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Morphine


Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase VF-5MSSPB-1DB-1Methyl Silicone5 % Phenyl methyl siloxane
Column length (m) 30.30.15.12.12.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.750.320.20.2
Phase thickness (mum) 0.251.00.250.330.33
Tstart (C) 60.160.120.50.50.
Tend (C) 270.280.280.300.300.
Heat rate (K/min)  10.8.20.20.
Initial hold (min)    1.1.
Final hold (min)  12.5.3.3.
I 2535.32455.2406.2397.52479.0
ReferenceTretyakov, 2014Christ, Noomano, et al., 1988Perrigo, Peel, et al., 1985Newton and Foery, 1984Newton and Foery, 1984
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryPacked
Active phase DB-1SE-30
Column length (m) 15.1.8
Carrier gas HeN2
Substrate  Chromosorb W
Column diameter (mm) 0.25 
Phase thickness (mum) 0.25 
Tstart (C) 120.130.
Tend (C) 280.290.
Heat rate (K/min) 8.8.
Initial hold (min)  2.
Final hold (min) 5.8.
I 2406.2425.
ReferencePerrigo, Ballantyne, et al., 1984Perrigo and Peel, 1981
Comment MSDC-RI MSDC-RI

References

Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Tretyakov, 2014
Tretyakov, K.V., Retention Data. NIST Mass Spectrometry Data Center., NIST Mass Spectrometry Data Center, 2014. [all data]

Christ, Noomano, et al., 1988
Christ, D.W.; Noomano, P.; Rosas, M.; Rhone, D., Retention indices by wide-bore capillary gas chromatography with nitrogen-phosphorus detection, J. Anal. Toxicol., 1988, 12, 2, 84-88, https://doi.org/10.1093/jat/12.2.84 . [all data]

Perrigo, Peel, et al., 1985
Perrigo, B.J.; Peel, H.W.; Ballantyne, D.J., Use of Dual-Column Fused-Silica Capillary Gas Chromatography in Combination with Detector Response Factors for Analytical Toxicology., J. Chromatogr., 1985, 341, 81-88, https://doi.org/10.1016/S0378-4347(00)84011-6 . [all data]

Newton and Foery, 1984
Newton, B.; Foery, R.F., Retention indices and dual capillary gas chromatography for rapid identification of sedative hypnotic drugs in emergency toxicology, J. Anal. Toxicol., 1984, 8, 3, 129-134, https://doi.org/10.1093/jat/8.3.129 . [all data]

Perrigo, Ballantyne, et al., 1984
Perrigo, B.J.; Ballantyne, D.J.; Peel, H.W., Condierations in developing a data base for drugs on a DBI capillary column, J. Can. Soc. Forensic Sci., 1984, 17, 2, 41-49, https://doi.org/10.1080/00085030.1984.10757360 . [all data]

Perrigo and Peel, 1981
Perrigo, B.J.; Peel, H.W., The use of retention indices and temperature-programmed gas chromatography in analytical toxicology, J. Chromatogr. Sci., 1981, 19, 5, 219-226, https://doi.org/10.1093/chromsci/19.5.219 . [all data]


Notes

Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, References