1-Hexene

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Normal alkane RI, non-polar column, temperature ramp

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Polydimethyl siloxane: CP-Sil 5 CBPetrocol DHUltra-ALLOY-5Ultra-ALLOY-5Ultra-ALLOY-5
Column length (m) 60.100.30.30.30.
Carrier gas HeliumHelium   
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 1.00.500.250.250.25
Tstart (C) 45.20.40.40.40.
Tend (C) 210.220.320.320.320.
Heat rate (K/min) 3.615.20.20.20.
Initial hold (min) 1.4515.2.2.2.
Final hold (min) 2.7230.13.13.13.
I 589.589.583.585.585.
ReferenceBramston-Cook, 2013Supelco, 2012Tsuge, Ohtan, et al., 2011Tsuge, Ohtan, et al., 2011Tsuge, Ohtan, et al., 2011
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Ultra-ALLOY-5Ultra-ALLOY-5PONAPetrocol DHDB-5MS
Column length (m) 30.30.50.150.30.
Carrier gas   Nitrogen He
Substrate      
Column diameter (mm) 0.250.250.200.250.25
Phase thickness (μm) 0.250.250.501.00.25
Tstart (C) 40.40.35.40.40.
Tend (C) 320.320.200.300.250.
Heat rate (K/min) 20.20.2.1.3.
Initial hold (min) 2.2.15. 1.
Final hold (min) 13.13.10.  
I 592.593.585.585.584.7
ReferenceTsuge, Ohtan, et al., 2011Tsuge, Ohtan, et al., 2011Zhang, Ding, et al., 2009Sojak, Kubinec, et al., 2006Shoenmakers, Oomen, et al., 2000
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Methyl SiliconeOV-101OV-101SE-54HP-5
Column length (m) 60.50.52.50. 
Carrier gas  HeliumN2  
Substrate      
Column diameter (mm) 0.250.200.260.32 
Phase thickness (μm) 0.250.50   
Tstart (C) 40.30.50.60.35.
Tend (C) 220.100.220.200.200.
Heat rate (K/min) 5.1.3.4.6.
Initial hold (min) 10.6. 2.2.
Final hold (min)      
I 585.32589.587.584.590.
ReferenceBaraldi, Rapparini, et al., 1999Orav, Kailas, et al., 1999Chupalov and Zenkevich, 1996Guan, Li, et al., 1995Larsen and Frisvad, 1995
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5DB-1DB-1OV-101OV-101
Column length (m)  50.60.50.50.
Carrier gas  HeHeNitrogenNitrogen
Substrate      
Column diameter (mm)  0.320.320.250.25
Phase thickness (μm)  1.01.2  
Tstart (C) 35.-20.30.70.80.
Tend (C) 200. 240.200.200.
Heat rate (K/min) 6.2.3.2.2.
Initial hold (min) 2. 10.  
Final hold (min)      
I 591.588.585.590.592.
ReferenceLarsen and Frisvad, 1995, 2Ramnas, Ostermark, et al., 1994Ciccioli, Cecinato, et al., 1992Sugisawa, Nakamura, et al., 1990Sugisawa, Nakamura, et al., 1990
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type Capillary
Active phase SP-2100
Column length (m) 30.
Carrier gas He
Substrate  
Column diameter (mm) 0.25
Phase thickness (μm)  
Tstart (C) 40.
Tend (C) 250.
Heat rate (K/min) 4.
Initial hold (min)  
Final hold (min)  
I 584.
ReferenceAlencar, Alves, et al., 1983
Comment MSDC-RI

References

Go To: Top, Normal alkane RI, non-polar column, temperature ramp, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bramston-Cook, 2013
Bramston-Cook, R., Kovats indices for C2-C13 hydrocarbons and selected oxygenated/halocarbons with 100 % dimethylpolysiloxane columns, 2013, retrieved from http://lotusinstruments.com/monographs/List .... [all data]

Supelco, 2012
Supelco, CatalogNo. 24160-U, Petrocol DH Columns. Catalog No. 24160-U, 2012, retrieved from http://www.sigmaaldrich.com/etc/medialib/docs/Supelco/Datasheet/1/w97949.Par.0001.File.tmp/w97949.pdf. [all data]

Tsuge, Ohtan, et al., 2011
Tsuge, S.; Ohtan, H.; Watanabe, C., Pyrolysis - GC/MS Data Book of Synthetic Polymers, Elsevier, 2011, 420. [all data]

Zhang, Ding, et al., 2009
Zhang, X.; Ding, L.; Sun, Z.; Song, L.; Sun, T., Study on quantitative structure-retention relationships for hydrocarbons in FCC gasoline, Chromatographia, 2009, 70, 3/4, 511-518, https://doi.org/10.1365/s10337-009-1174-0 . [all data]

Sojak, Kubinec, et al., 2006
Sojak, L.; Kubinec, R.; Jurdakova, H.; Hajekova, E.; Bajus, M., GC-MS of polyethylene and polypropylene thermal cracking produxts, Petroleum Coal, 2006, 48, 1, 1-14. [all data]

Shoenmakers, Oomen, et al., 2000
Shoenmakers, P.J.; Oomen, J.L.M.M.; Blomberg, J.; Genuit, W.; van Velzen, G., Comparison of comprehensive two-dimensional gas chromatography and gas chromatography-mass spectrometry for the characterization of complex hydrocarbon mixtures, J. Chromatogr. A, 2000, 892, 1-2, 29-46, https://doi.org/10.1016/S0021-9673(00)00744-5 . [all data]

Baraldi, Rapparini, et al., 1999
Baraldi, R.; Rapparini, F.; Rossi, F.; Latella, A.; Ciccioli, P., Volatile organic compound emissions from flowers of the most occurring and economically important species of fruit trees, Phys. Chem. Earth, 1999, 24, 6, 729-732, https://doi.org/10.1016/S1464-1909(99)00073-8 . [all data]

Orav, Kailas, et al., 1999
Orav, A.; Kailas, T.; Muurisepp, M.; Kann, J., Composition of the oil from waste tires. 1. Fraction boiling at yp to 160 0C, Proc. Estonian Acad. Sci. Chem., 1999, 48, 1, 30-39. [all data]

Chupalov and Zenkevich, 1996
Chupalov, A.A.; Zenkevich, I.G., Chromatographic Characterization of Structural Transformations of Organic Compounds in Diels-Alder Reaction. Aliphatic Dienes and Dienophyls, Zh. Org. Khim., 1996, 32, 6, 675-684. [all data]

Guan, Li, et al., 1995
Guan, Y.; Li, L.; Zhou, L., Live retention database for compound identification in capillary gas chromatography, Chin. J. Chromatogr., 1995, 13, 5, 851-857. [all data]

Larsen and Frisvad, 1995
Larsen, T.O.; Frisvad, J.C., Characterization of volatile metabolites from 47 Penicillium taxa, Mycol. Res., 1995, 99, 10, 1153-1166, https://doi.org/10.1016/S0953-7562(09)80271-2 . [all data]

Larsen and Frisvad, 1995, 2
Larsen, T.O.; Frisvad, J.C., Comparison of different methods for collection of volatile chemical markers from fungi, J. Microbiol. Methods, 1995, 24, 2, 135-144, https://doi.org/10.1016/0167-7012(95)00063-1 . [all data]

Ramnas, Ostermark, et al., 1994
Ramnas, O.; Ostermark, U.; Peterson, G., Characterization of sixty alkenes in a cat-cracked gasoline naphtha by gas chromatography, Chromatographia, 1994, 38, 3/4, 222-226, https://doi.org/10.1007/BF02290340 . [all data]

Ciccioli, Cecinato, et al., 1992
Ciccioli, P.; Cecinato, A.; Brancaleoni, E.; Frattoni, M.; Liberti, A., Use of carbon adsorption traps combined with high resolution gas chromatography - mass spectrometry for the analysis of polar and non-polar C4-C14 hydrocarbons involved in photochemical smog formation, J. Hi. Res. Chromatogr., 1992, 15, 2, 75-84, https://doi.org/10.1002/jhrc.1240150205 . [all data]

Sugisawa, Nakamura, et al., 1990
Sugisawa, H.; Nakamura, K.; Tamura, H., The aroma profile of the volatile in marine green algae (Ulva pertusa), Food Reviews International, 1990, 6, 4, 573-589, https://doi.org/10.1080/87559129009540893 . [all data]

Alencar, Alves, et al., 1983
Alencar, J.W.; Alves, P.B.; Craveiro, A.A., Pyrolysis of tropical vegetable oils, J. Agric. Food Chem., 1983, 31, 6, 1268-1270, https://doi.org/10.1021/jf00120a031 . [all data]


Notes

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