Cl2O+

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   F
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 54380 ± 320 gas Cornford, Frost, et al., 1971

State:   E
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 46070 ± 320 gas Cornford, Frost, et al., 1971

State:   D
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 40020 ± 320 gas Cornford, Frost, et al., 1971

State:   C
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 14970 ± 70 gas Cornford, Frost, et al., 1971
Motte-Tollet, Delwiche, et al.
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1 Sym. stretch 613 ± 40 gas PE Motte-Tollet, Delwiche, et al.
2 Bend 306 T gas PE Motte-Tollet, Delwiche, et al.

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 12630 ± 70 U gas Cornford, Frost, et al., 1971
Motte-Tollet, Delwiche, et al.
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 2 Bend 282 ± 40 gas PE Motte-Tollet, Delwiche, et al.

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 9110 ± 70 gas Cornford, Frost, et al., 1971
Motte-Tollet, Delwiche, et al.
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 2 Bend 290 ± 40 gas PE Motte-Tollet, Delwiche, et al.

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1 Sym. stretch 678 ± 40 gas PE Cornford, Frost, et al., 1971
Motte-Tollet, Delwiche, et al.
2 Bend 274 ± 40 gas PE Cornford, Frost, et al., 1971
Motte-Tollet, Delwiche, et al.

Additional references: Jacox, 1994, page 111; Jacox, 2003, page 148; Wang, Lee, et al., 2000

Notes

UUpper bound
TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Cornford, Frost, et al., 1971
Cornford, A.B.; Frost, D.C.; Herring, F.G.; McDowell, C.A., Photoelectron spectra of F2O and Cl2O, J. Chem. Phys., 1971, 55, 2820. [all data]

Motte-Tollet, Delwiche, et al.
Motte-Tollet, F.; Delwiche, J.; Heinesch, J.; Hubin-Franskin, M.-J.; Gingell, J.M.; Jones, N.C.; Mason, N.J.; Marston, G., Chem. Phys. Lett. 284, 452.. [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Wang, Lee, et al., 2000
Wang, D.-C.; Lee, E.P.F.; Chau, F.-T.; Mok, D.K.W.; Dyke, J.M., The X, J. Phys. Chem. A, 2000, 104, 21, 4936, https://doi.org/10.1021/jp993931+ . [all data]

Notes

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