Butane, 2-chloro-2-methyl-

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

Butane, 2-chloro-2-methyl- = Butane, 2-chloro-3-methyl-

By formula: C5H11Cl = C5H11Cl

Quantity Value Units Method Reference Comment
Δr9.12kJ/molEqkEsipenok, Kabo, et al., 1973liquid phase; solvent: liquid phase
Δr7.9 ± 0.2kJ/molEqkEsipenok, Kabo, et al., 1973liquid phase; solvent: cyclohexane

2-Butene, 2-methyl- + Hydrogen chloride = Butane, 2-chloro-2-methyl-

By formula: C5H10 + HCl = C5H11Cl

Quantity Value Units Method Reference Comment
Δr-59.08 ± 0.92kJ/molCmArnett and Pienta, 1980liquid phase; solvent: Methylene chloride; Hydrochloroination

2-Methyl-1-butene + Hydrogen chloride = Butane, 2-chloro-2-methyl-

By formula: C5H10 + HCl = C5H11Cl

Quantity Value Units Method Reference Comment
Δr-63.7 ± 1.4kJ/molCmArnett and Pienta, 1980liquid phase; solvent: Methylene chloride; Hydrochlorination

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Esipenok, Kabo, et al., 1973
Esipenok, G.E.; Kabo, G.Ya.; Andreevskii, D.N., Equilibrium and thermodynamics of the isomerisation of methylchlorobutanes, Russ. J. Phys. Chem. (Engl. Transl.), 1973, 47, 420. [all data]

Arnett and Pienta, 1980
Arnett, E.M.; Pienta, N.J., Stabilities of carbonium ions in solution. 12. Heats of formation of alkyl chlorides as an entree to heats of solvation of aliphatic carbonium ions, J. Am. Chem. Soc., 1980, 102, 3329-3334. [all data]


Notes

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