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Benzoic acid, 3-bromo-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Tboil553.KN/ABuckingham and Donaghy, 1982BS
Quantity Value Units Method Reference Comment
Tfus428.KN/ABuckingham and Donaghy, 1982BS
Tfus427.KN/ASimons and Ramler, 1943Uncertainty assigned by TRC = 4. K; TRC
Quantity Value Units Method Reference Comment
Deltasub25.3 ± 0.2kcal/molMERibeiro da Silva, Fonseca, et al., 2005Based on data from 328. - 347. K.; AC
Deltasub23.7 ± 0.05kcal/molCTan and Raphael, 1994AC
Deltasub25.10 ± 0.26kcal/molCFerrao and Pilcher, 1987ALS
Deltasub25.10 ± 0.26kcal/molCFerrao and Pilcher, 1987AC

Enthalpy of sublimation

DeltasubH (kcal/mol) Temperature (K) Method Reference Comment
24.9 ± 0.1338.MERibeiro da Silva, Fonseca, et al., 2005Based on data from 328. - 347. K.; AC

Enthalpy of fusion

DeltafusH (kcal/mol) Temperature (K) Method Reference Comment
5.954430.1DSCRibeiro da Silva, Fonseca, et al., 2005AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Buckingham and Donaghy, 1982
Buckingham, J.; Donaghy, S.M., Dictionary of Organic Compounds: Fifth Edition, Chapman and Hall, New York, 1982, 1. [all data]

Simons and Ramler, 1943
Simons, J.H.; Ramler, E.O., Preparation and Properties of SOme New Trifluoromethyl Compounds, J. Am. Chem. Soc., 1943, 65, 389. [all data]

Ribeiro da Silva, Fonseca, et al., 2005
Ribeiro da Silva, Manuel A.V.; Fonseca, José M.S.; Carvalho, Rui P.B.M.; Monte, Manuel J.S., Thermodynamic study of the sublimation of six halobenzoic acids, The Journal of Chemical Thermodynamics, 2005, 37, 3, 271-279, https://doi.org/10.1016/j.jct.2004.09.005 . [all data]

Tan and Raphael, 1994
Tan, Z.-C.; Raphael, S., Thermodynamic study of the three isomers of bromobenzoic acid, Sci. China, Ser. B: Chem., Life Sci., Earth Sci., 1994, 37, 6, 641. [all data]

Ferrao and Pilcher, 1987
Ferrao, M.C.C.H.; Pilcher, G., Enthalpies of combustion of the three bromobenzoic acids by rotating-bomb calorimetry, J. Chem. Thermodyn., 1987, 19, 543-548. [all data]


Notes

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