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Hexane, 3-methyl-

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Normal boiling point

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director

Tboil (K) Reference Comment
364.2Aldrich Chemical Company Inc., 1990BS; Data excluded from overall average
365.Majer and Svoboda, 1985 
364.7Petrov, Sergienko, et al., 1958Uncertainty assigned by TRC = 0.5 K; TRC
365.Desty and Whyman, 1957Uncertainty assigned by TRC = 0.3 K; TRC
365.05Roebuck and Evering, 1953Uncertainty assigned by TRC = 0.3 K; TRC
365.05Heller, 1952Uncertainty assigned by TRC = 0.5 K; TRC
365.03Boord, Henne, et al., 1949Uncertainty assigned by TRC = 0.3 K; TRC
364.75Buck, Elsner, et al., 1949Uncertainty assigned by TRC = 0.5 K; TRC
364.75Denyer, Fidler, et al., 1949Uncertainty assigned by TRC = 0.3 K; TRC
365.0000Forziati and Rossini, 1949Uncertainty assigned by TRC = 0.2 K; TRC
365.15Lecat, 1949Uncertainty assigned by TRC = 0.5 K; TRC
365.Rossini, Mair, et al., 1949Uncertainty assigned by TRC = 0.2 K; TRC
365.2Rossini, 1948Uncertainty assigned by TRC = 0.5 K; TRC
365.04Boord, Greenlee, et al., 1947Uncertainty assigned by TRC = 0.2 K; TRC
365.0Brescia, 1947Uncertainty assigned by TRC = 0.2 K; TRC
365.Fenske, Braun, et al., 1947Uncertainty assigned by TRC = 0.15 K; TRC
363.65Shikheev, 1946Uncertainty assigned by TRC = 3. K; TRC; Data excluded from overall average
365.3Grummitt, Sensel, et al., 1945Uncertainty assigned by TRC = 1.5 K; TRC
365.15Appleby, Dobratz, et al., 1944Uncertainty assigned by TRC = 0.5 K; TRC
365.1Forziati, Willingham, et al., 1944Uncertainty assigned by TRC = 0.06 K; TRC
364.75Anonymous, 1943Uncertainty assigned by TRC = 0.3 K; TRC
365.2Rossini, 1943Uncertainty assigned by TRC = 0.5 K; TRC
365.11Davies and Gilbert, 1941Uncertainty assigned by TRC = 0.3 K; TRC
365.15Henne, Chanan, et al., 1941Uncertainty assigned by TRC = 0.5 K; TRC
364.95Koch and Hilberath, 1941Uncertainty assigned by TRC = 0.5 K; TRC
365.11Glasgow, 1940Uncertainty assigned by TRC = 0.2 K; TRC
364.75Beltz, 1939Uncertainty assigned by TRC = 0.5 K; TRC
365.03Wojciechowski, 1939Uncertainty assigned by TRC = 0.2 K; TRC
364.95Hoog, Smittenberg, et al., 1937Uncertainty assigned by TRC = 0.6 K; from Egloff, Vol. 1, 1939; TRC
365.15Leslie and White, 1935Uncertainty assigned by TRC = 0.5 K; TRC
365.15Rossini, 1935Uncertainty assigned by TRC = 0.5 K; TRC
362.5Soday and Boord, 1933Uncertainty assigned by TRC = 2. K; boiling point given corresponds to that for 2,3-dimethylpentane; TRC; Data excluded from overall average
364.95McKee and Szayna, 1930Uncertainty assigned by TRC = 0.5 K; TRC
364.95Edgar, Calingaert, et al., 1929Uncertainty assigned by TRC = 0.5 K; TRC
364.95Edgar and Calingaert, 1929Uncertainty assigned by TRC = 0.5 K; TRC
364.95Timmermans, 1927Uncertainty assigned by TRC = 0.5 K; source of data not clear; TRC
364.95De Graef, 1925Uncertainty assigned by TRC = 0.3 K; TRC
363.65Timmermans, 1921Uncertainty assigned by TRC = 0.7 K; TRC; Data excluded from overall average

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Normal boiling point, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Petrov, Sergienko, et al., 1958
Petrov, A.A.; Sergienko, S.R.; Tsedlina, A.L.; Teterina, M.P.; Kislinskii, A.N.; Gal'pern, G.D., Isomerization of Saturated Hydrocarbons Communication 1. Isomerization of C6-C8 Parafins, Izv. Akad. Nauk SSSR Ser. Khim., 1958, 1958, 419-26. [all data]

Desty and Whyman, 1957
Desty, D.H.; Whyman, B.H.F., Anal. Chem., 1957, 29, 320. [all data]

Roebuck and Evering, 1953
Roebuck, A.K.; Evering, B.L., Sulfuric Acid Isomerization of Methylalkanes, Dimethylalkanes, and Dimethylcyclohexanes, J. Am. Chem. Soc., 1953, 75, 1631. [all data]

Heller, 1952
Heller, H.E., The Racemization of d(+)-3-Methylhexane, J. Am. Chem. Soc., 1952, 74, 4858. [all data]

Boord, Henne, et al., 1949
Boord, C.E.; Henne, A.L.; Greenlee, K.W.; Perilstein, W.L.; Derfer, J.M., The Grignard Reagent in hydrocarbon synthesis, Ind. Eng. Chem., 1949, 41, 609. [all data]

Buck, Elsner, et al., 1949
Buck, F.R.; Elsner, B.B.; Henshall, T.; Moore, T.S.; Murray, A.R.; Morrell, S.H.; Muller, G.; Plant, M.M.T.; Smith, J.C.; Wallsgrove, E.R., Hydrocarbon synthesis., J. Inst. Pet., 1949, 35, 631. [all data]

Denyer, Fidler, et al., 1949
Denyer, R.L.; Fidler, F.A.; Lowry, R.A., Azeotrope Formation Between Thiols and Hydrocarbons, Ind. Eng. Chem., 1949, 41, 2727-37. [all data]

Forziati and Rossini, 1949
Forziati, A.F.; Rossini, F.D., J. Res. Natl. Bur. Stand. (U. S.), 1949, 43, 473. [all data]

Lecat, 1949
Lecat, M., Homofunctional azeotropes of hydrocarbons, Ann. Soc. Sci. Bruxelles, Ser. 1, 1949, 63, 58. [all data]

Rossini, Mair, et al., 1949
Rossini, F.D.; Mair, B.J.; Glasgow, A.R., Record Chem. Progr., 1949, 10, 121. [all data]

Rossini, 1948
Rossini, F.D., Pure compounds from petroleum purification and purity of hydrocarbons, Anal. Chem., 1948, 20, 110-21. [all data]

Boord, Greenlee, et al., 1947
Boord, C.E.; Greenlee, K.W.; Perilstein, W.L.; Derfer, J.M., The Synthesis, Purification and Prop. of Hydrocarbons of Low Mol. Wt., Am. Pet. Inst. Res. Proj. 45, Ninth Annu. Rep., Ohio State Univ., June 30, 1947. [all data]

Brescia, 1947
Brescia, F., The Critical Temperature, J. Chem. Educ., 1947, 24, 123. [all data]

Fenske, Braun, et al., 1947
Fenske, M.R.; Braun, W.G.; Wiegand, R.V.; Quiggle, D.; McCormick, R.H.; Rank, D.H., Raman Spectra of Hydrocarbons, Anal. Chem., 1947, 19, 700. [all data]

Shikheev, 1946
Shikheev, I.A., Methylpropylethynyl- and Methylpropylvinylcarbinols and Hydrocarbons Obtained from Them, Zh. Obshch. Khim., 1946, 16, 657. [all data]

Grummitt, Sensel, et al., 1945
Grummitt, O.; Sensel, E.E.; Smith, W.R.; Burk, R.E.; Lankelma, H.P., The Action of Aluminum Bromide on Paraffin Hydrocarbons I. n-Hexane and n-Heptane, J. Am. Chem. Soc., 1945, 67, 910. [all data]

Appleby, Dobratz, et al., 1944
Appleby, W.G.; Dobratz, C.J.; Kapranos, S.W., Vapor Phase Dehydration of 1-Heptanol ofer Activated Alumina, J. Am. Chem. Soc., 1944, 66, 1938. [all data]

Forziati, Willingham, et al., 1944
Forziati, A.F.; Willingham, C.B.; Mair, B.J.; Rossini, F.D., Hydrocarbons in the Gasolene Fraction of Seven Representative Crudes, Including All the Distillates to 102 deg. C and the Aromatics to 160 C, J. Res. Natl. Bur. Stand. (U. S.), 1944, 32, 11. [all data]

Anonymous, 1943
Anonymous, R., , Sunbury Rep. No. 2176, Anglo-Iranian Oil Co., 1943. [all data]

Rossini, 1943
Rossini, F.D., Pet. Eng., 1943, 14, 5, 41-2. [all data]

Davies and Gilbert, 1941
Davies, G.F.; Gilbert, E.C., Heats of Combustion and of Formation of the Nine Isomeric Heptanes in the Liquid State, J. Am. Chem. Soc., 1941, 63, 2730. [all data]

Henne, Chanan, et al., 1941
Henne, A.L.; Chanan, H.H.; Turk, A., Olefins and Diolefins from Allylic Chlorides, J. Am. Chem. Soc., 1941, 63, 3474-6. [all data]

Koch and Hilberath, 1941
Koch, H.; Hilberath, F., Uber unterhalb 100C siedenden kohlenwassestoffe des synthetischen benzins aus kohlenoxyd und wasserstoff (kogasin), Brennst.-Chem., 1941, 22, 145. [all data]

Glasgow, 1940
Glasgow, A.R., Isolation of 3-methylhexane, trans-1,2-dimethylcyclopentane, and trans-1,3- dimethylcyclopentane from petroleum, J. Res. Natl. Bur. Stand. (U. S.), 1940, 24, 509. [all data]

Beltz, 1939
Beltz, J.C., , Diss. Abstr. No. 28, 1939. [all data]

Wojciechowski, 1939
Wojciechowski, M., Przem. Chem., 1939, 23, 129. [all data]

Hoog, Smittenberg, et al., 1937
Hoog, H.; Smittenberg, J.; Visser, G.H., Composition of the Primary Polymerization Prod. of Propene and Butenes in IIe Congr. Mondial Pet. 2, Sect. 2, Phys. Chim. Raffin- age, p 489, 1937. [all data]

Leslie and White, 1935
Leslie, R.T.; White, J.D., Present Status or the Isolation and Identification of The Volatile Hydrocarbons in a Midcontinent Petroleum, J. Res. Natl. Bur. Stand. (U. S.), 1935, 15, 211. [all data]

Rossini, 1935
Rossini, F.D., Refin. Nat. Gasoline Manuf., 1935, 14, 255. [all data]

Soday and Boord, 1933
Soday, F.J.; Boord, C.E., Synthesis in the Olefin Series IV. The Heptenes, J. Am. Chem. Soc., 1933, 55, 3293. [all data]

McKee and Szayna, 1930
McKee, R.H.; Szayna, A., Ind. Eng. Chem., 1930, 22, 953. [all data]

Edgar, Calingaert, et al., 1929
Edgar, G.; Calingaert, G.; Marker, R.E., Preparation and Properties of the Isomeric Heptanes I. Preparation Preparation., J. Am. Chem. Soc., 1929, 51, 1483. [all data]

Edgar and Calingaert, 1929
Edgar, G.; Calingaert, G., Preparation and Properties of the Isomeric Heptanes II. Physical Prop. properties, J. Am. Chem. Soc., 1929, 51, 1540. [all data]

Timmermans, 1927
Timmermans, J., The Melting Point of Organic Substances, Bull. Soc. Chim. Belg., 1927, 36, 502. [all data]

De Graef, 1925
De Graef, H., Trimethylpropylmethane and Methylethylpropyllmethane, Bull. Soc. Chim. Belg., 1925, 34, 427. [all data]

Timmermans, 1921
Timmermans, J., The Freezing Points of Organic Substances IV. New Exp. Determinations, Bull. Soc. Chim. Belg., 1921, 30, 62. [all data]


Notes

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