Cyclohexene, 1-methyl-4-(1-methylethylidene)-

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Normal alkane RI, polar column, custom temperature program

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase PEG-20M InnowaxInnowax FSCInnowax FSCHP InnowaxDB-Wax
Column length (m) 30.60.60.30.60.
Carrier gas NitrogenHeliumHeliumNitrogenHelium
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.50
Program 50 0C (7 min) 20 0C/min -> 130 0C (1 min) 1 0C/min -> 150 0C 8 0C/min -> 190 0C (5 min)60 0C (10 min) 4 0C/min -> 220 0C (10 min) 1 oC/min -> 240 0C60 0C (10 min) 4 0C/min -> 220 0C (10 min) 1 0C/min -> 240 0C35 0C (10 min) 3 0C/min -> 205 0C 10 0C/min -> 225 0C40 0C 4 0C/min -> 230 0C 100 0C/min -> 260 0C (11.7 min)
I 1277.1290.1290.1290.1282.
ReferenceWang, Tian, et al., 2013Akin, Saracoglu, et al., 2012Demirci, Temel, et al., 2011Laribi, Kouki, et al., 2011Miyazaki, Plotto, et al., 2011
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase InnowaxHP InnowaxInnowax FSCInnowax FSCHP Innowax FSP
Column length (m) 60.60.60.60.60.
Carrier gas   HeliumHeliumHelium
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.330.330.250.250.25
Program not specifiednot specified60 0C (10 min) 4 0C/min -> 220 0C (10 min) 1 0C/min -> 240 0C60 0C (10 min) 4 0C/min -> 220 0C (10 min) 1 0C/min -> 240 0C60 0C (10 min) 4 0C/min -> 220 0C (10 min) 1 0C/min -> 240 0C (20 min)
I 1265.1265.1290.1290.1290.
ReferenceNoorizadeh, Farmany, et al., 2011Noorizadeh and Farmany, 2010Polatoglu, Demirci, et al., 2010Baser, Demirci, et al., 2009Wedge, Klun, et al., 2009
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase InnowaxCP-Wax 52 CBSupelcowax-10Supelcowax-10HP-Innowax
Column length (m) 30.50.30.30.50.
Carrier gas HeliumHeliumHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.2
Phase thickness (μm) 0.250.290.250.250.2
Program not specified33 0C (1 min) 2 0C/min -> 130 0C 10 0C/min -> 220 0C35C(8min) => 6C/min => 60C => 4C/min => 160C => 20C/min => 200C(1min)35C(8min) => 6C/min => 60C => 4C/min => 160C => 20C/min => 200C(1min)40C(5min) => 2C/min => 250C(15min) => 10C/min => 270C
I 1286.1272.1276.1280.1265.
ReferenceAicha, Ines, et al., 2008Kaack and Christensen, 2008Berard, Bianchi, et al., 2007Berard, Bianchi, et al., 2007Formisano, Mignola, et al., 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Carbowax 20MInnowax FSCHP Innowax FSPInnowax FSCHP-Innowax FSC
Column length (m) 30.60.60.60.60.
Carrier gas HeNitrogenN2HeN2
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Program not specified60 0C (10 min) 1 0C/min -> 220 0C (10 min) 1 0C/min -> 240 0C60C(10min) => 4C/min => 220C(10min) => 1C/min => 240C60C(10min) => 4C/min >220C (10min) => 1C/min => 240C60C(10min) => 4C/min => 220C(10min) => 1C/min => 240C
I 1291.1290.1290.1290.1290.
ReferenceHudaib and Aburjai, 2007Kaya, Benirci, et al., 2007Tabanca N., Demirci B., et al., 2007Baser, Özek, et al., 2006Demirci B., Baser K.H.C., et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-Innowax FSCHP-Innowax FSCHP-Innowax FSCHP-Innowax FSCDB-Wax
Column length (m) 60.60.60.60.30.
Carrier gas HeHeHeN2He
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Program 60C(10min) => 4C/min => 220C (10min) => 1C/min => 240C60C(10min) => 4C/min => 220C (10min) => 1C/min => 240C60(10min) => 4C/min => 220C(10min) => 1C/min => 240C60C(10min) => 4C/min => 220C => (10min) => 1C/min => 240Cnot specified
I 1290.1290.1290.1290.1284.
ReferenceErdurak, Coskun, et al., 2006Kürkçüoglu, Hüsnü Can Baser, et al., 2006Suleimenov Y.M., Atazhanova G.A., et al., 2006Tabanca, Demirci, et al., 2006Berlinet, Ducruet, et al., 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-InnowaxHP-Innowax FSCCP-Wax 52CBInnowax FSCHP-Innowax FSC
Column length (m) 60.60. 60.60.
Carrier gas N2N2HydrogenHeHe
Substrate      
Column diameter (mm) 0.250.25 0.250.25
Phase thickness (μm) 0.250.25 0.250.25
Program 60C(10min) => 4C/min => 220C (10min) => 1C/min => 240C60C(10min) => 4C/min => 220C (10min) => 1C/min => 240Cnot specified60C(10min) => 4C/min => 220C(10min) => 1C/min => 240C60C(10min) => 4C/min => 220C(10min) => 1C/min => 240C
I 1290.1290.1290.1290.1290.
ReferenceDemirci, Demirci, et al., 2005Demirci, Demirci, et al., 2005, 2Jales, Maia, et al., 2005Kosar, Özek, et al., 2005Sezik E., Kocakulak E., et al., 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-Innowax FSCHP-Innowax FSCHP-Innowax FSCHP-Innowax FSCHP-Innowax FSC
Column length (m) 60.60.60.60.60.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Program 60C(10min) => 4C/min => 220C(10min) => 1C/min => 240C60C(10min) => 4C/min => 220C(10min) => 1C/min => 240C60C(10min) => 4C/min => 220C(10min) => 1C/min => 240C60C(10min) => 4C/min => 220C(10min) => 1C/min => 240C60C(10min) => 4C/min => 220C(10min) => 1C/min => 240C
I 1290.1290.1290.1290.1290.
ReferenceTabanca, Demirci, et al., 2005Viljoen, Subramoney, et al., 2005Demirci, Paper, et al., 2004Kivcak, Akay, et al., 2004Kivcak, Akay, et al., 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase InnowaxCarbowax 20MCarbowax 20MHP-Innowax FSCHP-Innowax FSC
Column length (m) 60.  60.60.
Carrier gas He  HeHe
Substrate      
Column diameter (mm) 0.25  0.250.25
Phase thickness (μm) 0.25  0.250.25
Program 50C(10min) => 4C/min => 220C(10min) => 1C/min => 240Cnot specifiednot specified60C (10min) => 4C/min => 220C (10min) => 1C/min => 240C60C(10min) => 4C/min => 220C(10min) => 1C/min => 240C
I 1290.1286.1287.1290.1290.
ReferenceSelli, Kürkçüoglu, et al., 2004Vinogradov, 2004Vinogradov, 2004Demirci, Baser, et al., 2003Demirci, Demirci, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase CarbowaxHP-Innowax FSCHP-Innowax FSCHP-FFAPInnowax
Column length (m)  60.60.30.60.
Carrier gas  N2HeHeHe
Substrate      
Column diameter (mm)  0.250.250.250.25
Phase thickness (μm)  0.250.25 0.25
Program not specified60C(10min) => 4C/min => 220C(10min) => 1C/min => 240C60C(10min) => 4C/min => 220C(10min) => 1C/min => 240C(40min)60C (2min) => 5C/min => 160C (1min) => 10C/min => 230C (12min)60C(10min) => 4C/min => 220C(10min) => 1C/min => 240C (20min)
I 1283.1290.1290.1315.1290.
ReferenceEdris, Shalaby, et al., 2003Kaya, Demirci, et al., 2003Kürkcüoglu, Demirci, et al., 2003Mockute and Judzentiene, 2003Tunaher, Kirimer, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-InnowaxHP-InnowaxInnowax FSCInnowaxHP-Innowax
Column length (m) 60.60.60.60.60.
Carrier gas  HeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Program 60C(10min) => 4C/min => 220C(10min) => 1C/min => 240C60 0C (10 min) 4 K/min -> 220 0C (10 min) 1 K/min -> 240 0C60C(10min) => 4C/min => 220C(10min) => 1C/min => 240C60C(10min) => 4C/min => 220C(10min) => 1C/min => 240C60 0C (10 min) 4 K/min -> 220 0C (10 min) 1 K/min -> 240 0C
I 1290.1290.1290.1290.1290.
ReferenceViljoen, van Vuuren, et al., 2003Baser, Demirci, et al., 2002Baser, Demirei, et al., 2002Baser, Nuriddinov, et al., 2002Demirci, Baser, et al., 2002
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-FFAPInnowax FSCHP-InnowaxCarbowax 20MHP-Innowax
Column length (m) 25.60.60. 60.
Carrier gas He HeH2He
Substrate      
Column diameter (mm) 0.220.250.25 0.25
Phase thickness (μm)  0.250.25 0.25
Program 60C(2min) => 5C/min => 160C(1min) => 10C/min => 230C(12min)60C(10min) => 4C/min => 220C(10min) => 1C/min => 240C60 0C (10 min) 10 K/min -> 220 0C (10 min) 1K/min -> 240 0Cnot specified60 0C (10 min) 4 K/min -> 220 0C (10 min) 1 K/min -> 240 0C
I 1315.1290.1290.1292.1290.
ReferenceMockute and Judzentiene, 2002Tunalier, Kirimer, et al., 2002Baser, Demirci, et al., 2001Gallori, Bilia, et al., 2001Gören, Demirci, et al., 2001
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-Innowax FSCHP-Innowax FSCInnowaxInnowax FSCInnowax FSC
Column length (m) 60.60.60.60.60.
Carrier gas  HeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Program 60C(10min) => 4C/min => 220C(10min) => 1C/min => 240C60C(10min) => 4C/min => 220C(10min) => 1C/min => 240C60C(10min) => 4C/min => 200C(10min) => 1C/min => 240C60C(10min) => 4C/min => 220C(10min) => 1C/min => 240C60C(10min) => 4C/min => 220C(10min) => 1C/min => 240C
I 1290.1290.1290.1290.1290.
ReferenceKaya, Demirci, et al., 2001Kirimer N., Tabanea N., et al., 2001Özcan, Akgül, et al., 2001Saglam, Gozler, et al., 2001Tabanca N., Demirci F., et al., 2001
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-Innowax FSCHP-InnowaxFFAPHP-WaxInnowax
Column length (m) 60.60.50.60.60.
Carrier gas  He HeHe
Substrate      
Column diameter (mm) 0.250.250.20.250.25
Phase thickness (μm) 0.250.250.330.250.25
Program 60C(10min) => 4C/min => 220C(10min) => 1C/min => 240C60C(10min) => 4C/min => 220C(10min) => 1C/min => 240C60C(1min) => 2.5C/min => 115C => 1C/min => 210C(30min)50 0C 3 K/min -> 200 0C 8 K/min -> 280 0C60 0C (10 min) 4 K/min -> 220 0C (10 min) 1 K/min -> 240 0C
I 1290.1290.1257.1280.1290.
ReferenceTabanca, Kirimer, et al., 2001Tabanca, Kirimer, et al., 2001, 2Tucker, Maciarello, et al., 2001Usubillaga, Aparicio, et al., 2001Baser, Özek, et al., 2000
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase InnowaxInnowaxInnowax FSCSupelcowax-10HP-Innowax FSC
Column length (m) 60.60.60. 60.
Carrier gas HeHeHe He
Substrate      
Column diameter (mm) 0.250.250.25 0.25
Phase thickness (μm) 0.250.250.25 0.25
Program 60 0C (10 min) 4 K/min -> 220 0C (10 min) 1 K/min -> 240 0C60 0C (10 min) 4 K/min -> 220 0C (10 min) 1 K/min -> 240 0C60C(10 min) => 4C/min => 220C(10min) => 1C/min => 240Cnot specified60C(10min) => 4C/min => 220C(10min) => 1C/min => 240C
I 1290.1290.1290.1281.1290.
ReferenceBaser, Özek, et al., 2000, 2Baser, Tabanca, et al., 2000Kirimer, Tabanca, et al., 2000Zunino, Lopez, et al., 2000Bagci, Baser, et al., 1999
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Innowax FSCFFAPSupelcowax 10Supelcowax 10Supelcowax 10
Column length (m) 60.25.60.60.60.
Carrier gas HeliumH2HeliumHeliumHelium
Substrate      
Column diameter (mm) 0.250.20.250.250.25
Phase thickness (μm) 0.250.330.250.250.25
Program 60 0C (10 min) 4 0C/min -> 220 0C (10 min) 1 0C/min -> 240 0C40C(5min) => 4C/min => 170C => 8C/min => 240C (12min)60 0C (10 min) 2 0C/min -> 80 0C 3 0C/min -> 100 0C 4 0C/min -> 220 0C (30 min)not specifiednot specified
I 1290.1269.1274.1288.1288.
ReferenceKirimer, Tabanca, et al., 1999Reddy, Angers, et al., 1998Castioni and Kapetanidis, 1996Castioni and Kapetanidis, 1996Castioni and Kapetanidis, 1996
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillary
Active phase Carbowax 20MNB-351NB-351CP-Wax 52CB
Column length (m) 60.25.25.50.
Carrier gas HeHe  
Substrate     
Column diameter (mm) 0.250.320.320.32
Phase thickness (μm) 0.250.20.2 
Program not specified35C(5min) => 2.5C/min => 150C => 5C/min => 240C (20min)40C(5min) => 4C/min => 150C => 8C/min => 240C(12min)not specified
I 1291.1276.1268.1285.
ReferenceTirado, Stashenko, et al., 1995Kerrola and Kallio, 1994Kerrola and Kallio, 1993Vernin, 1991
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI

References

Go To: Top, Normal alkane RI, polar column, custom temperature program, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wang, Tian, et al., 2013
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Laribi, Kouki, et al., 2011
Laribi, B.; Kouki, K.; Sahli, A.; Mougou, A.; Marzouk, B., Essential oil fatty acids composition of a Tunisian caraway (Carum carvi L.) seed ecotype cultivated under water deficit, Adv. Environ. Biol., 2011, 1-15, retrieved from http://www.thefreelibrary.com//print/PrintArticle.aspx?id=253057768. [all data]

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Polatoglu, K.; Demirci, F.; Demirci, B.; Goren, N.; Baser, K.H.C., Antimicrobial activity and essential oil composition of a new T. argyrophyllum (C. Koch) Tvzel var. argyrophyllium chemotype, J. Oleo Sci., 2010, 59, 6, 307-313, https://doi.org/10.5650/jos.59.307 . [all data]

Baser, Demirci, et al., 2009
Baser, K.H.C.; Demirci, B.; Kurkcuoglu, M.; Satin, F.; Tumen, G., Comparative morphological and phytochemical charactertization of Salvia cadmica and S. smyrnaea, Pak. J. Bot., 2009, 41, 4, 1545-1555. [all data]

Wedge, Klun, et al., 2009
Wedge, D.E.; Klun, J.A.; Tabanca, N.; Demirci, B.; Ozek, T.; Baser, K.H.C.; Liu, Z.; Zhang, S.; Cantrell, C.L.; Zhang, J., Bioactivity-guided fractionation and GC/MS fingerprinting of Amgelica sinensis and Angelica archangelica root components for antifungal and mosquito deterrent activity, J. Agric. Food Chem., 2009, 57, 2, 464-470, https://doi.org/10.1021/jf802820d . [all data]

Aicha, Ines, et al., 2008
Aicha, N.; Ines, S.; Mohamed, B.S.; Ines, B.; Soumaya, K.; Kamel, G.; Mohamed, N.; Imed, C.; Mohamed, H.; Leila, C.-G., Chemical composition, mutagenic and antimutagenic activities of essential oils from (Tunisian) Artemisia campestris and Artemisia herba-alba, J. Ess. Oil Res., 2008, 20, 5, 471-477. [all data]

Kaack and Christensen, 2008
Kaack, K.; Christensen, L.P., Effect of packing materials and storage time on volatile compounds in tea processes from flowers of black elder (Sambucus nigra L.), Eur. Food Res. Technol., 2008, 227, 4, 1259-1273, https://doi.org/10.1007/s00217-008-0844-8 . [all data]

Berard, Bianchi, et al., 2007
Berard, J.; Bianchi, F.; Careri, M.; Chatel, A.; Mangia, A.; Musci, M., Characterization of the volatile fraction and of free fatty acids of Fontina Valle d'Aosta, a protected designation of origin Italian cheese, Food Chem., 2007, 105, 1, 293-300, https://doi.org/10.1016/j.foodchem.2006.11.041 . [all data]

Formisano, Mignola, et al., 2007
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Hudaib and Aburjai, 2007
Hudaib, M.; Aburjai, T., Volatile components of Thymus vulgaris L. from wild-growing and cultivated plants in Jordan, Flavour Fragr. J., 2007, 22, 4, 322-327, https://doi.org/10.1002/ffj.1800 . [all data]

Kaya, Benirci, et al., 2007
Kaya, A.; Benirci, B.; Baser, K.H.C., Micromorphology of glandular trichomes of Nepeta congesta Fisch. Mey. var. congesta (LAmiaceae) and chemical analysis of the essential oils, South African J. Botany, 2007, 73, 1, 29-34, https://doi.org/10.1016/j.sajb.2006.05.004 . [all data]

Tabanca N., Demirci B., et al., 2007
Tabanca N.; Demirci B.; Crockett S.L.; Baser K.H.C.; Wedge D.E., Chemical composition and antifungal activity of Arnica longifolia, Aster hesperius, and Chrysothamnus nauseosus essential oils, J. Agric. Food Chem., 2007, 55, 21, 8430-8435, https://doi.org/10.1021/jf071379c . [all data]

Baser, Özek, et al., 2006
Baser, K.H.C.; Özek, G.; Özek, T.; Duran, A.; Duman, H., Composition of the essential oils of Rhabdosciadium oligocarpum (Post ex Boiss.) Hedge et Lamond and Rhabdosciadium microcalycinum Hand.-Mazz., Flavour Fragr. J., 2006, 21, 4, 650-655, https://doi.org/10.1002/ffj.1639 . [all data]

Demirci B., Baser K.H.C., et al., 2006
Demirci B.; Baser K.H.C.; Tabanca N.; Wedge D.E., Characterization of volatile constituents of Haplopappus greenei and studies on the antifungal activity against phytopathogens, J. Agric. Food Chem., 2006, 54, 8, 3146-3150, https://doi.org/10.1021/jf053222v . [all data]

Erdurak, Coskun, et al., 2006
Erdurak, C.S.; Coskun, M.; Demirci, B.; Baser, K.H.C., Composition of the essential oil of fruits and roots of Ferulago isaurica Pesmen and F. syriaca Boiss. (Umbelliferae) from Turkey, Flavour Fragr. J., 2006, 21, 1, 118-121, https://doi.org/10.1002/ffj.1540 . [all data]

Kürkçüoglu, Hüsnü Can Baser, et al., 2006
Kürkçüoglu, M.; Hüsnü Can Baser, K.; Iscan, G.; Malyer, H.; Kaynak, G., Composition and anticandidal activity of the essential oil of Chaerophyllum byzantinum Boiss., Flavour Fragr. J., 2006, 21, 1, 115-117, https://doi.org/10.1002/ffj.1539 . [all data]

Suleimenov Y.M., Atazhanova G.A., et al., 2006
Suleimenov Y.M.; Atazhanova G.A.; Ozek T.; Demirci B.; Kulyyasov A.T.; Adekenov S.M.; Baser K.H.C., Essential oil composition of three species of Achillea from Kazakhstan, Chem. Nat. Compd. (Engl. Transl.), 2006, 37, 5, 447-450, https://doi.org/10.1023/A:1014471326724 . [all data]

Tabanca, Demirci, et al., 2006
Tabanca, N.; Demirci, B.; Can Baser, K.H.; Aytac, Z.; Ekici, M.; Khan, S.I.; Jacob, M.R.; Wedge, D.E., Chemical Composition and Antifungal Activity of Salvia macrochlamys and Salvia recognita Essential Oils, J. Agric. Food Chem., 2006, 54, 18, 6593-6597, https://doi.org/10.1021/jf0608773 . [all data]

Berlinet, Ducruet, et al., 2005
Berlinet, C.; Ducruet, V.; Brillouet, J.-M.; Reynes, M.; Brat, P., Evolution of aroma compounds from orange juice stored in polyethylene terephthalate (PET), Food Addit. Contam., 2005, 22, 2, 185-195, https://doi.org/10.1080/02652030500037860 . [all data]

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Notes

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