Mercury, diphenyl-

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Mercury, diphenyl- (l) + Cl2Hg (cr) = 2Mercury, chlorophenyl- (cr)

By formula: C12H10Hg (l) + Cl2Hg (cr) = 2C6H5ClHg (cr)

Quantity Value Units Method Reference Comment
Δr-13.9 ± 0.50kcal/molRSCChernick, Skinner, et al., 1956Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.; MS

Mercury, diphenyl- (l) + Mercury(II) bromide (cr) = 2C6H5BrHg (cr)

By formula: C12H10Hg (l) + Br2Hg (cr) = 2C6H5BrHg (cr)

Quantity Value Units Method Reference Comment
Δr-8.48 ± 0.29kcal/molRSCHartley, Pritchard, et al., 1951Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.; MS

Mercury, diphenyl- (l) + Mercury diiodide (cr) = 2Phenyl mercuric iodide (cr)

By formula: C12H10Hg (l) + HgI2 (cr) = 2C6H5HgI (cr)

Quantity Value Units Method Reference Comment
Δr-5.2 ± 0.2kcal/molRSCHartley, Pritchard, et al., 1951Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.; MS

2Benzene, bromo- + Mercury(II) bromide = Mercury, diphenyl- + 2Bromine

By formula: 2C6H5Br + Br2Hg = C12H10Hg + 2Br2

Quantity Value Units Method Reference Comment
Δr78.53 ± 0.80kcal/molCmChernick, Skinner, et al., 1956, 2liquid phase; ALS

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chernick, Skinner, et al., 1956
Chernick, C.L.; Skinner, H.A.; Wadsö, I., Trans. Faraday Soc., 1956, 52, 1088. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Hartley, Pritchard, et al., 1951
Hartley, K.; Pritchard, H.O.; Skinner, H.A., Thermochemistry of metallic alkyls. IV. Mercury diethyl and mercury diphenyl, Trans. Faraday Soc., 1951, 47, 254, https://doi.org/10.1039/tf9514700254 . [all data]

Chernick, Skinner, et al., 1956, 2
Chernick, C.L.; Skinner, H.A.; Wadso, I., Thermochemistry of metallic alkyls. Part 7.-The heat of formation of mercury diphenyl, and of mercury phenyl chloride, Trans. Faraday Soc., 1956, 52, 1088-1093. [all data]


Notes

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