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Cyclohexanol, 1-methyl-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil428.2KN/AWeast and Grasselli, 1989BS
Tboil438.65KN/AWalling and Padwa, 1963Uncertainty assigned by TRC = 1.5 K; TRC
Tboil427.15KN/AZeiss and Tsutsui, 1953Uncertainty assigned by TRC = 2. K; TRC
Quantity Value Units Method Reference Comment
Tfus299.1KN/APlate, Liberman, et al., 1953Uncertainty assigned by TRC = 2. K; TRC
Tfus297.9KN/AZeiss and Tsutsui, 1953Uncertainty assigned by TRC = 1.5 K; TRC
Quantity Value Units Method Reference Comment
Ttriple299.40KN/AKabo, Kozyro, et al., 1999Uncertainty assigned by TRC = 0.15 K; TRC

Reduced pressure boiling point

Tboil (K) Pressure (bar) Reference Comment
441.21.00Aldrich Chemical Company Inc., 1990BS

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
49.1355.AStephenson and Malanowski, 1987Based on data from 340. - 430. K.; AC

Enthalpy of sublimation

DeltasubH (kJ/mol) Temperature (K) Method Reference Comment
75.9 ± 0.4291.CKabo, Blokhin, et al., 1998AC

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
14.32299.4Kabo, Blokhin, et al., 1998AC
10.87299.2Wiberg, Wasserman, et al., 1985AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Walling and Padwa, 1963
Walling, C.; Padwa, A., Positive Halogen Compounds VI. Effects of Structure and Medium on the «beta»-Scission of Alkoxy Radicals, J. Am. Chem. Soc., 1963, 85, 1593. [all data]

Zeiss and Tsutsui, 1953
Zeiss, H.H.; Tsutsui, M., The Carbon-Oxygen Absorption Band in the Infrared Spectra of Alcohols, J. Am. Chem. Soc., 1953, 75, 897. [all data]

Plate, Liberman, et al., 1953
Plate, A.F.; Liberman, A.L.; Momma, N.A., Preparation of 1,2-Dialkylcycloanes. Synthesis of Stereoisomeric 1-Methyl-2-butylcyclopentanes, Izv. Akad. Nauk SSSR, 1953, 1953, 689. [all data]

Kabo, Kozyro, et al., 1999
Kabo, G.J. (see Kabo; Kozyro, A.A.; Frenkel, M. (see frenke ml); Blokhin, A.V., Solid Phase Transitions of the Cyclohexane Derivatives and the Model of Energy States of Molecules in Plastic Crystals, Mol. Cryst. Liq. Cryst., 1999, 326, 333-5. [all data]

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Kabo, Blokhin, et al., 1998
Kabo, G.J.; Blokhin, A.V.; Kozyro, A.A.; Diky, V.V.; Ivashkevich, L.S.; Krasulin, A.P.; Sevruk, V.M.; Frenkel, Michael, Thermodynamic properties and phase transitions of 1-methylcyclohexanol and 1-chloro-1-methylcyclohexane, Thermochimica Acta, 1998, 313, 2, 111-124, https://doi.org/10.1016/S0040-6031(97)00481-4 . [all data]

Wiberg, Wasserman, et al., 1985
Wiberg, K.B.; Wasserman, D.J.; Martin, E.J.; Murcko, M.A., Enthalpies of hydration of alkenes. 3. Cycloalkenes, J. Am. Chem. Soc., 1985, 107, 6019-6022. [all data]


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