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Bismuthine, trimethyl-


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafgas194. ± 14.kJ/molReviewMartinho Simões 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafliquid158. ± 14.kJ/molReviewMartinho Simões 
Quantity Value Units Method Reference Comment
Deltacliquid-2912. ± 14.kJ/molCC-SBLong and Sackman, 1954Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Deltavap36.0 ± 1.3kJ/molCC-SBAmberger, 1961MS
Deltavap35.8kJ/molN/AAmberger, 1961, 2Based on data from 215. - 380. K.; AC

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Bismuthine, trimethyl- (g) = C2H6Bi (g) + Methane (g)

By formula: C3H9Bi (g) = C2H6Bi (g) + CH4 (g)

Quantity Value Units Method Reference Comment
Deltar209. - 222.kJ/molN/ASmith and Patrick, 1983 
Deltar218. ± 17.kJ/molN/AMcMillen and Golden, 1982 

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
NIST MS number 12398

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References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Long and Sackman, 1954
Long, L.H.; Sackman, J.F., The heat of formation of bismuth trimethyl, Trans. Faraday Soc., 1954, 50, 1177, https://doi.org/10.1039/tf9545001177 . [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Amberger, 1961
Amberger, E., Chem. Ber., 1961, 94, 1447. [all data]

Amberger, 1961, 2
Amberger, Eberhard, Hydride des Wismuts, Chem. Ber., 1961, 94, 6, 1447-1452, https://doi.org/10.1002/cber.19610940607 . [all data]

Smith and Patrick, 1983
Smith, G.P.; Patrick, R., Int. J. Chem. Kinet., 1983, 15, 167. [all data]

McMillen and Golden, 1982
McMillen, D.F.; Golden, D.M., Hydrocarbon bond dissociation energies, Ann. Rev. Phys. Chem., 1982, 33, 493. [all data]


Notes

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