Bicyclo[3.1.1]hept-2-ene-2-carboxaldehyde, 6,6-dimethyl-
- Formula: C10H14O
- Molecular weight: 150.2176
- IUPAC Standard InChIKey: KMRMUZKLFIEVAO-UHFFFAOYSA-N
- CAS Registry Number: 564-94-3
- Chemical structure:
This structure is also available as a 2d Mol file - Species with the same structure:
- Stereoisomers:
- Other names: 2-Norpinene-2-carboxaldehyde, 6,6-dimethyl-; Myrtenal; Benihinal; 6,6-Dimethylbicyclo(3.1.1)hept-2-ene-2-carboxaldehyde; 2-Formyl-6,6-dimethylbicyclo(3.1.1)hept-2-ene; 6,6-Dimethyl-bicyclo[3,1,1]hept-2-ene-2-carboxaldehyde; 6,6-Dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde; (-)-Myrtenal; (+)-myrtenal; 6,6-dimethyl-bicyclo[3.1.1]hept-2-ene-2-carboxaldehyde (myrtenal); cis-Myrtenal; pin-2-ene-1-carbaldehyde
- Information on this page:
- Other data available:
- Options:
Kovats' RI, non-polar column, temperature ramp
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | DB-5MS | DB-1 | HP-5 | BP-1 | DB-5 |
Column length (m) | 30. | 25. | 25. | 30. | 30. |
Carrier gas | He | He | N2 | He | |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.2 | 0.2 | 0.32 | 0.26 |
Phase thickness (μm) | 0.25 | 0.33 | 0.25 | 0.25 | |
Tstart (C) | 60. | 60. | 60. | 60. | 60. |
Tend (C) | 180. | 220. | 240. | 220. | 246. |
Heat rate (K/min) | 3. | 3. | 3. | 5. | 3. |
Initial hold (min) | 3. | ||||
Final hold (min) | 15. | 3. | |||
I | 1195. | 1188. | 1196. | 1168. | 1196. |
Reference | Angioni, Barra, et al., 2006 | Mevy, Bessiere, et al., 2006 | Oliveira, Leitao, et al., 2006 | Srivastava, Srivastava, et al., 2006 | Adams, Morris, et al., 2005 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | HP-5MS | DB-5MS | SPB-1 | CP Sil 8 CB | DB-5 |
Column length (m) | 30. | 30. | 30. | 30. | 25. |
Carrier gas | He | He | He | H2 | He |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.32 | 0.25 | 0.25 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | |
Tstart (C) | 50. | 60. | 50. | 50. | 40. |
Tend (C) | 250. | 240. | 250. | 220. | 280. |
Heat rate (K/min) | 3. | 3. | 2. | 3. | 3. |
Initial hold (min) | 10. | 2. | 2. | 5. | |
Final hold (min) | 5. | 5. | 5. | ||
I | 1197. | 1196. | 1173. | 1181. | 1192. |
Reference | Asuming, Beauchamp, et al., 2005 | Maia, Andrade, et al., 2005 | Behera, Nagarajan, et al., 2004 | Schwob, Bessiere, et al., 2004 | Amparo Blázquez, Pérez, et al., 2003 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | DB-5 | HP-5MS | CP Sil 5 CB | BP-1 | HP-5MS |
Column length (m) | 50. | 30. | 25. | 25. | 30. |
Carrier gas | He | He | He | N2 | He |
Substrate | |||||
Column diameter (mm) | 0.32 | 0.25 | 0.25 | 0.55 | 0.25 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | |
Tstart (C) | 50. | 60. | 50. | 60. | 50. |
Tend (C) | 280. | 280. | 230. | 220. | 250. |
Heat rate (K/min) | 5. | 3. | 3. | 5. | 3. |
Initial hold (min) | 2. | ||||
Final hold (min) | 10. | 15. | |||
I | 1215. | 1176. | 1173. | 1173. | 1194. |
Reference | Baranauskiene, Venskutonis, et al., 2003 | Gkinis, Tzakou, et al., 2003 | Kasali, Adio, et al., 2002 | Raina, Srivastava, et al., 2002 | Salido, Altarejos, et al., 2002 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | BP-1 | SSP-1 | DB-1 | SE-54 | DB-5 |
Column length (m) | 30. | 30. | 50. | 30. | 30. |
Carrier gas | N2 | He | N2 | He | He |
Substrate | |||||
Column diameter (mm) | 0.32 | 0.32 | 0.25 | 0.26 | 0.26 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
Tstart (C) | 60. | 50. | 80. | 60. | 60. |
Tend (C) | 220. | 250. | 225. | 246. | 240. |
Heat rate (K/min) | 5. | 2. | 4. | 3. | 3. |
Initial hold (min) | 2. | ||||
Final hold (min) | 13. | 5. | |||
I | 1169. | 1155. | 1169. | 1191. | 1193. |
Reference | Shawl, Srivastava, et al., 2002 | Nagarajan, Rao, et al., 2001 | Palá-Paúl, Velasco-Negueruela, et al., 2001 | Adams, 2000 | Adams, 2000, 2 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | SE-54 | DB-5 | Methyl Silicone | DB-5 | DB-5 |
Column length (m) | 30. | 30. | 30. | 30. | 30. |
Carrier gas | He | He | He | ||
Substrate | |||||
Column diameter (mm) | 0.26 | 0.26 | 0.32 | 0.25 | |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | |
Tstart (C) | 60. | 60. | 60. | 40. | 40. |
Tend (C) | 246. | 246. | 250. | 250. | 210. |
Heat rate (K/min) | 3. | 3. | 2. | 2. | 2. |
Initial hold (min) | 2. | 5. | 2. | ||
Final hold (min) | 5. | 20. | 120. | ||
I | 1193. | 1193. | 1169. | 1151. | 1189. |
Reference | Adams, 2000, 3 | Adams, 2000, 4 | Adegoke, Rao, et al., 1998 | Senatore, Urrunaga Soria, et al., 1997 | Loayza, Abujder, et al., 1995 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
References
Go To: Top, Kovats' RI, non-polar column, temperature ramp, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
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Notes
Go To: Top, Kovats' RI, non-polar column, temperature ramp, References
- Symbols used in this document:
Tend Final temperature Tstart Initial temperature - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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