Propylene Glycol

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Enthalpy of vaporization at standard conditions (nominally 298.15 K, 1 atm.)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.

ΔvapH° (kcal/mol) Method Reference Comment
16.1 ± 0.1GSVerevkin, Emel'yanenko, et al., 2009Based on data from 284. - 331. K.; AC
18.EBChylinski, Fras, et al., 2004Based on data from 293. - 423. K.; AC
15.4 ± 0.05GSVerevkin, 2004Author later recalculated this earlier value in a later paper Verevkin, Emel'yanenko, et al., 2009. The recalculated value was reported to be 68.5±0.5; AC
14.9TGATatavarti, Dollimore, et al., 2002Based on data from 366. - 396. K.; AC
15.2 ± 0.07EBWilding, Wilson, et al., 1991Based on data from 348. - 453. K. See also Verevkin, 2004.; AC
17.0 ± 0.02CKnauth and Sabbah, 1990ALS
17.0N/AKnauth and Sabbah, 1990DRB
15.5N/AGardner and Hussain, 1972DRB
15.5EBThomas and Meatyard, 1966Based on data from 359. - 461. K. See also Verevkin, 2004.; AC

References

Go To: Top, Enthalpy of vaporization at standard conditions (nominally 298.15 K, 1 atm.), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Verevkin, Emel'yanenko, et al., 2009
Verevkin, Sergey P.; Emel'yanenko, Vladimir N.; Nell, Gernot, 1,2-Propanediol. Comprehensive experimental and theoretical study, The Journal of Chemical Thermodynamics, 2009, 41, 10, 1125-1131, https://doi.org/10.1016/j.jct.2009.04.019 . [all data]

Chylinski, Fras, et al., 2004
Chylinski, Krzysztof; Fras, Zbigniew; Malanowski, Stanislaw K., Vapor-Liquid Equilibrium for Propylene Glycol + 2-(2-Hexyloxyethoxy)ethanol and 1-Methyl-2-pyrrolidone + 1-Methoxypropan-2-ol «8224», J. Chem. Eng. Data, 2004, 49, 1, 18-23, https://doi.org/10.1021/je034096z . [all data]

Verevkin, 2004
Verevkin, Sergey P., Determination of vapor pressures and enthalpies of vaporization of 1,2-alkanediols, Fluid Phase Equilibria, 2004, 224, 1, 23-29, https://doi.org/10.1016/j.fluid.2004.05.010 . [all data]

Tatavarti, Dollimore, et al., 2002
Tatavarti, Aditya S.; Dollimore, David; Alexander, Kenneth S., A thermogravimetric analysis of non-polymeric pharmaceutical plasticizers: Kinetic analysis, method validation, and thermal stability evaluation, AAPS PharmSci, 2002, 4, 4, 231-242, https://doi.org/10.1208/ps040445 . [all data]

Wilding, Wilson, et al., 1991
Wilding, W.V.; Wilson, L.C.; Wilson, G.M., Vapor-liquid equilibrium measurements on eight binary mixtures:  DIPPR Projects 805(A)/89 and 805(E)/89, AIChE Data Ser., 1991, 1, 6. [all data]

Knauth and Sabbah, 1990
Knauth, P.; Sabbah, R., Energetics of inter- and intramolecular bonds in alkanediols. IV. The thermochemical study of 1,2-alkanediols at 298.15 K, Thermochim. Acta, 1990, 164, 145-152. [all data]

Gardner and Hussain, 1972
Gardner, P.J.; Hussain, K.S., The standard enthalpies of formation of some aliphatic diols, J. Chem. Thermodyn., 1972, 4, 819-827. [all data]

Thomas and Meatyard, 1966
Thomas, Leo H.; Meatyard, R., Viscosity and molecular association. Part VI. Association of dihydric alcohols and phenols, J. Chem. Soc., A, 1966, 92, https://doi.org/10.1039/j19660000092 . [all data]


Notes

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