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Stannane, tetramethyl-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
MS - José A. Martinho Simões
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil351.KN/APCR Inc., 1990BS
Quantity Value Units Method Reference Comment
Tfus218.18KN/AStaveley, Warren, et al., 1954Uncertainty assigned by TRC = 0.05 K; TRC
Quantity Value Units Method Reference Comment
Ttriple218.05KN/ASheiman, Rabinovich, et al., 1989Uncertainty assigned by TRC = 0.02 K; TRC
Quantity Value Units Method Reference Comment
Tc521.81KN/ABendtsen, 1977Uncertainty assigned by TRC = 0.02 K; Visual, observed with periscope in heated metal block, PRT, IPTS-68, PP.; TRC
Quantity Value Units Method Reference Comment
Pc29.813barN/ABendtsen, 1977Uncertainty assigned by TRC = 0.005 bar; Visual, observed with periscope in heated metal block, PRT,; TRC
Quantity Value Units Method Reference Comment
Deltavap32.0 ± 0.8kJ/molCC-SBAbraham and Irving, 1980Anoher value for the enthalpy of vaporization has been reported: 33.1 ± 1.3 kJ/mol Bullard and Haussmann, 1930.; MS
Deltavap31.1 ± 0.1kJ/molCAbraham and Irving, 1980, 2AC
Deltavap32.8 ± 0.1kJ/molN/AValerga, 1970AC
Deltavap30.5kJ/molN/AThompson and Linnett, 1936AC
Deltavap33.1kJ/molIBullard and Haussmann, 1929AC

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
32.6 ± 0.2311.N/ABaev, 2001Based on data from 273. - 350. K.; AC
31.3313. - 393.GCHawker, 1992AC
33.4290.IBullard and Haussmann, 1929Based on data from 273. - 308. K.; AC
31.6331.IBullard and Haussmann, 1929Based on data from 308. - 355. K.; AC
31.6303.N/ATanaka and Nagai, 1929Based on data from 298. - 308. K.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
221.9 - 351.4.098931286.161-37.304Stull, 1947Coefficents calculated by NIST from author's data.

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Method Reference Comment
9.234218.05N/ASheiman, Rabinovich, et al., 1989, 2DH
9.439218.18N/AStaveley, Warren, et al., 1954, 2DH
9.23218.2DSCSheiman, Rabinovich, et al., 1989See also Utschick, Bachmann, et al., 1974.; AC

Entropy of fusion

DeltafusS (J/mol*K) Temperature (K) Reference Comment
42.35218.05Sheiman, Rabinovich, et al., 1989, 2DH
43.26218.18Staveley, Warren, et al., 1954, 2DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

PCR Inc., 1990
PCR Inc., Research Chemicals Catalog 1990-1991, PCR Inc., Gainesville, FL, 1990, 1. [all data]

Staveley, Warren, et al., 1954
Staveley, L.A.K.; Warren, J.B.; Paget, H.P.; Dowrick, D.J., Some Thermodynamic Properties of Compounds of the Formula MX4 II. Tetraalkyl Compounds, J. Chem. Soc., 1954, 1954, 1992. [all data]

Sheiman, Rabinovich, et al., 1989
Sheiman, M.S.; Rabinovich, I.B.; Nistratov, V.P.; Kamelova, G.P.; Karataev, E.N.; Feshchenko, I.A., Heat capacity and thermodynamic characteristics of tetramethylstannane, Zh. Fiz. Khim., 1989, 63, 3, 836. [all data]

Bendtsen, 1977
Bendtsen, J., J. Raman Spectrosc., 1977, 6, 306. [all data]

Abraham and Irving, 1980
Abraham, M.H.; Irving, R.J., J. Chem. Thermodyn., 1980, 12, 539. [all data]

Bullard and Haussmann, 1930
Bullard, R.H.; Haussmann, A.C., J. Phys. Chem., 1930, 34, 743. [all data]

Abraham and Irving, 1980, 2
Abraham, M.H.; Irving, R.J., Enthalpies of vaporization of tetramethyltin, tetraethyltin, tetra-n-propyltin, and tetraethyl-lead, and a survey of the Group IV tetramethyl and tetraethyl compounds, The Journal of Chemical Thermodynamics, 1980, 12, 6, 539-544, https://doi.org/10.1016/0021-9614(80)90183-4 . [all data]

Valerga, 1970
Valerga, A.J., Entropy and related thermodynamic properties of tetramethylgermane, Diss. Abstr. Int., B, 1970, 31, 6, 3316. [all data]

Thompson and Linnett, 1936
Thompson, H.W.; Linnett, J.W., The vapour pressures and association of some metallic and non-metallic alkyls, Trans. Faraday Soc., 1936, 32, 681, https://doi.org/10.1039/tf9363200681 . [all data]

Bullard and Haussmann, 1929
Bullard, R.H.; Haussmann, A.C., The Vapor Pressure of Some Stannanes, J. Phys. Chem., 1929, 34, 4, 743-747, https://doi.org/10.1021/j150310a006 . [all data]

Baev, 2001
Baev, A.K., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 2001, 44, 1, 3. [all data]

Hawker, 1992
Hawker, Darryl, Equilibrium vapour pressures of tetraorganostannanes, Chemosphere, 1992, 25, 4, 427-436, https://doi.org/10.1016/0045-6535(92)90276-W . [all data]

Tanaka and Nagai, 1929
Tanaka, Y.; Nagai, Y., Proc. Imp. Acad. (Tokyo), 1929, 5, 78. [all data]

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]

Sheiman, Rabinovich, et al., 1989, 2
Sheiman, M.S.; Rabinovich, I.B.; Nistratov, V.P.; Kamelova, G.P.; Karataev, E.N.; Feshchenko, I.A., Specific heat and thermodynamic characteristics of tetramethylstanane, Zhur. Fiz. Khim., 1989, 63, 836-838. [all data]

Staveley, Warren, et al., 1954, 2
Staveley, L.A.K.; Warren, J.B.; Paget, H.P.; Dowrick, D.J., Some thermodynamic properties of compounds of the formula MX4. Part II. Tetra-alkyl compounds, 1954, J. [all data]

Utschick, Bachmann, et al., 1974
Utschick, H.; Bachmann, G.; Kapitza, H., Chem. Tech. (Leipzig), 1974, 26, 423. [all data]


Notes

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