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2-Butene, 2,3-dimethyl-

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
GT - Glushko Thermocenter, Russian Academy of Sciences, Moscow

Quantity Value Units Method Reference Comment
Deltafgas-70.3 ± 1.5kJ/molEqkWiberg and Hao, 1991Heat of hydration; ALS
Deltafgas-68.4 ± 1.5kJ/molEqkRodgers and Wu, 1971Heat of isomerization; ALS

Constant pressure heat capacity of gas

Cp,gas (J/mol*K) Temperature (K) Reference Comment
135.31 ± 0.27334.20Scott D.W., 1955GT
142.00 ± 0.28355.25
154.64 ± 0.31393.20
167.65 ± 0.34433.20
180.33 ± 0.36473.20

Constant pressure heat capacity of gas

Cp,gas (J/mol*K) Temperature (K) Reference Comment
115.94273.15Scott D.W., 1955Recommended results of statistical thermodynamics calculation are in good agreement with experimental data.; GT
123.60298.15
124.18300.
156.82400.
188.45500.
216.65600.
241.29700.
262.67800.
281.37900.
297.651000.
311.921100.
324.301200.
335.051300.
344.471400.
352.751500.

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-102.9 ± 1.5kJ/molEqkWiberg and Hao, 1991Heat of hydration; ALS
Quantity Value Units Method Reference Comment
liquid270.20J/mol*KN/AScott, Finke, et al., 1955DH
liquid272.4J/mol*KN/AParks, Todd, et al., 1936Extrapolation below 90 K, 58.45 J/mol*K.; DH

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
174.68298.15Scott, Finke, et al., 1955T = 10 to 320 K.; DH
175.73295.5Parks, Todd, et al., 1936T = 83 to 296 K. Value is unsmoothed experimental datum.; DH

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wiberg and Hao, 1991
Wiberg, K.B.; Hao, S., Enthalpies of hydration of alkenes. 4. Formation of acyclic tert-alcohols, J. Org. Chem., 1991, 56, 5108-5110. [all data]

Rodgers and Wu, 1971
Rodgers, A.S.; Wu, M.-C.R., Thermochemistry of the gas-phase iodine catalyzed isomerization: 2,3-dimethyl-1-butene = 2,3-dimethyl-2-butene, J. Chem. Thermodyn., 1971, 3, 591-597. [all data]

Scott D.W., 1955
Scott D.W., 2,3-Dimethyl-2-butene: thermodynamic properties in the solid, liquid and vapor states, J. Am. Chem. Soc., 1955, 77, 4993-4998. [all data]

Scott, Finke, et al., 1955
Scott, D.W.; Finke, H.L.; McCullough, J.P.; Gross, M.E.; Messerly, J.F.; Pennington, R.E.; Waddington, G., 2,3-Dimethyl-2-butene: Thermodynamic properties in the solid, liquid and vapor states, J. Am. Chem. Soc., 1955, 77, 4993-4998. [all data]

Parks, Todd, et al., 1936
Parks, G.S.; Todd, S.S.; Shomate, C.H., Thermal data on organic compounds. XVII. Some heat capacity, entropy and free energy data for five higher olefins, J. Am. Chem. Soc., 1936, 58, 2505-2508. [all data]


Notes

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