MSDC-RI |
References
Go To: Top, Normal alkane RI, non-polar column, temperature ramp, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Kahriman, Tosun, et al., 2011
Kahriman, N.; Tosun, G.; Terzioglu, S.; Karaoglu, S.A.; Yayh, N.,
Chemical composition and antimicrobial activity of the essential oils from the flower, leaf, and stem of Senecio pandurifolis,
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Analysis if the essential oils of pine cones of Pinus koraiensis Steb. et Zucc. and P. sylvestris L. from China,
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Museli, Pau, et al., 2009
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Volatile constituents of Achllea ligustica All. by HS-SPME/GC/GC-MS. Comparison with essential oils obtained by hydrodistillation from Corsica and Sardinia,
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Baziou, Couladis, et al., 2008
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Composition and antioxidant activity of the essential oil of Hypericum perfoliatum from Greece, 2008, retrieved from http://www.amapseec.org/cmapseec.1/Papers/papp065.htm. [all data]
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Gas Chromatographic - nass spectrometric investigation of metabolites from the needles and roots of pine seedlings at early stages of pathogenic fungi Armillaria ostoyae attack,
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Composition of commercial Cape chamomile oil (Eriocephalus punctuatus / Eriocephalus tenuifolius), 2008, retrieved from http://www.chemische-analysen-hamburg.de/Publikationen?CapeChamomileOil/. [all data]
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Noudogbessi, J.-P.; Yedomonhan, P.; Sohounhloue, D.C.K.; Chalchat, J.-C.; Figueredo, G.,
Chemical composition of essential oil of syzygium guineense (Willd.) DC. var. guineense (Myrtaceae) from Benin,
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Sarikurkcu, Tepe, et al., 2008
Sarikurkcu, C.; Tepe, B.; Daferera, D.; Polissiou, M.; Harmandar, M.,
Studies on the anioxidant activity of the essential oil and methanol extract of Marrubium globosum subsp. globosum (lamiaceae) by three different chemical assays,
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Baran, von Reuss, et al., 2007
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Pontes, de Olivera, et al., 2007
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Chemical composition and acaridical activity of the leaf and fruit essential oils of Protium heptaphyllum (Aubl.) Marchand (Burseraceae),
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Smelcerovic, Spiteller, et al., 2007
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Yassa and Akhani, 2007
Yassa, N.; Akhani, H.,
The essential oils composition in two species of the genus Eriocycla Lindl. (Apiaceae) from Iran, 2007, retrieved from http://biology.ut.ac.ir/members/akhani/PdfReprintNumber/27.pdf. [all data]
Havlik, Kokoska, et al., 2006
Havlik, J.; Kokoska, L.; Vasickova, S.; Valterova, I.,
Chemical composition of essential oil from the seeds of Nigella arvensis L. and assessment of its actimicrobial activity,
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Composition of the concrete, absolute, headspace and essential oil of the flowers of Michelia champaca Linn.,
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Dötterl, Wolfe, et al., 2005
Dötterl, S.; Wolfe, L.M.; Jürgens, A.,
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Chemical composition of the essential oils from Turkish and Honduras Styrax,
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Utsunomia, Kawata, et al., 2005
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Ghannadi and Zolfaghari, 2003
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Compositional analysis of the essential oil of Lallemantia royleana (Benth. in Wall.) Benth. from Iran,
Flavour Fragr. J., 2003, 18, 3, 237-239, https://doi.org/10.1002/ffj.1215
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Mierendorff, Stahl-Biskup, et al., 2003
Mierendorff, H.-G.; Stahl-Biskup, E.; Posthumus, M.A.; van Beek, T.A.,
Composition of commercial Cape chamomile oil (Eriocephalus punctulatus),
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Yassa, Akhani, et al., 2003
Yassa, N.; Akhani, H.; Aqaahmadi, M.; Salimian, M.,
Essential oils from two endemic species of Apiaceae from Iran,
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Damon, Hernández, et al., 2002
Damon, A.A.; Hernández, A.S.; Rojas, J.C.,
Analysis of the fragrance produced by the epiphytic orchid Anathallis (Pleurothallis) racemiflora (orchidaceae) in the Soconusco region, Chiapas, Mexico,
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Schwob, Bessière, et al., 2002
Schwob, I.; Bessière, J.-M.; Viano, J.,
Composition of the essential oils of Hypericum perforatum L. from southeastern France,
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Zoghbi, Andrade, et al., 2002
Zoghbi, M.G.B.; Andrade, E.H.A.; da Silva, M.H.; Maia, J.G.S.; Luz, A.I.R.; da Silva, J.D.,
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Jirovetz L., Buchbauer G., et al., 2001
Jirovetz L.; Buchbauer G.; Shafi P.M.; Rosamma M.K.; Geissler M.,
Analysis of the composition and aroma of the essential leaf oil of Syzygium travancoricum from South India by GC-FID, GC-MS, and olfactometry. Seasonal changes of composition,
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Jirovetz, Puschmann, et al., 2000
Jirovetz, L.; Puschmann, C.; Stojanova, A.; Metodiev, S.; Buchbauer, G.,
Analysis of the essential oil volatiles of Douglas fir (Pseudotsuga menziesii) from Bulgaria,
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Elias, Simoneit, et al., 1997
Elias, V.O.; Simoneit, B.R.T.; Cardoso, J.N.,
Analysis of volatile sesquiterpenoids in environmental and geological samples,
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. [all data]
Notes
Go To: Top, Normal alkane RI, non-polar column, temperature ramp, References
- Symbols used in this document:
Tend Final temperature Tstart Initial temperature - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
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