Diethyl sulfone

• Formula: C₄H₁₀O₂S
• Molecular weight: 122.186
• IUPAC Standard InChI: InChI=1S/C4H10O2S/c1-3-7(5,6)4-2/h3-4H2,1-2H3 Copy

  
• IUPAC Standard InChIKey: MBDUIEKYVPVZJH-UHFFFAOYSA-N Copy
• CAS Registry Number: 597-35-3
• Chemical structure:
  This structure is also available as a 2d Mol file
• Other names: Ethane, 1,1'-sulfonylbis-; Ethyl sulfone; Diethyl sulphone; 1,1'-Sulphonylbisethane; (C2H5)2SO2
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• Information on this page:
  • Condensed phase thermochemistry data
  • Phase change data
  • Gas phase ion energetics data
  • References
  • Notes
• Other data available:
  • Gas phase thermochemistry data
  • Mass spectrum (electron ionization)
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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Mackle and O'Hare, 1961
Mackle, H.; O'Hare, P.A.G., Studies in the thermochemistry of sulphones. Part 5.-Heats of combustion, formation, fusion, vaporization and atomization of eleven aliphatic sulphones, Trans. Faraday Soc., 1961, 57, 1070-1074. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Dyer, Harris, et al., 1982
Dyer, J.C.; Harris, D.L.; Evans, S.A., Oxygen-17 Nulcear Magnetic RFesonacne SPtroscopy of Sulfoxides and Sulfones. Alkyl Substituent Induced Chemical Shifts, J. Org. Chem., 1982, 47, 3660-4. [all data]

Boehme and Sitorus, 1972
Boehme, V.H.; Sitorus, U., Oxidation of Thioethers to Sulfones with Hydrogen Peroxide in Alkaline Solution, Chem.-Ztg., 1972, 96, 37-8. [all data]

Hall and Robinson, 1964
Hall, S.K.; Robinson, E.A., The Sulphuric Acid Solvent System. Part VI. The Basicities of Compounds Containing Sulphur-Oxyten Bonds, Can. J. Chem., 1964, 42, 1113-22. [all data]

Mcallan, Cullum, et al., 1951
Mcallan, D.T.; Cullum, T.V.; Dean, R.A.; Fidler, F.A., The Preparation and Properties of Sulfur Compounds Related to Petroleum I. The Dialkyl Sulfides and Disulfides, J. Am. Chem. Soc., 1951, 73, 3627-32. [all data]

Evlasheva, Puchkova, et al., 1975
Evlasheva, T.I.; Puchkova, V.V.; Potapov, V.K.; Gur'yanova, E.N., Ionisation potentials and electron-donating properties of sulphones, Russ. J. Phys. Chem., 1975, 49, 453. [all data]

Notes

Go To: Top, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, References

• Symbols used in this document:
  

  Tfus	Fusion (melting) point
  ΔcH°solid	Enthalpy of combustion of solid at standard conditions
  ΔfH°solid	Enthalpy of formation of solid at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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