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1,2-Butadiene

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Tboil284.KN/AMajer and Svoboda, 1985 
Tboil291.7KN/AFeugeas and Giusti, 1968Uncertainty assigned by TRC = 2. K; TRC
Tboil284.06KN/AStreiff, Murphy, et al., 1946Uncertainty assigned by TRC = 0.3 K; TRC
Tboil283.5KN/AHurd and Meinert, 1931Uncertainty assigned by TRC = 0.5 K; TRC
Quantity Value Units Method Reference Comment
Tfus136.940KN/AStreiff, Murphy, et al., 1947Uncertainty assigned by TRC = 0.05 K; TRC
Tfus136.960KN/AStreiff, Murphy, et al., 1947Uncertainty assigned by TRC = 0.02 K; TRC
Quantity Value Units Method Reference Comment
Ttriple136.920KN/AAston and Szasz, 1947Uncertainty assigned by TRC = 0.06 K; TRC
Ttriple136.950KN/AAston and Szasz, 1947Uncertainty assigned by TRC = 0.05 K; TRC
Ttriple136.94KN/ATooke and Aston, 1945Uncertainty assigned by TRC = 0.08 K; TRC
Quantity Value Units Method Reference Comment
Deltavap23.68kJ/molN/AMajer and Svoboda, 1985 
Deltavap23.9kJ/molN/AReid, 1972AC

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
24.623273.24N/AAston and Szasz, 1947, 2P = 66.41 kPa; DH
24.02284.N/AMajer and Svoboda, 1985 
25.3276.AStephenson and Malanowski, 1987Based on data from 243. - 291. K.; AC
26.4228.AStephenson and Malanowski, 1987Based on data from 204. - 243. K.; AC
24.6 ± 0.3273.25CAston and Szasz, 1947, 3ALS
24.6 ± 0.1273.CAston and Szasz, 1947, 2AC
25.2276.N/AStull, 1947Based on data from 184. - 291. K.; AC

Entropy of vaporization

DeltavapS (J/mol*K) Temperature (K) Reference Comment
90.11273.24Aston and Szasz, 1947, 2P; DH

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
184. - 291.73.78159941.601-42.565Stull, 1947Coefficents calculated by NIST from author's data.

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
6.9613136.92Aston and Szasz, 1947, 2DH
6.95136.9Domalski and Hearing, 1996AC

Entropy of fusion

DeltafusS (J/mol*K) Temperature (K) Reference Comment
50.84136.92Aston and Szasz, 1947, 2DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Feugeas and Giusti, 1968
Feugeas, C.; Giusti, G.L., C. R. Acad. Sci. Paris, Ser. C, 1968, 267, 84. [all data]

Streiff, Murphy, et al., 1946
Streiff, A.J.; Murphy, E.T.; Cahill, J.C.; Soule, L.F.; Sedlak, V.A.; Willingham, C.B.; Rossini, F.D., , Am. Pet. Inst. Res. Proj. 6, unpublished, Natl. Bur. Stand., 1946. [all data]

Hurd and Meinert, 1931
Hurd, C.D.; Meinert, R.N., Synthesis and pyrolysis of methylallene and ethylacetylene, J. Am. Chem. Soc., 1931, 53, 289-300. [all data]

Streiff, Murphy, et al., 1947
Streiff, A.J.; Murphy, E.T.; Zimmerman, J.C.; Soule, L.F.; Sedlak, V.A.; Willingham, C.B.; Rossini, F.D., Purification, purity, and freezing points of n-decane, 4 alkylcyclopentanes 9 alkylcyclohexanes, 2 monoolefins, 1,2-butadiene, and 2-butyne of the API-standard and API-NBS series., J. Res. Natl. Bur. Stand. (U. S.), 1947, 39, 321. [all data]

Aston and Szasz, 1947
Aston, J.G.; Szasz, G.J., The Thermodynamics of Butadiene-1,2 from Calorimetric and Spectroscopic Data, J. Am. Chem. Soc., 1947, 69, 3108. [all data]

Tooke and Aston, 1945
Tooke, J.W.; Aston, J.G., Solid Solutions in Hydrocarbon Systems, J. Am. Chem. Soc., 1945, 67, 2275. [all data]

Reid, 1972
Reid, Robert C., Handbook on vapor pressure and heats of vaporization of hydrocarbons and related compounds, R. C. Wilhort and B. J. Zwolinski, Texas A Research Foundation. College Station, Texas(1971). 329 pages.$10.00, AIChE J., 1972, 18, 6, 1278-1278, https://doi.org/10.1002/aic.690180637 . [all data]

Aston and Szasz, 1947, 2
Aston, J.G.; Szasz, G.J., The thermodynamics of butadiene-1,2 from calorimetric and spectroscopic data, J. Am. Chem. Soc., 1947, 69, 3108-3114. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Aston and Szasz, 1947, 3
Aston, J.G.; Szasz, G.J., The thermodynamics of butadiene-1,2 from calorimetric and spectroscopic data, J. Am. Chem. Soc., 1947, 69, 3108-31. [all data]

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]


Notes

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