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Acetamide, N-(aminocarbonyl)-

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
10.3PEDougherty, Wittel, et al., 1976Vertical value; LLK

De-protonation reactions

C3H5N2O2- + Hydrogen cation = Acetamide, N-(aminocarbonyl)-

By formula: C3H5N2O2- + H+ = C3H6N2O2

Quantity Value Units Method Reference Comment
Deltar348.5 ± 2.9kcal/molG+TSCumming and Kebarle, 1978gas phase; Acid: acetylurea; B
Quantity Value Units Method Reference Comment
Deltar341.1 ± 2.0kcal/molIMRECumming and Kebarle, 1978gas phase; Acid: acetylurea; B

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Dougherty, Wittel, et al., 1976
Dougherty, D.; Wittel, K.; Meeks, J.; McGlynn, S.P., Photoelectron spectroscopy of carbonyls. Ureas, uracils, and thymine, J. Am. Chem. Soc., 1976, 98, 3815. [all data]

Cumming and Kebarle, 1978
Cumming, J.B.; Kebarle, P., Summary of gas phase measurements involving acids AH. Entropy changes in proton transfer reactions involving negative ions. Bond dissociation energies D(A-H) and electron affinities EA(A), Can. J. Chem., 1978, 56, 1. [all data]


Notes

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