Bismuthine, trimethyl-


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas194. ± 14.kJ/molReviewMartinho Simões 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfliquid158. ± 14.kJ/molReviewMartinho Simões 
Quantity Value Units Method Reference Comment
Δcliquid-2912. ± 14.kJ/molCC-SBLong and Sackman, 1954Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

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Individual Reactions

Bismuthine, trimethyl- (g) = C2H6Bi (g) + Methane (g)

By formula: C3H9Bi (g) = C2H6Bi (g) + CH4 (g)

Quantity Value Units Method Reference Comment
Δr209. - 222.kJ/molN/ASmith and Patrick, 1983 
Δr218. ± 17.kJ/molN/AMcMillen and Golden, 1982 

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Long and Sackman, 1954
Long, L.H.; Sackman, J.F., The heat of formation of bismuth trimethyl, Trans. Faraday Soc., 1954, 50, 1177, https://doi.org/10.1039/tf9545001177 . [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Smith and Patrick, 1983
Smith, G.P.; Patrick, R., Int. J. Chem. Kinet., 1983, 15, 167. [all data]

McMillen and Golden, 1982
McMillen, D.F.; Golden, D.M., Hydrocarbon bond dissociation energies, Ann. Rev. Phys. Chem., 1982, 33, 493. [all data]


Notes

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