Bicyclo[3.1.1]hept-2-ene-2-carboxaldehyde, 6,6-dimethyl-


Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase CP-Sil PONA GBSPB-1HP-5MSHP-5MSHP-5MS
Column length (m) 100.30.30.30.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 140.50.60.60.60.
Tend (C) 230.250.280.280.280.
Heat rate (K/min) 5.5.4.4.4.
Initial hold (min) 10.3.5.5.5.
Final hold (min) 25.15.   
I 1187.1175.1193.1176.1193.
ReferenceCunicao, Lopes, et al., 2007Radulovic, Lazarevic, et al., 2007Radulovic, Lazarevic, et al., 2007Saroglou, Arfan, et al., 2007Saroglou, Marin, et al., 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5MSHP-5MSBP-1BP-1Mega 5MS
Column length (m) 30.30.50.50.60.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.220.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.80.60.60.60.
Tend (C) 280.300.220.220.240.
Heat rate (K/min) 3.4.2.2.3.
Initial hold (min)      
Final hold (min)   20.20. 
I 1193.1203.61165.1169.1193.
ReferenceVagionas, Ngassapa, et al., 2007Zeng, Zhao, et al., 2007Boti, Bighelli, et al., 2006Bousmaha, Boti, et al., 2006Condurso, Verzera, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase BP-1SPB-1DB-1SPB-1HP-5MS
Column length (m) 50.30.30.30.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.220.250.250.20.25
Phase thickness (μm) 0.250.250.250.20.25
Tstart (C) 60.50.50.70.60.
Tend (C) 220.250.265.220.280.
Heat rate (K/min) 2.5.2.53.4.
Initial hold (min)  3.  5.
Final hold (min) 20.15. 15. 
I 1170.1176.1157.1165.1192.
ReferenceGonny, Cavaleiro, et al., 2006Radulovic, Lazarevic, et al., 2006Ramezani, Behravan, et al., 2006Salgueiro L.R., Pinto E., et al., 2006Saroglou, Dorizas, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase RTX-1DB-1DB-1DB-5DB-1
Column length (m) 60.30.30.30.30.
Carrier gas  N2 HeN2
Substrate      
Column diameter (mm) 0.220.320.320.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.50.50.40.50.
Tend (C) 220.260.250.260.200.
Heat rate (K/min) 2.2.2.2.5.
Initial hold (min)  3.8.5. 
Final hold (min) 20.5. 20. 
I 1172.1168.1172.1193.1179.
ReferenceCozzani, Muselli, et al., 2005Dob, Berramdane, et al., 2005Dob, Dahmane, et al., 2005Senatore, Napolitano, et al., 2005Tchoumbougnang, Zollo, et al., 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase SE-54SPB-1SPB-1BP-1HP-5MS
Column length (m) 30.30.30.50.30.
Carrier gas HeHeHe He
Substrate      
Column diameter (mm) 0.250.250.20.220.25
Phase thickness (μm) 0.250.250.20.250.25
Tstart (C) 60.70.70.60.60.
Tend (C) 260.220.220.220.280.
Heat rate (K/min) 2.3.3.2.4.
Initial hold (min) 5.   5.
Final hold (min)  15.15.20. 
I 1188.1165.1165.1170.1193.
ReferenceAlma, Nitz, et al., 2004Antunes, Sevinate-Pinto, et al., 2004Cavaleiro, Salgueiro, et al., 2004Gonny, Bradesi, et al., 2004Grujic-Jovanovic, Skaltsa, et al., 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5HP-5MSHP-5MSHP-5MSOV-1
Column length (m) 30.30.30.30.25.
Carrier gas HeHeHeHeH2
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm)  0.250.250.250.3
Tstart (C) 60.60.50.50.50.
Tend (C) 260.280.300.200.200.
Heat rate (K/min) 3.4.5.6.3.
Initial hold (min)  5.5.1.51.
Final hold (min)    5.20.
I 1193.1189.1202.1205.1165.
ReferenceJavidnia, Miri, et al., 2004Karioti, Hadjipavlou-Litina, et al., 2004Mumm, Tiemann, et al., 2004Weissbecker, Holighaus, et al., 2004Bicchi, Rubiolo, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase RTX-1HP-5HP-5HP-5HP-5
Column length (m) 60.30.30.30.30.
Carrier gas HeN2HeHeHe
Substrate      
Column diameter (mm) 0.220.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.60.60.60.60.
Tend (C) 230.220.240.280.280.
Heat rate (K/min) 2.5.3.3.4.
Initial hold (min)  10.  5.
Final hold (min) 45.    
I 1170.1196.1194.1193.1193.
ReferenceCavalli, Tomi, et al., 2003Emilio Tomei, Manganelli, et al., 2003Macchioni, Cioni, et al., 2003Ngassapa, Runyoro, et al., 2003Skaltsa, Demetzos, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5HP-5HP-5MSHP-5MSCP Sil 5 CB
Column length (m) 30.30.30.30.25.
Carrier gas HeHeHe N2
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.60.60.50.60.
Tend (C) 280.280.300.280.280.
Heat rate (K/min) 3.3.3.3.4.
Initial hold (min)    5.6.
Final hold (min)      
I 1196.1196.1196.1193.1164.
ReferenceTsiri, Kretsi, et al., 2003Tsiri, Kretsi, et al., 2003Couladis, Chinou, et al., 2002Demetzos, Angelopoulou, et al., 2002Pino, Marbot, et al., 2002
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5HP-5HP-5MSHP-5MSHP-5
Column length (m) 30.30.30.30.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.60.60.60.50.
Tend (C) 280.380.280.280.280.
Heat rate (K/min) 3.3.3.4.4.
Initial hold (min) 5. 5.5.5.
Final hold (min)      
I 1193.1193.1193.1193.1191.
ReferenceAligiannis, Kalpoutzakis, et al., 2001Couladis, Tsortanidou, et al., 2001Giamakis, Kretsi, et al., 2001Skaltsa, Mavrommati, et al., 2001Skaltsa, Lazari, et al., 2000
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillary
Active phase DB-1HP-1OV-1BP-1
Column length (m) 30.60.25.50.
Carrier gas  He He
Substrate     
Column diameter (mm) 0.250.250.250.22
Phase thickness (μm) 0.250.250.30.25
Tstart (C) 50.50.50.60.
Tend (C) 220.250.200.230.
Heat rate (K/min) 3.2.53.2.
Initial hold (min) 3.5.1. 
Final hold (min)   20.35.
I 1166.1176.1165.1168.
ReferenceMuselli, Hoi, et al., 1999Stashenko, Cervantes, et al., 1999Bicchi, Rubiolo, et al., 1998Mariotti, Tomi, et al., 1997
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI

References

Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

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Ngassapa, Runyoro, et al., 2003
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Skaltsa, Demetzos, et al., 2003
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Tsiri, Kretsi, et al., 2003
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Couladis, Chinou, et al., 2002
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Demetzos, Angelopoulou, et al., 2002
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Pino, Marbot, et al., 2002
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Aligiannis, Kalpoutzakis, et al., 2001
Aligiannis, N.; Kalpoutzakis, E.; Chinou, I.B.; Mitaku, S.; Gikas, E.; Tsarbopoulos, A., Composition and antimicrobial activity of the essential oils of five taxa of Sideritis from Greece, J. Agric. Food Chem., 2001, 49, 2, 811-815, https://doi.org/10.1021/jf001018w . [all data]

Couladis, Tsortanidou, et al., 2001
Couladis, M.; Tsortanidou, V.; Francisco-Ortega, J.; Santos-Guerra, A.; Harvala, C., Composition of the essential oils of Argyranthemum species growing in the Canary Islands, Flavour Fragr. J., 2001, 16, 2, 103-106, https://doi.org/10.1002/ffj.954 . [all data]

Giamakis, Kretsi, et al., 2001
Giamakis, A.; Kretsi, O.; Chinou, I.; Spyropoulos, C.G., Eucalyptus camaldulensis: volatiles from immature flowers and high production of 1,8-cineole and β-pinene by in vitro cultures, Phytochemistry, 2001, 58, 2, 351-355, https://doi.org/10.1016/S0031-9422(01)00193-5 . [all data]

Skaltsa, Mavrommati, et al., 2001
Skaltsa, H.D.; Mavrommati, A.; Constantinidis, T., A chemotaxonomic investigation of volatile constituents in Stachys subsect. Swainsonianeae (Labiatae), Phytochemistry, 2001, 57, 2, 235-244, https://doi.org/10.1016/S0031-9422(01)00003-6 . [all data]

Skaltsa, Lazari, et al., 2000
Skaltsa, H.D.; Lazari, D.M.; Loukis, A.E.; Constantinidis, T., Essential oil analysis of Nepeta argolica Bory Chaub. subsp. argolica (Lamiaceae) growing wild in Greece, Flavour Fragr. J., 2000, 15, 2, 96-99, https://doi.org/10.1002/(SICI)1099-1026(200003/04)15:2<96::AID-FFJ873>3.0.CO;2-F . [all data]

Muselli, Hoi, et al., 1999
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Notes

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