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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to C6H10+ (ion structure unspecified)

Ionization energy determinations

IE (eV) Method Reference Comment
8.48 ± 0.05EIFranklin and Mogenis, 1967RDSH
8.19PEWerstiuk, Clark, et al., 1990Vertical value; LL
8.09 ± 0.03PEHeilbronner, Hoshi, et al., 1976Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C3H3+14.92 ± 0.03?EIFranklin and Mogenis, 1967RDSH
C3H5+13.06 ± 0.02?EIFranklin and Mogenis, 1967RDSH
C4H2+23.6 ± 0.2?EIFranklin and Mogenis, 1967RDSH
C4H3+18.32 ± 0.04?EIFranklin and Mogenis, 1967RDSH
C4H4+15.41 ± 0.08?EIFranklin and Mogenis, 1967RDSH
C4H5+13.23 ± 0.05?EIFranklin and Mogenis, 1967RDSH
C4H6+11.53 ± 0.07?EIFranklin and Mogenis, 1967RDSH
C4H7+13.2 ± 0.1?EIFranklin and Mogenis, 1967RDSH
C5H5+13.79 ± 0.04?EIFranklin and Mogenis, 1967RDSH
C5H7+10.72 ± 0.05CH3EIFranklin and Mogenis, 1967RDSH
C6H7+13.42 ± 0.02H2+HEIFranklin and Mogenis, 1967RDSH
C6H9+10.95 ± 0.03HEIFranklin and Mogenis, 1967RDSH


Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Franklin and Mogenis, 1967
Franklin, J.L.; Mogenis, A., An electron impact study of ions from several dienes, J. Phys. Chem., 1967, 71, 2820. [all data]

Werstiuk, Clark, et al., 1990
Werstiuk, N.H.; Clark, K.B.; Leigh, W.J., Conformational analysis and structure elucidation of 2,3-dimethyl and 2,4-dimethyl-2,4-hexadienes by AM1 and He(I) ultraviolet photoelectron spectroscopy, Can. J. Chem., 1990, 68, 2078. [all data]

Heilbronner, Hoshi, et al., 1976
Heilbronner, E.; Hoshi, T.; von Rosenberg, J.L.; Hafner, K., Alkyl-induced, natural hypsochromic shifts of the 2A←2X and 2B←2X transitions of azulene and naphthalene radical cations, Nouv. J. Chim., 1976, 1, 105. [all data]


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