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Butane, 2-chloro-2-methyl-

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafliquid-235. ± 2.kJ/molCmArnett and Pienta, 1980Hydrochlorination
Quantity Value Units Method Reference Comment
Deltacliquid-3327.5 ± 8.4kJ/molCcbSmith, Bjellerup, et al., 1953Reanalyzed by Cox and Pilcher, 1970, Original value = -3322. ± 8. kJ/mol

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Butane, 2-chloro-2-methyl- = Butane, 2-chloro-3-methyl-

By formula: C5H11Cl = C5H11Cl

Quantity Value Units Method Reference Comment
Deltar9.12kJ/molEqkEsipenok, Kabo, et al., 1973liquid phase; solvent: liquid phase
Deltar7.9 ± 0.2kJ/molEqkEsipenok, Kabo, et al., 1973liquid phase; solvent: cyclohexane

2-Butene, 2-methyl- + Hydrogen chloride = Butane, 2-chloro-2-methyl-

By formula: C5H10 + HCl = C5H11Cl

Quantity Value Units Method Reference Comment
Deltar-59.08 ± 0.92kJ/molCmArnett and Pienta, 1980liquid phase; solvent: Methylene chloride; Hydrochloroination

2-Methyl-1-butene + Hydrogen chloride = Butane, 2-chloro-2-methyl-

By formula: C5H10 + HCl = C5H11Cl

Quantity Value Units Method Reference Comment
Deltar-63.7 ± 1.4kJ/molCmArnett and Pienta, 1980liquid phase; solvent: Methylene chloride; Hydrochlorination

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Arnett and Pienta, 1980
Arnett, E.M.; Pienta, N.J., Stabilities of carbonium ions in solution. 12. Heats of formation of alkyl chlorides as an entree to heats of solvation of aliphatic carbonium ions, J. Am. Chem. Soc., 1980, 102, 3329-3334. [all data]

Smith, Bjellerup, et al., 1953
Smith, L.; Bjellerup, L.; Krook, S.; Westermark, H., Heats of combustion of organic chloro compounds determined by the "quartz wool" method, Acta Chem. Scand., 1953, 7, 65. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Esipenok, Kabo, et al., 1973
Esipenok, G.E.; Kabo, G.Ya.; Andreevskii, D.N., Equilibrium and thermodynamics of the isomerisation of methylchlorobutanes, Russ. J. Phys. Chem. (Engl. Transl.), 1973, 47, 420. [all data]


Notes

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