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Stibine, trimethyl-

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafgas32. ± 25.kJ/molReviewMartinho Simões 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafliquid1. ± 25.kJ/molReviewMartinho Simões 
Quantity Value Units Method Reference Comment
Deltacliquid-2921. ± 25.kJ/molCC-SBLong and Sackman, 1955Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltavap32.5 ± 0.01kJ/molN/AFulem, Moravek, et al., 2010Based on data from 249. - 296. K.; AC
Deltavap31.4 ± 1.3kJ/molCC-SBBamford, Levi, et al., 1946Please also see Long and Sackman, 1955, 2.; MS

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Stibine, trimethyl- (g) = C2H6Sb (g) + Methane (g)

By formula: C3H9Sb (g) = C2H6Sb (g) + CH4 (g)

Quantity Value Units Method Reference Comment
Deltar247. - 259.kJ/molN/ASmith and Patrick, 1983 
Deltar255. ± 17.kJ/molN/AMcMillen and Golden, 1982 

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
7.7PEElbel, Dieck, et al., 1982LBLHLM
8.04 ± 0.16EIWinters and Kiser, 1967RDSH
8.48PEElbel, Dieck, et al., 1982Vertical value; LBLHLM
8.48PEElbel, Bergmann, et al., 1974Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
CHSb+13.7 ± 0.4?EIWinters and Kiser, 1967RDSH
CH2Sb+15.1 ± 0.2?EIWinters and Kiser, 1967RDSH
CH3Sb+14.3 ± 0.2?EIWinters and Kiser, 1967RDSH
CH4Sb+13.4 ± 0.3?EIWinters and Kiser, 1967RDSH
C2H4Sb+12.6 ± 0.3?EIWinters and Kiser, 1967RDSH
C2H6Sb+10.5 ± 0.2CH3EIWinters and Kiser, 1967RDSH
SbH+14.5 ± 0.5?EIWinters and Kiser, 1967RDSH
SbH2+13.7 ± 0.2?EIWinters and Kiser, 1967RDSH
Sb+14.8 ± 0.4?EIWinters and Kiser, 1967RDSH

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
NIST MS number 6352

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References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Mass spectrum (electron ionization), NIST Free Links, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Long and Sackman, 1955
Long, L.H.; Sackman, J.F., The heat of formation of antimony trimethyl, Trans. Faraday Soc., 1955, 51, 1062, https://doi.org/10.1039/tf9555101062 . [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Fulem, Moravek, et al., 2010
Fulem, Michal; Moravek, Pavel; Pangrac, Jiri; Hulicius, Eduard; Simecek, Tomislav; Ruzicka, Kvetoslav; Ruzicka, Vlastimil; Kozyrkin, Boris; Shatunov, Valery, Vapor Pressure of Trimethylantimony and tert -Butyldimethylantimony, J. Chem. Eng. Data, 2010, 55, 1, 362-365, https://doi.org/10.1021/je900372v . [all data]

Bamford, Levi, et al., 1946
Bamford, C.H.; Levi, D.L.; Newitt, D.M., J. Chem. Soc., 1946, 468.. [all data]

Long and Sackman, 1955, 2
Long, L.H.; Sackman, J.F., Research (Correspondence), 1955, 8, 523. [all data]

Smith and Patrick, 1983
Smith, G.P.; Patrick, R., Int. J. Chem. Kinet., 1983, 15, 167. [all data]

McMillen and Golden, 1982
McMillen, D.F.; Golden, D.M., Hydrocarbon bond dissociation energies, Ann. Rev. Phys. Chem., 1982, 33, 493. [all data]

Elbel, Dieck, et al., 1982
Elbel, S.; Dieck, H.T.; Demuth, R., Photoelectron sSpectra of group V compounds. IX. The relative perfluoroalkyl substituent effect, J. Fluorine Chem., 1982, 19, 349. [all data]

Winters and Kiser, 1967
Winters, R.E.; Kiser, R.W., Ionization and fragmentation of dimethylzinc, trimethylaluminum, and trimethylantimony, J. Organometal. Chem., 1967, 10, 7. [all data]

Elbel, Bergmann, et al., 1974
Elbel, S.; Bergmann, H.; EnBlin, W., Photoelectron spectra of the trimethyl compounds of the Group V elements, J. Chem. Soc. Faraday Trans. 2., 1974, 70, 555. [all data]


Notes

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