Ledol


Normal alkane RI, non-polar column, temperature ramp

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5 MSHP-5 MSHP-5 MSHP-5 MSHP-5
Column length (m) 60.30.30.30.30.
Carrier gas Helium HeliumHeliumHelium
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 40.60.50.50.50.
Tend (C) 250.300.250.180.240.
Heat rate (K/min) 3.15.7.2.3.
Initial hold (min) 1.2.1. 5.
Final hold (min) 20.10.5.  
I 1571.1565.1616.1562.1607.
ReferenceSardashti, Valizadeh, et al., 2013Xu, Han, et al., 2012Zouari, Ayadi, et al., 2012Hammami, Kamoun, et al., 2011Monsef-Esfahani, Miri, et al., 2010
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5DB-1DB-5DB-5RTX-1
Column length (m) 30.30.30.30.60.
Carrier gas HeliumHeliumHeliumHeliumHelium
Substrate      
Column diameter (mm) 0.250.250.250.250.22
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 40.50.35.50.60.
Tend (C) 240.220.220.250.230.
Heat rate (K/min) 3.4.3.5.2.
Initial hold (min) 1.2. 2. 
Final hold (min)  2.40. 30.
I 1574.1567.1552.1569.1593.
Referencede Souza, Lopes, et al., 2010Xu, Tang, et al., 2010El-Massry, El-Ghorab, et al., 2009Ho, Wang, et al., 2009Museli, Pau, et al., 2009
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase RTX-1DB-5HP-5 MSDB-5 MSRTX-1
Column length (m) 60.30.30.30.60.
Carrier gas HeliumHeliumHeliumHeliumHe
Substrate      
Column diameter (mm) 0.220.250.250.250.22
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.40.60.50.60.
Tend (C) 230.240.300.300.230.
Heat rate (K/min) 2.3.15.5.2.
Initial hold (min)  1.2.5. 
Final hold (min) 30. 10.5.35.
I 1600.1574.1565.1563.1588.
ReferenceMuseli, Pau, et al., 2009de Souza, Lopes, et al., 2009Xu, Han, et al., 2009Noudogbessi, Yedomonhan, et al., 2008Paolini, Tomi, et al., 2008
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5HP-5MSDB-5DB-5HP-1
Column length (m) 30.30.30.30.30.
Carrier gas HeHeHeliumHeHe
Substrate      
Column diameter (mm) 0.260.250.260.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.60.60.35.60.
Tend (C) 240.280.290.220.240.
Heat rate (K/min) 3.3.3.3.2.
Initial hold (min)      
Final hold (min)    40.20.
I 1560.1563.1560.1564.1601.
ReferenceBos, Woerdenbag, et al., 2007Bozin B., Mlmica-Dukic N., et al., 2007Elfami, Bos, et al., 2007El-Ghorab A., El-Massry K.F., et al., 2007Hachicha, Skanji, et al., 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5DB-5SPB-1SPB-5DB-5
Column length (m) 30.30.30.30.30.
Carrier gas HeHeliumHeHe 
Substrate      
Column diameter (mm) 0.250.250.20.250.25
Phase thickness (μm) 0.250.250.20.250.25
Tstart (C) 60.60.70.50.60.
Tend (C) 300.300.220.250.300.
Heat rate (K/min) 3.3.3.2.3.
Initial hold (min)      
Final hold (min)   15.  
I 1554.1539.1582.1559.1561.
ReferenceLimberger, Scopel, et al., 2007Moreno, Lima, et al., 2007Pinto, Salgueiro, et al., 2007Raal, Orav, et al., 2007Apel, Sobral, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase AT-5BP-1HP-5MSDB-1DB-5
Column length (m) 60.50.30.60.30.
Carrier gas He HeNitrogenHelium
Substrate      
Column diameter (mm) 0.250.220.250.250.26
Phase thickness (μm) 0.250.250.25 0.25
Tstart (C) 60.60.60.40.60.
Tend (C) 200.220.280.200.290.
Heat rate (K/min) 4.2.3.2.3.
Initial hold (min)    1. 
Final hold (min) 20.20. 9. 
I 1568.1600.1563.1593.1560.
ReferenceBorges, Rojas, et al., 2006Boti, Yao, et al., 2006Bozin, Mimicá-Dukic, et al., 2006Chen, Sheu, et al., 2006Elfami, Komar, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5HP-1NB-30DB-5DB-5
Column length (m) 30.50.30.30.30.
Carrier gas HeHeHeN2He
Substrate      
Column diameter (mm) 0.250.20.20.250.25
Phase thickness (μm) 0.250.330.250.250.25
Tstart (C) 50.60.50.60.60.
Tend (C) 300.250.250.240.230.
Heat rate (K/min) 5.2.2.4.3.
Initial hold (min) 5.    
Final hold (min) 5.40.   
I 1569.1586.1604.1605.1555.
ReferenceFiguérédo, Cabassu, et al., 2006Filippi, Lanfranchi, et al., 2006Orav, Raal, et al., 2006Trilles, Bombarda, et al., 2006Limberger, Sobral, et al., 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase CP Sil 5 CBDB-1HP-5MSDB-5DB-5
Column length (m) 25.50.30.30.30.
Carrier gas  N2HeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.150.250.250.250.25
Tstart (C) 50.95.60.60.60.
Tend (C) 230.240.280.300.300.
Heat rate (K/min) 3.4.4.3.3.
Initial hold (min)      
Final hold (min)      
I 1598.1570.1565.1562.1562.
ReferenceOgunwande, Olawore, et al., 2005Pala-Paul, Perez-Alonso, et al., 2005Sajjadi S.E. and Eskandari B., 2005Simoes-Pires C.A., Debenedetti S., et al., 2005Simoes-Pires C.A., Debenedetti S., et al., 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5DB-5DB-5RTX-1DB-5
Column length (m) 30.30.30.30.30.
Carrier gas HeHeH2N2He
Substrate      
Column diameter (mm) 0.250.320.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.60.50.60.60.
Tend (C) 300.280.290.300.300.
Heat rate (K/min) 3.3.4.4.3.
Initial hold (min)      
Final hold (min)      
I 1562.1547.1559.1601.1554.
ReferenceSimoes-Pires C.A., Debenedetti S., et al., 2005Tzakou and Constantinidis, 2005Abreu, Reis, et al., 2004Kalemba and Thiem, 2004Lago, de Ávila, et al., 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5HP-5MSNB-30NB-30NB-30
Column length (m) 30.30.50.50.50.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.20.20.20
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.60.50.50.50.
Tend (C) 300.280.250.250.250.
Heat rate (K/min) 3.3.2.2.2.
Initial hold (min)      
Final hold (min)      
I 1560.1565.1600.1600.1598.
ReferenceLimberger, Sobral, et al., 2004Mimica-Dukic, Bozin, et al., 2004Orav, Stulova, et al., 2004Orav, Stulova, et al., 2004Raal, Paaver, et al., 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Methyl SiliconeHP-5 MSHP-1Methyl SiliconeRSL-200
Column length (m) 60.30.30.30.30.
Carrier gas HeHeliumHeHeH2
Substrate      
Column diameter (mm) 0.250.250.250.320.32
Phase thickness (μm) 0.250.250.330.250.25
Tstart (C) 60.60.40.60.40.
Tend (C) 200.200.260.250.280.
Heat rate (K/min) 4.4.2.2.6.
Initial hold (min) 1.1.5.2.5.
Final hold (min) 20.20.20.5.5.
I 1565.1565.1550.1540.1592.
ReferenceRojas, Usubillaga, et al., 2004Royas, Usubillaga, et al., 2004Senatore, Napolitano, et al., 2004Jayaprakasha, Rao, et al., 2003Jirovetz, Buchbauer, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5HP-5DB-5DB-5HP-5
Column length (m) 30.60.30.30.30.
Carrier gas He N2He 
Substrate      
Column diameter (mm) 0.250.250.250.250.32
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.40.50.60.100.
Tend (C) 250.250.250.240.240.
Heat rate (K/min) 3.5.4.3.5.
Initial hold (min)  15.  2.
Final hold (min)     5.
I 1561.1567.1565.1565.1566.
ReferenceLimberger, Simões-Pires, et al., 2003Stashenko, Jaramillo, et al., 2003Farah, Fechtal, et al., 2002Kobaisy, Tellez, et al., 2002Lago, Reis, et al., 2002
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5MSDB-1OV-101RTX-1OV-101
Column length (m) 30.30.25.30.50.
Carrier gas HeN2N2N2N2
Substrate      
Column diameter (mm) 0.250.250.250.250.2
Phase thickness (μm) 0.250.25 0.25 
Tstart (C) 60.80.50.60.80.
Tend (C) 240.225.200.300.200.
Heat rate (K/min) 3.4.5.4.1.
Initial hold (min)      
Final hold (min) 30.   20.
I 1550.1539.1562.1601.1597.
ReferenceMarongiu, Porcedda, et al., 2001Palá-Paúl, Pérez-Alonso, et al., 2001Ayedoun, Adéoti, et al., 1999Kalemba, 1999Menon, Chacko, et al., 1999
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase OV-1HP-1CP Sil 5 CBCP Sil 5 CBCP Sil 5 CB
Column length (m) 50.60.25.25.25.
Carrier gas HeHeN2N2He
Substrate      
Column diameter (mm) 0.320.250.320.320.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 50.50.50.50.60.
Tend (C) 250.280.290.290.300.
Heat rate (K/min) 10.4.4.4.6.
Initial hold (min) 5.5.   
Final hold (min) 20.    
I 1560.1585.1575.1575.1575.
ReferenceKökdil, Kurucu, et al., 1998Stashenko, Cervantes, et al., 1998Bos, Woerdenbag, et al., 1997Bos, Woerdenbag, et al., 1997Bos, Woerdenbag, et al., 1997, 2
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-1DB-5CBP-1HP-1OV-1
Column length (m)  30.25.25.50.
Carrier gas  HeliumHeHeliumN2
Substrate      
Column diameter (mm)  0.250.220.320.27
Phase thickness (μm)  0.25 0.250.2
Tstart (C) 80.60.60.60.80.
Tend (C) 220.240.240.220.240.
Heat rate (K/min) 6.3.5.4.3.
Initial hold (min)    2. 
Final hold (min)    20. 
I 1580.1568.1595.1585.1596.
ReferenceSalgueiro, Vila, et al., 1997Tellez, Estell, et al., 1997Zygadlo, Ariza-Espinar, et al., 1997Thanh, Dung, et al., 1996Ramanoelina, Viano, et al., 1994
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillary
Active phase DB-1DB-1BP-1
Column length (m) 30.60.50.
Carrier gas N2 H2
Substrate    
Column diameter (mm)  0.320.30
Phase thickness (μm)    
Tstart (C) 80.50.40.
Tend (C) 220.250.250.
Heat rate (K/min) 4.4.10.
Initial hold (min)  0.11.
Final hold (min)  5. 
I 1594.1590.1604.
ReferenceVelasco-Negueruela, Pérez Alonso, et al., 1991Binder and Flath, 1989Brophy, Davies, et al., 1989
Comment MSDC-RI MSDC-RI MSDC-RI

References

Go To: Top, Normal alkane RI, non-polar column, temperature ramp, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Sardashti, Valizadeh, et al., 2013
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Borges, Rojas, et al., 2006
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Boti, Yao, et al., 2006
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Chen, Sheu, et al., 2006
Chen, H.-C.; Sheu, M.-J.; Wu, C.-M., Characterization of Volatiles in Guava (Psidium guajava L. cv. Chung-Shan-Yueh-Pa) Fruit from Taiwan, J. Food Drug. Anal., 2006, 14, 4, 398-402. [all data]

Elfami, Komar, et al., 2006
Elfami, R.B.; Komar, R.; Woerdenbag, H.J.; Kayser, P.; Quax, W.J., Essential oil constituents of Piper cubeba from Indonesia, 2006, retrieved from http://dissertations.ub.rug.nl/FILES/facultiew/science/2006/elfahmi/05c5.pdf. [all data]

Figuérédo, Cabassu, et al., 2006
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Filippi, Lanfranchi, et al., 2006
Filippi, J.-J.; Lanfranchi, D.-A.; Prado, S.; Baldovini, N.; Meierhenrich, U.J., Composition, Enantiomeric Distribution, and Antibacterial Activity of the Essential Oil of Achillea ligustica All. from Corsica, J. Agric. Food Chem., 2006, 54, 17, 6308-6313, https://doi.org/10.1021/jf060752y . [all data]

Orav, Raal, et al., 2006
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Notes

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