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Stannane, tetraethyl-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
MS - José A. Martinho Simões
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil473.1KN/ADibrivnyi, Dolbneva, et al., 1986Uncertainty assigned by TRC = 0.5 K; TRC
Quantity Value Units Method Reference Comment
Tfus142.14KN/AStaveley, Warren, et al., 1954Uncertainty assigned by TRC = 0.2 K; TRC
Quantity Value Units Method Reference Comment
Ttriple141.9KN/AMaslova, Rabinovich, et al., 1972Crystal phase 1 phase; Uncertainty assigned by TRC = 0.2 K; TRC
Quantity Value Units Method Reference Comment
Deltavap50.6 ± 0.2kJ/molCC-SBAbraham and Irving, 1980Another value for the enthalpy of vaporization has been reported: 51.0 ± 2.1 kJ/mol Davies, Pope, et al., 1963.; MS
Deltavap50.6 ± 0.2kJ/molCAbraham and Irving, 1980, 2AC

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
46.6 ± 0.6374.N/ABaev, 2001Based on data from 293. - 455. K.; AC
42.4313. - 393.GCHawker, 1992AC

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
9.146142.14Staveley, Warren, et al., 1954, 2DH
9.15142.1Domalski and Hearing, 1996AC

Entropy of fusion

DeltafusS (J/mol*K) Temperature (K) Reference Comment
64.35142.14Staveley, Warren, et al., 1954, 2DH

Enthalpy of phase transition

DeltaHtrs (kJ/mol) Temperature (K) Initial Phase Final Phase Reference Comment
-1.090121.4crystaline, IIcrystaline, IMaslova, Rabinovich, et al., 1972, 2Metastable transition.; DH
8.929141.9crystaline, IliquidMaslova, Rabinovich, et al., 1972, 2DH

Entropy of phase transition

DeltaStrs (J/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
62.9141.9crystaline, IliquidMaslova, Rabinovich, et al., 1972, 2DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Dibrivnyi, Dolbneva, et al., 1986
Dibrivnyi, V.N.; Dolbneva, T.N.; Dikii, M.A., Saturated vapor pressure and vaporization enthalpies of aromatic peroxides in Vses. Konf. po Kalorimetrii i Khim. Termodinamike, 11th, Novosibirsk, Nr 2, p 115, 1986. [all data]

Staveley, Warren, et al., 1954
Staveley, L.A.K.; Warren, J.B.; Paget, H.P.; Dowrick, D.J., Some Thermodynamic Properties of Compounds of the Formula MX4 II. Tetraalkyl Compounds, J. Chem. Soc., 1954, 1954, 1992. [all data]

Maslova, Rabinovich, et al., 1972
Maslova, V.A.; Rabinovich, I.B.; Nistoalov, V.P.; Faminskaya, L.A., Specific heat and phase transition of some alkyl compounds of silicon, germanium, and tin, Tr. Khim. Khim. Tekhnol., 1972, 1972, 44. [all data]

Abraham and Irving, 1980
Abraham, M.H.; Irving, R.J., J. Chem. Thermodyn., 1980, 12, 539. [all data]

Davies, Pope, et al., 1963
Davies, J.V.; Pope, A.E.; Skinner, H.A., Thermochemistry of metallic alkyls. Part 10.?Heats of combustion of some tetra-alkyls of tin, Trans. Faraday Soc., 1963, 59, 2233, https://doi.org/10.1039/tf9635902233 . [all data]

Abraham and Irving, 1980, 2
Abraham, M.H.; Irving, R.J., Enthalpies of vaporization of tetramethyltin, tetraethyltin, tetra-n-propyltin, and tetraethyl-lead, and a survey of the Group IV tetramethyl and tetraethyl compounds, The Journal of Chemical Thermodynamics, 1980, 12, 6, 539-544, https://doi.org/10.1016/0021-9614(80)90183-4 . [all data]

Baev, 2001
Baev, A.K., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 2001, 44, 1, 3. [all data]

Hawker, 1992
Hawker, Darryl, Equilibrium vapour pressures of tetraorganostannanes, Chemosphere, 1992, 25, 4, 427-436, https://doi.org/10.1016/0045-6535(92)90276-W . [all data]

Staveley, Warren, et al., 1954, 2
Staveley, L.A.K.; Warren, J.B.; Paget, H.P.; Dowrick, D.J., Some thermodynamic properties of compounds of the formula MX4. Part II. Tetra-alkyl compounds, 1954, J. [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]

Maslova, Rabinovich, et al., 1972, 2
Maslova, V.A.; Rabinovich, I.B.; Nistoalov, V.P.; Faminskaya, L.A., Specific heat and phase transitions of some alkyl compounds of silicon, germanium, and tin, Tr. Khim. Khim. Tekhnol., 1972, (2), 44-50. [all data]


Notes

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