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Plumbane, tetraphenyl-


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltasub194.6 ± 6.3kJ/molEPilcher and Skinner, 1983See also Carson, Laye, et al., 1972.; AC
Deltasub159. ± 1.kJ/molCC-RBKana'an and Morrison, 1977MS
Deltasub159. ± 1.kJ/molME,TEKana'an and Morrison, 1977, 2Based on data from 412. - 474. K.; AC
Deltasub82.8kJ/molN/ANewkirk, 1972AC

Enthalpy of sublimation

DeltasubH (kJ/mol) Temperature (K) Reference Comment
151.446.Stephenson and Malanowski, 1987Based on data from 412. - 480. K.; AC

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A., Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2 . [all data]

Carson, Laye, et al., 1972
Carson, A.S.; Laye, P.G.; Spencer, J.A.; Steele, W.V., The enthalpy of combustion of organo-metallic compounds measured with a vacuum-jacketed rotating aneroid calorimeter. The enthalpy of formation of lead tetraphenyl, The Journal of Chemical Thermodynamics, 1972, 4, 5, 783-787, https://doi.org/10.1016/0021-9614(72)90052-3 . [all data]

Kana'an and Morrison, 1977
Kana'an, A.S.; Morrison, T.I., J. Chem. Thermodyn., 1977, 9, 423. [all data]

Kana'an and Morrison, 1977, 2
Kana'an, Adli S.; Morrison, T.I., Enthalpy and entropy of sublimation of tetraphenyl plumbane the bond dissociation energy of Pb«58872»C, The Journal of Chemical Thermodynamics, 1977, 9, 5, 423-429, https://doi.org/10.1016/0021-9614(77)90142-2 . [all data]

Newkirk, 1972
Newkirk, Herbert W., Piezoelectric organometallic crystal: Growth and properties of tetraphenylsilicon, -germanium, -ti and -lead, Journal of Organometallic Chemistry, 1972, 44, 2, 263-271, https://doi.org/10.1016/S0022-328X(00)82914-9 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]


Notes

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