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Morphine


Normal alkane RI, non-polar column, temperature ramp

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type PackedPackedCapillaryCapillaryCapillary
Active phase Polydimethyl siloxaneSE-30Polymethylsiloxane, (PMS-20000)OV-1BP-1
Column length (m) 2.2.12. 12.
Carrier gas NitrogenNitrogenHe He
Substrate  Chromosorb G AW DMCS (80-100 mesh)   
Column diameter (mm)   0.20 0.22
Phase thickness (mum)   0.33 0.25
Tstart (C) 100.100.160.200.120.
Tend (C) 300.300.300.280.280.
Heat rate (K/min)   10.16.8.
Initial hold (min)      
Final hold (min)      
I 2454.2454.2445.2455.2406.
ReferenceMHA, 9999MHA, 9999Gambaro, Saligari, et al., 1997Schutz and Wollrab A., 1988Stowell and Wilson, 1985
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryPackedPackedPackedPacked
Active phase BP-1OV-1SE-30SE-30SE-30
Column length (m) 12.2.2.2.2.
Carrier gas He  NitrogenNitrogen
Substrate  Gas Chrom PGas Chrom PChromosorb W AW DMS (80-100 mesh)Chromosorb W AW DMS (80-100 mesh)
Column diameter (mm) 0.22    
Phase thickness (mum) 0.25    
Tstart (C) 50.150.150.130.130.
Tend (C) 300.300.300.290.290.
Heat rate (K/min) 20.5.5.8.8.
Initial hold (min)    2.2.
Final hold (min)    8.8.
I 2396.2450.2420.2433.2417.
ReferenceStowell and Wilson, 1985Marozzi, Gambaro, et al., 1982Marozzi, Gambaro, et al., 1982Peel and Perrigo, 1976Peel and Perrigo, 1976
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type PackedPackedPackedPackedPacked
Active phase SE-30SE-30SE-30SE-30SE-30
Column length (m) 2.2.2.2.2.
Carrier gas NitrogenNitrogenNitrogenNitrogenNitrogen
Substrate Chromosorb W AW DMS (80-100 mesh)Chromosorb W AW DMS (80-100 mesh)Chromosorb W AW DMS (80-100 mesh)Chromosorb W AW DMS (80-100 mesh)Chromosorb W AW DMS (80-100 mesh)
Column diameter (mm)      
Phase thickness (mum)      
Tstart (C) 130.130.130.130.130.
Tend (C) 290.290.290.290.290.
Heat rate (K/min) 8.8.8.8.8.
Initial hold (min) 2.2.2.2.2.
Final hold (min) 8.8.8.8.8.
I 2423.2425.2425.2432.2433.
ReferencePeel and Perrigo, 1976Peel and Perrigo, 1976Peel and Perrigo, 1976Peel and Perrigo, 1976Peel and Perrigo, 1976
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type Packed
Active phase SE-30
Column length (m) 2.
Carrier gas N2
Substrate Chromosorb W AW DMS
Column diameter (mm)  
Phase thickness (mum)  
Tstart (C) 130.
Tend (C) 290.
Heat rate (K/min) 8.
Initial hold (min) 2.
Final hold (min) 8.
I 2433.
ReferencePeel and Perrigo, 1975
Comment MSDC-RI

References

Go To: Top, Normal alkane RI, non-polar column, temperature ramp, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

MHA, 9999
MHA, Directorate of ForensicScience., Forensic Toxicology, 9999. [all data]

Gambaro, Saligari, et al., 1997
Gambaro, V.; Saligari, E.; Froldi, R.; Bianchi, L., Analysis of street drugs by means of HRGC, Bollettino Chimico Farmaceutica, 1997, 36, 4, 359-367. [all data]

Schutz and Wollrab A., 1988
Schutz, H.; Wollrab A., The significance of the retention index in toxicologic analysis II, Pharmazie in unzerer Zeit, 1988, 17, 4, 97-101. [all data]

Stowell and Wilson, 1985
Stowell, A.; Wilson, L., Use of retention indices in drug screening by capillary gas chromatography, Rep. # CD 2362, Department of Scientific and Industrial Reseach, Chemistry Division, Lower Hutt, NZ, 1985, 32. [all data]

Marozzi, Gambaro, et al., 1982
Marozzi, E.; Gambaro, V.; Saligari, E.; Mariani, R.; Lodi, F., Use of the retention index in gas chromatographic studies of drugs, J. Anal. Toxicol., 1982, 6, 4, 185-192, https://doi.org/10.1093/jat/6.4.185 . [all data]

Peel and Perrigo, 1976
Peel, H.W.; Perrigo, B., A practical gas chromatographic screening procedure for toxicological analysis, Can. Soc. Forens. Sci. J., 1976, 9, 2, 69-74, https://doi.org/10.1080/00085030.1976.10757247 . [all data]

Peel and Perrigo, 1975
Peel, H.W.; Perrigo, B., A practical gas chromatographic screening procedure for toxicological analysis, Can.Soc.Forens.Sci.J., 1975, 9, 2, 69-74, https://doi.org/10.1080/00085030.1976.10757247 . [all data]


Notes

Go To: Top, Normal alkane RI, non-polar column, temperature ramp, References