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Stannane, tetramethyl-

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafgas-5. ± 20.kcal/molAVGN/AAverage of 7 values; Individual data points

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-12. ± 20.kcal/molAVGN/AAverage of 7 values; Individual data points
Quantity Value Units Method Reference Comment
Deltacliquid-910. ± 20.kcal/molAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
liquid74.28cal/mol*KN/ASheiman, Rabinovich, et al., 1989DH

Constant pressure heat capacity of liquid

Cp,liquid (cal/mol*K) Temperature (K) Reference Comment
47.30298.15Sheiman, Rabinovich, et al., 1989T = 5 to 313 K.; DH

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Stannane, tetramethyl- (g) = Trimethyltin (g) + Methane (g)

By formula: C4H12Sn (g) = C3H9Sn (g) + CH4 (g)

Quantity Value Units Method Reference Comment
Deltar71.0 ± 4.0kcal/molN/AMcMillen and Golden, 1982 
Deltar69. ± 2.kcal/molVLPPBaldwin, Lewis, et al., 1979Please also see Smith and Patrick, 1983.

Stannane, tetramethyl- (l) + Bromine (g) = C3H9BrSn (l) + Methane, bromo- (g)

By formula: C4H12Sn (l) + Br2 (g) = C3H9BrSn (l) + CH3Br (g)

Quantity Value Units Method Reference Comment
Deltar-48.30 ± 0.69kcal/molRSCPedley, Skinner, et al., 1957Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.

3Stannane, tetramethyl- (l) + Tin(IV) chloride (l) = 4Stannane, chlorotrimethyl- (l)

By formula: 3C4H12Sn (l) + Cl4Sn (l) = 4C3H9ClSn (l)

Quantity Value Units Method Reference Comment
Deltar-43.9 ± 6.6kcal/molRSCNash, Skinner, et al., 1965Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.

Stannane, tetramethyl- (l) + 3Tin(IV) chloride (l) = 4Methyltin trichloride (l)

By formula: C4H12Sn (l) + 3Cl4Sn (l) = 4CH3Cl3Sn (l)

Quantity Value Units Method Reference Comment
Deltar-44.5 ± 6.6kcal/molRSCNash, Skinner, et al., 1965Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.

Stannane, tetramethyl- (l) + Tin(IV) chloride (l) = 2Tin, dichlorodimethyl- (l)

By formula: C4H12Sn (l) + Cl4Sn (l) = 2C2H6Cl2Sn (l)

Quantity Value Units Method Reference Comment
Deltar-23.2 ± 3.5kcal/molRSCNash, Skinner, et al., 1965Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Sheiman, Rabinovich, et al., 1989
Sheiman, M.S.; Rabinovich, I.B.; Nistratov, V.P.; Kamelova, G.P.; Karataev, E.N.; Feshchenko, I.A., Specific heat and thermodynamic characteristics of tetramethylstanane, Zhur. Fiz. Khim., 1989, 63, 836-838. [all data]

McMillen and Golden, 1982
McMillen, D.F.; Golden, D.M., Hydrocarbon bond dissociation energies, Ann. Rev. Phys. Chem., 1982, 33, 493. [all data]

Baldwin, Lewis, et al., 1979
Baldwin, A.C.; Lewis, K.E.; Golden, D.M., Int. J. Chem. Kinet., 1979, 11, 529. [all data]

Smith and Patrick, 1983
Smith, G.P.; Patrick, R., Int. J. Chem. Kinet., 1983, 15, 167. [all data]

Pedley, Skinner, et al., 1957
Pedley, J.B.; Skinner, H.A.; Chernick, C.L., Thermochemistry of metallic alkyls. Part 8.?Tin tetramethyl, and hexamethyl distannane, Trans. Faraday Soc., 1957, 53, 1612, https://doi.org/10.1039/tf9575301612 . [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Nash, Skinner, et al., 1965
Nash, G.A.; Skinner, H.A.; Stack, W.F., Trans. Faraday Soc., 1965, 61, 640. [all data]


Notes

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