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Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase SPB-1CBP-1DB-1Methyl Silicone5 % Phenyl methyl siloxane
Column length (m)
Carrier gas HeN2HeHeHe
Column diameter (mm) 0.750.530.320.20.2
Phase thickness (mum) 1.0 0.250.330.33
Tstart (C)
Tend (C)
Heat rate (K/min)
Initial hold (min)    1.1.
Final hold (min) 12. 5.3.3.
I 1497.1457.1465.1462.01510.0
ReferenceChrist, Noomano, et al., 1988Oyama, Sano, et al., 1987Perrigo, Peel, et al., 1985Newton and Foery, 1984Newton and Foery, 1984
Column type CapillaryPacked
Active phase DB-1SE-30
Column length (m) 15.1.8
Carrier gas HeN2
Substrate  Chromosorb W
Column diameter (mm) 0.25 
Phase thickness (mum) 0.25 
Tstart (C) 120.130.
Tend (C) 280.290.
Heat rate (K/min) 8.8.
Initial hold (min)  2.
Final hold (min) 5.8.
I 1465.1490.
ReferencePerrigo, Ballantyne, et al., 1984Perrigo and Peel, 1981


Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Christ, Noomano, et al., 1988
Christ, D.W.; Noomano, P.; Rosas, M.; Rhone, D., Retention indices by wide-bore capillary gas chromatography with nitrogen-phosphorus detection, J. Anal. Toxicol., 1988, 12, 2, 84-88, https://doi.org/10.1093/jat/12.2.84 . [all data]

Oyama, Sano, et al., 1987
Oyama, N.; Sano, T.; Syoyama, M.; Maeda, K., Studies on systematic analysis of poisonous compounds in forensic chemistry. II. Application of capillary column gas chromatography to substance identification by means of retention indices, Eisei Kagaku, 1987, 33, 5, 342-348, https://doi.org/10.1248/jhs1956.33.342 . [all data]

Perrigo, Peel, et al., 1985
Perrigo, B.J.; Peel, H.W.; Ballantyne, D.J., Use of Dual-Column Fused-Silica Capillary Gas Chromatography in Combination with Detector Response Factors for Analytical Toxicology., J. Chromatogr., 1985, 341, 81-88, https://doi.org/10.1016/S0378-4347(00)84011-6 . [all data]

Newton and Foery, 1984
Newton, B.; Foery, R.F., Retention indices and dual capillary gas chromatography for rapid identification of sedative hypnotic drugs in emergency toxicology, J. Anal. Toxicol., 1984, 8, 3, 129-134, https://doi.org/10.1093/jat/8.3.129 . [all data]

Perrigo, Ballantyne, et al., 1984
Perrigo, B.J.; Ballantyne, D.J.; Peel, H.W., Condierations in developing a data base for drugs on a DBI capillary column, J. Can. Soc. Forensic Sci., 1984, 17, 2, 41-49, https://doi.org/10.1080/00085030.1984.10757360 . [all data]

Perrigo and Peel, 1981
Perrigo, B.J.; Peel, H.W., The use of retention indices and temperature-programmed gas chromatography in analytical toxicology, J. Chromatogr. Sci., 1981, 19, 5, 219-226, https://doi.org/10.1093/chromsci/19.5.219 . [all data]


Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, References