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Stannane, tetraethyl-

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafgas-42.0 ± 2.6kJ/molReviewMartinho SimõesSelected data.
Deltafgas-65.4 ± 6.4kJ/molReviewMartinho Simões 
Deltafgas-44.0 ± 8.5kJ/molReviewMartinho Simões 
Deltafgas-60.8 ± 8.5kJ/molReviewMartinho Simões 
Deltafgas-169.5kJ/molReviewMartinho Simões 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-92.6 ± 2.6kJ/molReviewMartinho SimõesSelected data.; MS
Deltafliquid-116.0 ± 6.4kJ/molReviewMartinho SimõesMS
Deltafliquid-94.6 ± 8.5kJ/molReviewMartinho SimõesMS
Deltafliquid-111.4 ± 8.5kJ/molReviewMartinho SimõesMS
Deltafliquid-220.1kJ/molReviewMartinho SimõesMS
Quantity Value Units Method Reference Comment
Deltacliquid-6489.4 ± 8.4kJ/molCC-SBTel'noi and Rabinovich, 1966Please also see Cox and Pilcher, 1970.; MS
Deltacliquid-6491.4 ± 2.3kJ/molCC-SBDavies, Pope, et al., 1963Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.; MS
Deltacliquid-6472.6 ± 8.4kJ/molCC-SBDillard, McNeill, et al., 1958MS
Deltacliquid-6468.0 ± 6.3kJ/molCC-SBBalandin, Klabunovskii, et al., 1957Please also see Cox and Pilcher, 1970.; MS
Deltacliquid-6363.9kJ/molCC-SBJones, Evans, et al., 1935MS

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
301.7298.15Maslova, Rabinovich, et al., 1972T = 60 to 300 K.; DH

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
MS - José A. Martinho Simões
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil473.1KN/ADibrivnyi, Dolbneva, et al., 1986Uncertainty assigned by TRC = 0.5 K; TRC
Quantity Value Units Method Reference Comment
Tfus142.14KN/AStaveley, Warren, et al., 1954Uncertainty assigned by TRC = 0.2 K; TRC
Quantity Value Units Method Reference Comment
Ttriple141.9KN/AMaslova, Rabinovich, et al., 1972, 2Crystal phase 1 phase; Uncertainty assigned by TRC = 0.2 K; TRC
Quantity Value Units Method Reference Comment
Deltavap50.6 ± 0.2kJ/molCC-SBAbraham and Irving, 1980Another value for the enthalpy of vaporization has been reported: 51.0 ± 2.1 kJ/mol Davies, Pope, et al., 1963.; MS
Deltavap50.6 ± 0.2kJ/molCAbraham and Irving, 1980, 2AC

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
46.6 ± 0.6374.N/ABaev, 2001Based on data from 293. - 455. K.; AC
42.4313. - 393.GCHawker, 1992AC

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
9.146142.14Staveley, Warren, et al., 1954, 2DH
9.15142.1Domalski and Hearing, 1996AC

Entropy of fusion

DeltafusS (J/mol*K) Temperature (K) Reference Comment
64.35142.14Staveley, Warren, et al., 1954, 2DH

Enthalpy of phase transition

DeltaHtrs (kJ/mol) Temperature (K) Initial Phase Final Phase Reference Comment
-1.090121.4crystaline, IIcrystaline, IMaslova, Rabinovich, et al., 1972Metastable transition.; DH
8.929141.9crystaline, IliquidMaslova, Rabinovich, et al., 1972DH

Entropy of phase transition

DeltaStrs (J/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
62.9141.9crystaline, IliquidMaslova, Rabinovich, et al., 1972DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Stannane, tetraethyl- (l) + Tin(IV) chloride (l) = C2H5Cl3Sn (l) + Stannane, chlorotriethyl- (l)

By formula: C8H20Sn (l) + Cl4Sn (l) = C2H5Cl3Sn (l) + C6H15ClSn (l)

Quantity Value Units Method Reference Comment
Deltar-94.6 ± 4.6kJ/molRSC and ESTNash, Skinner, et al., 1965 

3Stannane, tetraethyl- (l) + Tin(IV) chloride (l) = 4Stannane, chlorotriethyl- (l)

By formula: 3C8H20Sn (l) + Cl4Sn (l) = 4C6H15ClSn (l)

Quantity Value Units Method Reference Comment
Deltar-189.5 ± 9.2kJ/molRSC and ESTNash, Skinner, et al., 1965 

IR Spectrum

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Gas Phase Spectrum

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IR spectrum
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Additional Data

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Owner NIST Standard Reference Data Program
Collection (C) 2018 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Sadtler Research Labs Under US-EPA Contract
State gas

This IR spectrum is from the NIST/EPA Gas-Phase Infrared Database .


Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Due to licensing restrictions, this spectrum cannot be downloaded.

Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Chemical Concepts
NIST MS number 162550

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References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, IR Spectrum, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Tel'noi and Rabinovich, 1966
Tel'noi, V.I.; Rabinovich, I.B., Russ. J. Phys. Chem., 1966, 40, 842. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Davies, Pope, et al., 1963
Davies, J.V.; Pope, A.E.; Skinner, H.A., Thermochemistry of metallic alkyls. Part 10.?Heats of combustion of some tetra-alkyls of tin, Trans. Faraday Soc., 1963, 59, 2233, https://doi.org/10.1039/tf9635902233 . [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Dillard, McNeill, et al., 1958
Dillard, C.R.; McNeill, E.H.; Simmons, D.E.; Yeldell, J.B., J. Am. Chem. Soc., 1958, 80, 3607. [all data]

Balandin, Klabunovskii, et al., 1957
Balandin, A.A.; Klabunovskii, E.I.; Kozina, M.P.; Ul'yanova, O.D., Izvest. Akad. Nauk SSSR Otdel. Khim. Nauk, 1957. [all data]

Jones, Evans, et al., 1935
Jones, W.J.; Evans, D.P.; Gulwell, T.; Griffiths, D.C., J. Chem. Soc., 1935, 39.. [all data]

Maslova, Rabinovich, et al., 1972
Maslova, V.A.; Rabinovich, I.B.; Nistoalov, V.P.; Faminskaya, L.A., Specific heat and phase transitions of some alkyl compounds of silicon, germanium, and tin, Tr. Khim. Khim. Tekhnol., 1972, (2), 44-50. [all data]

Dibrivnyi, Dolbneva, et al., 1986
Dibrivnyi, V.N.; Dolbneva, T.N.; Dikii, M.A., Saturated vapor pressure and vaporization enthalpies of aromatic peroxides in Vses. Konf. po Kalorimetrii i Khim. Termodinamike, 11th, Novosibirsk, Nr 2, p 115, 1986. [all data]

Staveley, Warren, et al., 1954
Staveley, L.A.K.; Warren, J.B.; Paget, H.P.; Dowrick, D.J., Some Thermodynamic Properties of Compounds of the Formula MX4 II. Tetraalkyl Compounds, J. Chem. Soc., 1954, 1954, 1992. [all data]

Maslova, Rabinovich, et al., 1972, 2
Maslova, V.A.; Rabinovich, I.B.; Nistoalov, V.P.; Faminskaya, L.A., Specific heat and phase transition of some alkyl compounds of silicon, germanium, and tin, Tr. Khim. Khim. Tekhnol., 1972, 1972, 44. [all data]

Abraham and Irving, 1980
Abraham, M.H.; Irving, R.J., J. Chem. Thermodyn., 1980, 12, 539. [all data]

Abraham and Irving, 1980, 2
Abraham, M.H.; Irving, R.J., Enthalpies of vaporization of tetramethyltin, tetraethyltin, tetra-n-propyltin, and tetraethyl-lead, and a survey of the Group IV tetramethyl and tetraethyl compounds, The Journal of Chemical Thermodynamics, 1980, 12, 6, 539-544, https://doi.org/10.1016/0021-9614(80)90183-4 . [all data]

Baev, 2001
Baev, A.K., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 2001, 44, 1, 3. [all data]

Hawker, 1992
Hawker, Darryl, Equilibrium vapour pressures of tetraorganostannanes, Chemosphere, 1992, 25, 4, 427-436, https://doi.org/10.1016/0045-6535(92)90276-W . [all data]

Staveley, Warren, et al., 1954, 2
Staveley, L.A.K.; Warren, J.B.; Paget, H.P.; Dowrick, D.J., Some thermodynamic properties of compounds of the formula MX4. Part II. Tetra-alkyl compounds, 1954, J. [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]

Nash, Skinner, et al., 1965
Nash, G.A.; Skinner, H.A.; Stack, W.F., Trans. Faraday Soc., 1965, 61, 640. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, IR Spectrum, Mass spectrum (electron ionization), References