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1-Heptene

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Hydrogen + 1-Heptene = Heptane

By formula: H2 + C7H14 = C7H16

Quantity Value Units Method Reference Comment
Deltar-29.8 ± 0.5kcal/molAVGN/AAverage of 6 values; Individual data points

2-Heptanol = 1-Heptene + Water

By formula: C7H16O = C7H14 + H2O

Quantity Value Units Method Reference Comment
Deltar7.98 ± 0.05kcal/molCmWiberg, Wasserman, et al., 1984liquid phase; Heat of hydration

3-Heptanol = 1-Heptene + Water

By formula: C7H16O = C7H14 + H2O

Quantity Value Units Method Reference Comment
Deltar7.94 ± 0.05kcal/molCmWiberg, Wasserman, et al., 1984liquid phase; Heat of hydration

4-Heptanol = 1-Heptene + Water

By formula: C7H16O = C7H14 + H2O

Quantity Value Units Method Reference Comment
Deltar7.84 ± 0.05kcal/molCmWiberg, Wasserman, et al., 1984liquid phase; Heat of hydration

1-Heptene + Bromine = C7H14Br2

By formula: C7H14 + Br2 = C7H14Br2

Quantity Value Units Method Reference Comment
Deltar-30.24kcal/molCmLister, 1941gas phase; Heat of bromination at 300 K

1-Heptene = 3-Heptene, (E)-

By formula: C7H14 = C7H14

Quantity Value Units Method Reference Comment
Deltar-2.60 ± 0.09kcal/molEqkKabo, Andreevskii, et al., 1967gas phase; Heat of isomerization

1-Heptene = 2-Heptene, (E)-

By formula: C7H14 = C7H14

Quantity Value Units Method Reference Comment
Deltar-2.39 ± 0.05kcal/molEqkKabo, Andreevskii, et al., 1967gas phase; Heat of isomerization

1-Heptene = (Z)-3-Heptene

By formula: C7H14 = C7H14

Quantity Value Units Method Reference Comment
Deltar-1.82 ± 0.26kcal/molEqkKabo, Andreevskii, et al., 1967gas phase; Heat of isomerization

1-Heptene = (Z)-2-Heptene

By formula: C7H14 = C7H14

Quantity Value Units Method Reference Comment
Deltar-1.82 ± 0.03kcal/molEqkKabo, Andreevskii, et al., 1967gas phase; Heat of isomerization

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wiberg, Wasserman, et al., 1984
Wiberg, K.B.; Wasserman, D.J.; Martin, E., Enthalpies of hydration of alkenes. 2. The n-heptenes and n-pentenes, J. Phys. Chem., 1984, 88, 3684-3688. [all data]

Lister, 1941
Lister, M.W., Heats of organic reactions. X. Heats of bromination of cyclic olefins, J. Am. Chem. Soc., 1941, 63, 143-149. [all data]

Kabo, Andreevskii, et al., 1967
Kabo, G.Ya.; Andreevskii, D.N.; Savinetskaya, G.A., Isomerization equilibrium of n-monochloroheptanes and n-heptenes, Neftekhimiya, 1967, 7, 364-368. [all data]


Notes

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