H2CCl+


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 CH2 s-stretch 2987.3 w m Ar IR Ma, Chen, et al., 2009
3 CCl stretch 1040 ± 30 gas PE Andrews, Dyke, et al., 1983
Andrews, Dyke, et al., 1984
3 CCl stretch 1037.6 vs Ar IR Ma, Chen, et al., 2009
b1 4 CH2 wag 1110.2 w m Ar IR Ma, Chen, et al., 2009
b2 5 CH2 a-stretch 3109.3 m s Ar IR Ma, Chen, et al., 2009

Additional references: Jacox, 1994, page 147

Notes

wWeak
mMedium
sStrong
vsVery strong

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ma, Chen, et al., 2009
Ma, R.; Chen, M.; Zhou, M., Infrared Spectra of the Chloromethyl and Bromomethyl Cations in Solid Argon, J. Phys. Chem. A, 2009, 113, 46, 12926, https://doi.org/10.1021/jp9084266 . [all data]

Andrews, Dyke, et al., 1983
Andrews, L.; Dyke, J.M.; Jonathan, N.; Keddar, N.; Morris, A.; Ridha, A., The first band in the He(I) photoelectron spectrum of the CH2Cl free radical, Chem. Phys. Lett., 1983, 97, 1, 89, https://doi.org/10.1016/0009-2614(83)87190-5 . [all data]

Andrews, Dyke, et al., 1984
Andrews, L.; Dyke, J.M.; Jonathan, N.; Keddar, N.; Morris, A., Photoelectron spectroscopic study of the ground states of CH2Cl+, CHCl2+, and CHFCl+, J. Am. Chem. Soc., 1984, 106, 299. [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]


Notes

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