3-Hexanone

• Formula: C₆H₁₂O
• Molecular weight: 100.1589
• IUPAC Standard InChI: InChI=1S/C6H12O/c1-3-5-6(7)4-2/h3-5H2,1-2H3 Copy

  
• IUPAC Standard InChIKey: PFCHFHIRKBAQGU-UHFFFAOYSA-N Copy
• CAS Registry Number: 589-38-8
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Other names: Ethyl propyl ketone; Hexan-3-one; n-C3H7COC2H5; Hexanone-(3); Aethylpropylketon; Ethyl n-propyl ketone
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• Information on this page:
  • Normal boiling point
  • References
  • Notes
• Other data available:
  • Gas phase thermochemistry data
  • Condensed phase thermochemistry data
  • Phase change data
  • Reaction thermochemistry data
  • Gas phase ion energetics data
  • Ion clustering data
  • IR Spectrum
  • Mass spectrum (electron ionization)
  • Gas Chromatography
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Normal boiling point

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Collerson, Counsell, et al., 1965
Collerson, R.R.; Counsell, J.F.; Handley, R.; Martin, J.F.; Sprake, C.H.S., 677. Thermodynamic properties of organic oxygen compounds. Part XV. Purification and vapour pressures of some ketones and ethers, J. Chem. Soc., 1965, 3697, https://doi.org/10.1039/jr9650003697 . [all data]

Shuikin, Karakhanov, et al., 1965
Shuikin, N.I.; Karakhanov, R.A.; Ibrakhimov, I., Conversion of Tetrahydrofuran Homologs on Paladized Carbon, Izv. Akad. Nauk SSSR, Ser. Khim., 1965, 1965, No. 1, 165-7. [all data]

Smith, 1960
Smith, R.F., J. Org. Chem., 1960, 25, 453-54. [all data]

Rabjohn, Phillips, et al., 1959
Rabjohn, N.; Phillips, L.V.; DeFeo, R.J., J. Org. Chem., 1959, 24, 1964. [all data]

Shuikin and Bel'skii, 1956
Shuikin, N.I.; Bel'skii, I.F., Hydrogenation and Hydrogenolysis of alpha-Ethyl and alpha-Propenyl- furan on Raney Nickel Catalyst, J. Gen. Chem. USSR (Engl. Transl.), 1956, 26, 3025. [all data]

Cook, 1952
Cook, N.C., , Unpublished, Final Rep. Stand. Proj. on Oxygenated Compounds, Penn. State Univ., College Park, PA, 1952. [all data]

Lecat, 1949
Lecat, M., Tables Azeotropiques, Vol. 1, 10th ed., Brussels, Belgium, 1949. [all data]

Schuerch and Huntress, 1949
Schuerch, C.; Huntress, E.H., The Schmidt Reaction II. A New Rearangement Obseved during Degradation of Triethylacetic Acid, J. Am. Chem. Soc., 1949, 71, 2238. [all data]

Lecat, 1947
Lecat, M., Orthobaric Azeotropes of Sulfides, Bull. Cl. Sci., Acad. R. Belg., 1947, 33, 160-82. [all data]

Lecat, 1947, 2
Lecat, M., Some azeotropes of which one constituant is heterocyclic nitrogen, Ann. Soc. Sci. Bruxelles, Ser. 1, 1947, 61, 73. [all data]

Paul, 1941
Paul, R., Bull. Soc. Chim. Fr., 1941, 8, 507. [all data]

Cowan, Jeffery, et al., 1940
Cowan, D.M.; Jeffery, G.H.; Vogel, A.I., Physical Properties and Chemical Constitution. V. Alkyl Ketones., J. Chem. Soc., 1940, 1940, 171. [all data]

Ginnings, Plonk, et al., 1940
Ginnings, P.M.; Plonk, D.; Carter, E., Aqueous Solubilities of Some Aliphatic Ketones, J. Am. Chem. Soc., 1940, 62, 1923-1924. [all data]

Montagne, 1930
Montagne, M., Ann. Chim. (Paris), 1930, 13, 40. [all data]

Suida and Poll, 1927
Suida, H.; Poll, Angew. Chem., 1927, 40, 505. [all data]

Baerts, 1922
Baerts, F., Action of organomagnesium compounds on nitriles n-butyronitrile, Bull. Soc. Chim. Belg., 1922, 31, 421. [all data]

Michael, 1919
Michael, A., J. Am. Chem. Soc., 1919, 41, 393. [all data]

Pickard and Kenyon, 1913
Pickard, R.H.; Kenyon, J., Investigations on the dependence of rotatory power on chemical constitution: IV the rotations of the normal secondary alcohols of the formula c(2)h(5).ch(oh).r, J. Chem. Soc., 1913, 103, 1923-59. [all data]

De Cininck, 1876
De Cininck, M.W.O., A secondary hexyl alcohol, Bull. Soc. Chim. Fr., 1876, 25, 7. [all data]

Lieben, 1875
Lieben, A., Mitheilungen aus dem universitatslaboatorium zu wein, Chem. Ber., 1875, 8, 1017. [all data]

Notes

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• Symbols used in this document:
  

  Tboil

  Boiling point

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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