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Normal alkane RI, non-polar column, temperature ramp

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type PackedPackedCapillaryCapillaryCapillary
Active phase Polydimethyl siloxaneSE-30OV-1Ultra-1SLB-5MS
Column length (m) 2.2.50.50.10.
Carrier gas NitrogenNitrogen HeliumHelium
Substrate  Chromosorb G AW DMCS (80-100 mesh)   
Column diameter (mm)   0.320.200.18
Phase thickness (mum)   0.500.330.18
Tstart (C) 100.100.40.50.40.
Tend (C) 300.300.270.280.295.
Heat rate (K/min)   2.2.10.
Initial hold (min)     1.5
Final hold (min)   10.20. 
I 1810.1810.1789.1772.1836.
ReferenceMHA, 9999MHA, 9999Da Costa, Yang, et al., 2010Du, Clery, et al., 2008Risticevic, Carasek, et al., 2008
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5 MSPolymethylsiloxane, (PMS-20000)DB-1BP-1BP-1
Column length (m) 30.12.15.12.12.
Carrier gas HeliumHeHeHeHe
Substrate      
Column diameter (mm) 0.250.200.250.220.22
Phase thickness (mum) 0.250.330.250.250.25
Tstart (C) 100.160.130.120.120.
Tend (C) 280.300.290.270.270.
Heat rate (K/min) 5.10.10.12.15.
Initial hold (min) 2. 1.  
Final hold (min) 20. 10.  
I 1842.1800.1774.1779.1784.
ReferenceChristov and Evstatieva, 2003Gambaro, Saligari, et al., 1997Sharp, 1987Stowell and Wilson, 1985Stowell and Wilson, 1985
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase BP-1BP-1BP-1BP-1BP-1
Column length (m) 12.12.12.12.12.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.220.220.220.220.22
Phase thickness (mum) 0.250.250.250.250.25
Tstart (C) 120.120.120.120.50.
Tend (C) 270.270.270.280.300.
Heat rate (K/min) 25.6.8.8.20.
Initial hold (min)      
Final hold (min)      
I 1800.1776.1775.1768.1764.
ReferenceStowell and Wilson, 1985Stowell and Wilson, 1985Stowell and Wilson, 1985Stowell and Wilson, 1985Stowell and Wilson, 1985
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type PackedCapillaryCapillaryPackedPacked
Active phase SE-30OV-101OV-101SE-30SE-30
Column length (m) 2.30.25.2.2.
Carrier gas  H2HeNitrogenN2
Substrate Gas Chrom P  Chromosorb W AW DMS (80-100 mesh)Chromosorb W AW DMS
Column diameter (mm)  0.3   
Phase thickness (mum)      
Tstart (C) 120.80.75.130.130.
Tend (C) 200.275.280.290.290.
Heat rate (K/min) 2.52.2.8.8.
Initial hold (min)  7.7.2.2.
Final hold (min)    8.8.
I 1815.1797.1797.1790.1790.
ReferenceMarozzi, Gambaro, et al., 1982Pinkston, Spiteller, et al., 1981Spiteller and Spiteller, 1979Peel and Perrigo, 1976Peel and Perrigo, 1975
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI

References

Go To: Top, Normal alkane RI, non-polar column, temperature ramp, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

MHA, 9999
MHA, Directorate of ForensicScience., Forensic Toxicology, 9999. [all data]

Da Costa, Yang, et al., 2010
Da Costa, N.C.; Yang, Y.; Kowalczyk, J.; Poulsen, M.L., The analysis of volatiles and non-volatiles in Yerba Mate tea (Ilex paraguariensis) in Proc. 12th Weurman Symp., Blank, I.; Wust, M.; Yeretzian, C., ed(s)., Institut fur Chemie und Biologisher Chemie, Wissenschafen, Winterthur, 2010, 494-497. [all data]

Du, Clery, et al., 2008
Du, Z.; Clery, R.; Hammond, C.J., Volatile organic nitrogen-containing constituents in ambrette seed Abelmoschus moschatus Medik (Malvaceae), J. Agric. Food Chem., 2008, 56, 16, 7388-7392, https://doi.org/10.1021/jf800958d . [all data]

Risticevic, Carasek, et al., 2008
Risticevic, S.; Carasek, E.; Pawliszyn, J., Headspace solid-phase microextraction-gas chromatographic-time-of-flight mass spectrometric methodology for geographical origin verification of coffee, Anal. Chim. Acta, 2008, 617, 1-2, 72-84, https://doi.org/10.1016/j.aca.2008.04.009 . [all data]

Christov and Evstatieva, 2003
Christov, V.; Evstatieva, L., Alkaloid profile of Bulgarian species from genus Senecio L., Z. Naturforsch., 2003, 58c, 300-302. [all data]

Gambaro, Saligari, et al., 1997
Gambaro, V.; Saligari, E.; Froldi, R.; Bianchi, L., Analysis of street drugs by means of HRGC, Bollettino Chimico Farmaceutica, 1997, 36, 4, 359-367. [all data]

Sharp, 1987
Sharp, M.E., A rapid screening procedure for acidic and neutral drugs in blood by high resolution gas chromatography, J. Anal. Toxicol., 1987, 11, 1, 8-11, https://doi.org/10.1093/jat/11.1.8 . [all data]

Stowell and Wilson, 1985
Stowell, A.; Wilson, L., Use of retention indices in drug screening by capillary gas chromatography, Rep. # CD 2362, Department of Scientific and Industrial Reseach, Chemistry Division, Lower Hutt, NZ, 1985, 32. [all data]

Marozzi, Gambaro, et al., 1982
Marozzi, E.; Gambaro, V.; Saligari, E.; Mariani, R.; Lodi, F., Use of the retention index in gas chromatographic studies of drugs, J. Anal. Toxicol., 1982, 6, 4, 185-192, https://doi.org/10.1093/jat/6.4.185 . [all data]

Pinkston, Spiteller, et al., 1981
Pinkston, D.; Spiteller, G.; von Henning, H.; Matthaei, D., High-resolution gas chromatography-mass spectrometry of the methyl esters of organic acids from uremic hemofiltrates, J. Chromatogr., 1981, 223, 1, 1-19, https://doi.org/10.1016/S0378-4347(00)80063-8 . [all data]

Spiteller and Spiteller, 1979
Spiteller, M.; Spiteller, G., Trennung und charakterisierung saurer harnbest and- teile, J. Chromatogr., 1979, 164, 3, 253-317, https://doi.org/10.1016/S0378-4347(00)81232-3 . [all data]

Peel and Perrigo, 1976
Peel, H.W.; Perrigo, B., A practical gas chromatographic screening procedure for toxicological analysis, Can. Soc. Forens. Sci. J., 1976, 9, 2, 69-74, https://doi.org/10.1080/00085030.1976.10757247 . [all data]

Peel and Perrigo, 1975
Peel, H.W.; Perrigo, B., A practical gas chromatographic screening procedure for toxicological analysis, Can.Soc.Forens.Sci.J., 1975, 9, 2, 69-74, https://doi.org/10.1080/00085030.1976.10757247 . [all data]


Notes

Go To: Top, Normal alkane RI, non-polar column, temperature ramp, References