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Stannane, tetramethyl-

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Quantity Value Units Method Reference Comment
IE (evaluated)8.89 ± 0.05eVN/AN/AL
Quantity Value Units Method Reference Comment
Proton affinity (review)196.9kcal/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity190.6kcal/molN/AHunter and Lias, 1998HL

Ionization energy determinations

IE (eV) Method Reference Comment
8.93 ± 0.04PEJonas, Schweitzer, et al., 1973LLK
8.9 ± 0.1PEEvans, Green, et al., 1972LLK
8.76 ± 0.12EILappert, Pedley, et al., 1971LLK
8.76 ± 0.12EILappert, Simpson, et al., 1969RDSH
8.76 ± 0.02EIYergey and Lampe, 1968RDSH
8.25 ± 0.15EIHobrock and Kiser, 1961RDSH
9.7PEBancroft, Pellach, et al., 1982Vertical value; LBLHLM
9.7PEKochi, 1980Vertical value; LLK
9.75PEHosomi and Traylor, 1975Vertical value; LLK
9.75PEBrown, Eaton, et al., 1974Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
CH3Sn+14.2?EIdeRidder and Dijkstra, 1967RDSH
CH3Sn+15.7 ± 0.4?EIHobrock and Kiser, 1961RDSH
C2H6Sn+13.6?EIdeRidder and Dijkstra, 1967RDSH
C2H6Sn+13.0 ± 0.2?EIOccolowitz, Lett. 1966RDSH
C2H6Sn+13.1 ± 0.2?EIHobrock and Kiser, 1961RDSH
C2H7Sn+13.9?EIdeRidder and Dijkstra, 1967RDSH
C3H9Sn+9.58 ± 0.19CH3EILappert, Pedley, et al., 1971LLK
C3H9Sn+9.58 ± 0.19CH3EILappert, Simpson, et al., 1969RDSH
C3H9Sn+9.65CH3EIYergey and Lampe, 1968RDSH
C3H9Sn+9.72 ± 0.06CH3EIYergey and Lampe, 1965RDSH
SnH+16.8?EIdeRidder and Dijkstra, 1967RDSH
SnH3+14.0?EIdeRidder and Dijkstra, 1967RDSH
Sn+16.7?EIdeRidder and Dijkstra, 1967RDSH
Sn+17.5 ± 0.5?EIOccolowitz, Lett. 1966RDSH
Sn+18.1 ± 0.3?EIHobrock and Kiser, 1961RDSH

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Jonas, Schweitzer, et al., 1973
Jonas, A.E.; Schweitzer, G.K.; Grimm, F.A.; Carlson, T.A., The photoelectron spectra of the tetrafluoro and tetramethyl compounds of the group IV elements, J. Electron Spectrosc. Relat. Phenom., 1973, 1, 29. [all data]

Evans, Green, et al., 1972
Evans, S.; Green, J.C.; Joachim, P.J.; Orchard, A.F.; Turner, D.W.; Maier, J.P., Electronic structures of the Group IVB tetramethyls by helium-(I) photoelectron spectroscopy, J. Chem. Soc. Faraday Trans. 2, 1972, 68, 905. [all data]

Lappert, Pedley, et al., 1971
Lappert, M.F.; Pedley, J.B.; Simpson, J.; Spalding, T.R., Bonding studies of compounds of boron and the Group IV elements. VI. Mass spectrometric studies on compounds Me4M and Me3M-M'Me3 (M and M'=C, Si, Ge, Sn, and Pb): thermochemical data, J. Organomet. Chem., 1971, 29, 195. [all data]

Lappert, Simpson, et al., 1969
Lappert, M.F.; Simpson, J.; Spalding, T.R., Bonding studies of compounds of the group IV elements: ionisation potentials of the Me3M radicals, J.Organometal. Chem., 1969, 17, PI. [all data]

Yergey and Lampe, 1968
Yergey, A.L.; Lampe, F.W., An electron impact study of ionization and dissociation of trimethylstannanes, J. Organometal. Chem., 1968, 15, 339. [all data]

Hobrock and Kiser, 1961
Hobrock, B.G.; Kiser, R.W., Electron impact spectroscopy of tetramethylsilicon, -tin and -lead, J. Phys. Chem., 1961, 65, 2186. [all data]

Bancroft, Pellach, et al., 1982
Bancroft, G.M.; Pellach, E.; Tse, J.S., High resolution HeI and HeII photoelectron spectra of TiCl4, SnCl4, and (CH3)4Sn, Inorg. Chem., 1982, 21, 2950. [all data]

Kochi, 1980
Kochi, J.K., The role of electron transfer and charge transfer in organometallic chemistry, Pure Appl. Chem., 1980, 52, 571. [all data]

Hosomi and Traylor, 1975
Hosomi, A.; Traylor, T.G., Studies of interactions of adjacent carbon-metal «sigma» bonds by photoelectron spectroscopy, J. Am. Chem. Soc., 1975, 97, 3682. [all data]

Brown, Eaton, et al., 1974
Brown, R.S.; Eaton, D.F.; Hosomi, A.; Traylor, T.G.; Wright, J.M., Photoelectron spectra of cyclopropylcarbinyltrimethyltin and allyltrimethyltin. A comparison of «sigma»-«sigma» and «sigma»-«pi» conjugation, J. Organomet. Chem., 1974, 66, 249. [all data]

deRidder and Dijkstra, 1967
deRidder, J.J.; Dijkstra, G., Mass spectra of the tetramethyl and tetraethyl compounds of carbon, silicon, germanium, tin and lead, Rec. Trav. Chim., 1967, 86, 737. [all data]

Occolowitz, Lett. 1966
Occolowitz, J.L., Electron impact fragmentation of some organotin compounds, Tetrahedron, Lett. 1966, 5291. [all data]

Yergey and Lampe, 1965
Yergey, A.L.; Lampe, F.W., An electron impact study of the bond dissociation energies of some trimethyltin compounds, J. Am. Chem. Soc., 1965, 87, 4204. [all data]


Notes

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