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3-Quinolinamine

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafgas49.81 ± 0.53kcal/molCcbRibeiro da Silva, Matos, et al., 1993 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafsolid25.17 ± 0.48kcal/molCcbRibeiro da Silva, Matos, et al., 1993 
Quantity Value Units Method Reference Comment
Deltacsolid-1144.9 ± 0.38kcal/molCcbRibeiro da Silva, Matos, et al., 1993 

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tfus429.65KN/ACumper, Ginman, et al., 1963Uncertainty assigned by TRC = 2. K; TRC
Quantity Value Units Method Reference Comment
Deltasub24.6 ± 0.2kcal/molCRibeiro da Silva, Matos, et al., 1993ALS
Deltasub24.64kcal/molN/ARibeiro da Silva, Matos, et al., 1993DRB
Deltasub24.6 ± 0.2kcal/molMEda Silva, Matos, et al., 1993Based on data from 329. - 345. K.; AC
Deltasub25.0 ± 1.1kcal/molCda Silva, Matos, et al., 1993AC

Enthalpy of sublimation

DeltasubH (kcal/mol) Temperature (K) Method Reference Comment
24.2 ± 0.2337.MEda Silva, Matos, et al., 1993Based on data from 329. - 345. K.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C9H7N2- + Hydrogen cation = 3-Quinolinamine

By formula: C9H7N2- + H+ = C9H8N2

Quantity Value Units Method Reference Comment
Deltar353.9 ± 2.9kcal/molG+TSBreuker, Knochenmuss, et al., 1999gas phase; Acid: 3-amino-quinoline
Quantity Value Units Method Reference Comment
Deltar346.7 ± 2.7kcal/molIMRBBreuker, Knochenmuss, et al., 1999gas phase; Acid: 3-amino-quinoline

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

De-protonation reactions

C9H7N2- + Hydrogen cation = 3-Quinolinamine

By formula: C9H7N2- + H+ = C9H8N2

Quantity Value Units Method Reference Comment
Deltar353.9 ± 2.9kcal/molG+TSBreuker, Knochenmuss, et al., 1999gas phase; Acid: 3-amino-quinoline
Quantity Value Units Method Reference Comment
Deltar346.7 ± 2.7kcal/molIMRBBreuker, Knochenmuss, et al., 1999gas phase; Acid: 3-amino-quinoline

IR Spectrum

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Coblentz Society, Inc.

Condensed Phase Spectrum

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IR spectrum
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Notice: Except where noted, spectra from this collection were measured on dispersive instruments, often in carefully selected solvents, and hence may differ in detail from measurements on FTIR instruments or in other chemical environments. More information on the manner in which spectra in this collection were collected can be found here.

Notice: Concentration information is not available for this spectrum and, therefore, molar absorptivity values cannot be derived.

Additional Data

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Owner COBLENTZ SOC.
Collection (C) 2018 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin DOW CHEMICAL COMPANY
Source reference COBLENTZ NO. 06498
Date 1963/11/07
Name(s) 3-quinolinylamine
3-quinolinamine
State SOLID (SPLIT MULL)
SPECTRAL FEATURE AT 1997 CM-1 IS PROBABLY AN ARTIFACT CAUSED BY GRATING CHANGE
Instrument BECKMAN IR-9 (GRATING)
Instrument parameters ORDER CHANGES: 670, 1200, 2000 CM-1
Resolution 2
Sampling procedure TRANSMISSION
Data processing DIGITIZED BY COBLENTZ SOCIETY (BATCH I) FROM HARD COPY

This IR spectrum is from the Coblentz Society's evaluated infrared reference spectra collection.


Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Japan AIST/NIMC Database- Spectrum MS-NW-2595
NIST MS number 234266

All mass spectra in this site (plus many more) are available from the NIST/EPA/NIH Mass Spectral Library. Please see the following for information about the library and its accompanying search program.


UV/Visible spectrum

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Victor Talrose, Alexander N. Yermakov, Alexy A. Usov, Antonina A. Goncharova, Axlexander N. Leskin, Natalia A. Messineva, Natalia V. Trusova, Margarita V. Efimkina

Spectrum

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UVVis spectrum
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Additional Data

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Source Steck and Ewing, 1948
Owner INEP CP RAS, NIST OSRD
Collection (C) 2007 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin INSTITUTE OF ENERGY PROBLEMS OF CHEMICAL PHYSICS, RAS
Source reference RAS UV No. 9841
Instrument n.i.g.
Melting point 93-95

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ribeiro da Silva, Matos, et al., 1993
Ribeiro da Silva, M.A.V.; Matos, M.A.R.; Monte, M.J.S.; Alves, M.C.B.; Vieira, J.M.A.P., Enthalpies of combustion, vapour pressures, and enthalpies of sublimation of 3-,5-,6-, and 8-aminoquinoline, J. Chem. Thermodyn., 1993, 25, 579-590. [all data]

Cumper, Ginman, et al., 1963
Cumper, C.W.N.; Ginman, R.F.A.; Redford, D.G.; Vogel, A.I., Physical Properties and Chemical Constitution. Part XXXVIII. The Electric Dipole Moments of Aminopyridines and Aminoquinolines., J. Chem. Soc., 1963, 1963, 1731. [all data]

da Silva, Matos, et al., 1993
da Silva, Manuel A.V. Ribeiro; Matos, M. Agostinha R.; Monte, Manuel J.S.; Alves, M. Céu B.; Vieira, João M.A.P., Enthalpies of combustion, vapour pressures, and enthalpies of sublimation of 3-, 5-, 6-, and 8-aminoquinoline, The Journal of Chemical Thermodynamics, 1993, 25, 5, 579-590, https://doi.org/10.1006/jcht.1993.1052 . [all data]

Breuker, Knochenmuss, et al., 1999
Breuker, K.; Knochenmuss, R.; Zenobi, R., Gas-phase basicities of deprotonated matrix-assisted laser desorption/ionization matrix molecules, Int. J. Mass Spectrom., 1999, 184, 1, 25-38, https://doi.org/10.1016/S1387-3806(98)14200-8 . [all data]

Steck and Ewing, 1948
Steck, E.A.; Ewing, G.W., J. Am. Chem. Soc., 1948, 70, 3397. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, References