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Dimethyl selenide

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil331.KN/AGoldish, Hedberg, et al., 1955Uncertainty assigned by TRC = 3. K; TRC
Quantity Value Units Method Reference Comment
Ttriple185.14KN/ARabinovich, Sheiman, et al., 1991Uncertainty assigned by TRC = 0.01 K; TRC

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
30.3 ± 0.1295.N/ADykyj, Svoboda, et al., 1999Based on data from 280. - 318. K. See also Baev, 1997.; AC
31.9295.IKarlson, Frankenberger, et al., 1994Based on data from 278. - 313. K.; AC

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
8.499185.14Rabinovich, Sheiman, et al., 1991, 2DH
8.5185.1Rabinovich, Sheiman, et al., 1991, 3AC

Entropy of fusion

DeltafusS (J/mol*K) Temperature (K) Reference Comment
45.90185.14Rabinovich, Sheiman, et al., 1991, 2DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Goldish, Hedberg, et al., 1955
Goldish, E.; Hedberg, K.; Marsh, R.E.; Schomaker, V., An Electron Diffraction Investigation of Dimethyl Selenide, J. Am. Chem. Soc., 1955, 77, 2948-9. [all data]

Rabinovich, Sheiman, et al., 1991
Rabinovich, I.B.; Sheiman, M.S.; Kamelova, G.P.; Nistratov, V.P.; Karataev, E.N., Heat capacities and thermodynamic functions of methyl selenium compounds, Zh. Fiz. Khim., 1991, 65, 2071-6. [all data]

Dykyj, Svoboda, et al., 1999
Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.L.; Hall, K.R., Vapor Pressure of Chemicals: Part A. Vapor Pressure and Antoine Constants for Hydrocarbons and Sulfur, Selenium, Tellurium and Hydrogen Containing Organic Compounds, Springer, Berlin, 1999, 373. [all data]

Baev, 1997
Baev, A.K., Thermodynamic study of structural changes in solutions of dimethyl-zinc with methyl compounds of Group VIB elements, Zh. Neorg. Khim., 1997, 42, 4, 662. [all data]

Karlson, Frankenberger, et al., 1994
Karlson, U.; Frankenberger, W.T.; Spencer, W.F., Physicochemical properties of dimethyl selenide and dimethyl diselenide, J. Chem. Eng. Data, 1994, 39, 3, 608-610, https://doi.org/10.1021/je00015a049 . [all data]

Rabinovich, Sheiman, et al., 1991, 2
Rabinovich, I.B.; Sheiman, M.S.; Kamelova, G.P.; Nistrotov, V.P.; Karataev, E.N., Heat capacity and thermodynamic functions of methyl derivatives of selenium, Zhur. Fiz. Khim., 1991, 65, 2071-2076. [all data]

Rabinovich, Sheiman, et al., 1991, 3
Rabinovich, I.B.; Sheiman, M.S.; Kamelova, G.P.; Nistratov, V.P.; Karataev, E.N., Heat capacities and thermodynamic functions of methyl selenium compounds, Zh. Fiz. Khim., 1991, 65, 8, 2071. [all data]


Notes

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