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1,2-Pentadiene

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil318.1KN/AAnonymous, 1959Uncertainty assigned by TRC = 0.4 K; TRC
Tboil319.KN/AJacobs, Akawie, et al., 1951Uncertainty assigned by TRC = 2. K; TRC
Tboil318.KN/ABouis, 1928Uncertainty assigned by TRC = 1. K; TRC
Quantity Value Units Method Reference Comment
Tfus135.880KN/AAnonymous, 1959Uncertainty assigned by TRC = 0.03 K; TRC
Tfus135.870KN/AAnonymous, 1959Uncertainty assigned by TRC = 0.04 K; TRC
Tfus135.890KN/AAnonymous, 1959Uncertainty assigned by TRC = 0.02 K; TRC
Tfus135.840KN/AStreiff, Soule, et al., 1950Uncertainty assigned by TRC = 0.03 K; TRC
Tfus135.820KN/AStreiff, Soule, et al., 1950Uncertainty assigned by TRC = 0.04 K; TRC
Quantity Value Units Method Reference Comment
Ttriple135.89KN/AMesserly, Todd, et al., 1970Uncertainty assigned by TRC = 0.05 K; TRC
Quantity Value Units Method Reference Comment
Deltavap6.86kcal/molN/AReid, 1972AC

Enthalpy of vaporization

DeltavapH (kcal/mol) Temperature (K) Method Reference Comment
7.55240.AStephenson and Malanowski, 1987Based on data from 231. - 249. K.; AC
7.31264.AStephenson and Malanowski, 1987Based on data from 249. - 331. K.; AC
7.70231.IPOsborn and Douslin, 1969Based on data from 213. - 245. K.; AC
6.96300.MMForziati, Camin, et al., 1950Based on data from 285. - 319. K.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
213.14 - 244.664.055511125.536-41.27Osborn and Douslin, 1969Coefficents calculated by NIST from author's data.

Enthalpy of fusion

DeltafusH (kcal/mol) Temperature (K) Reference Comment
1.8067135.89Messerly, Todd, et al., 1970, 2DH
1.81135.9Domalski and Hearing, 1996AC

Entropy of fusion

DeltafusS (cal/mol*K) Temperature (K) Reference Comment
13.295135.89Messerly, Todd, et al., 1970, 2DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Anonymous, 1959
Anonymous, R., , Am. Pet. Inst. Res. Proj. 6, Carnegie-Mellon Univ., 1959. [all data]

Jacobs, Akawie, et al., 1951
Jacobs; Akawie; Copper, Rearrangements Involving 1-Pentyne, 2-Pentyne and 1,2-Pentadiene, J. Am. Chem. Soc., 1951, 73, 1273. [all data]

Bouis, 1928
Bouis, M., Ann. Chim. (Paris), 1928, 9, 402. [all data]

Streiff, Soule, et al., 1950
Streiff, A.J.; Soule, L.F.; Kennedy, C.M.; Janes, M.E.; Sedlak, V.A.; Willingham, C.B.; Rossini, F.D., Purification, purity, and freezing points of twenty-nine hydrocarbons of the API-standard and API-NBS series., J. Res. Natl. Bur. Stand. (U. S.), 1950, 45, 173. [all data]

Messerly, Todd, et al., 1970
Messerly, J.F.; Todd, S.S.; Guthrie, G.B., Chemical thermodynamic properties of the pentadienes. Third law studies., J. Chem. Eng. Data, 1970, 15, 227-32. [all data]

Reid, 1972
Reid, Robert C., Handbook on vapor pressure and heats of vaporization of hydrocarbons and related compounds, R. C. Wilhort and B. J. Zwolinski, Texas A Research Foundation. College Station, Texas(1971). 329 pages.$10.00, AIChE J., 1972, 18, 6, 1278-1278, https://doi.org/10.1002/aic.690180637 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Osborn and Douslin, 1969
Osborn, Ann G.; Douslin, Donald R., Vapor pressure relations for the seven pentadienes, J. Chem. Eng. Data, 1969, 14, 2, 208-209, https://doi.org/10.1021/je60041a010 . [all data]

Forziati, Camin, et al., 1950
Forziati, A.F.; Camin, D.L.; Rossini, F.D., Density, refractive index, boiling point, and vapor pressure of eight monoolefin (1-alkene), six pentadiene, and two cyclomonoolefin hydrocarbons, J. RES. NATL. BUR. STAN., 1950, 45, 5, 406, https://doi.org/10.6028/jres.045.044 . [all data]

Messerly, Todd, et al., 1970, 2
Messerly, J.F.; Todd, S.S.; Guthrie, G.B., Chemical thermodynamic properties of the pentadienes, J. Chem. Eng. Data, 1970, 15, 227-232. [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]


Notes

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