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CS2+


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

CS2+ + Carbon disulfide = (CS2+ bullet Carbon disulfide)

By formula: CS2+ + CS2 = (CS2+ bullet CS2)

Quantity Value Units Method Reference Comment
Deltar24.9kcal/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase
Deltar21.9kcal/molPHPMSMeot-Ner (Mautner) and Field, 1977gas phase
Deltar17.5kcal/molPIOno, Linn, et al., 1980gas phase
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase
Deltar21.9cal/mol*KPHPMSMeot-Ner (Mautner) and Field, 1977gas phase

(CS2+ bullet 2Carbon disulfide) + Carbon disulfide = (CS2+ bullet 3Carbon disulfide)

By formula: (CS2+ bullet 2CS2) + CS2 = (CS2+ bullet 3CS2)

Quantity Value Units Method Reference Comment
Deltar4.9kcal/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; Entropy change calculated or estimated
Deltar3.9kcal/molPIOno, Linn, et al., 1980gas phase
Quantity Value Units Method Reference Comment
Deltar17.cal/mol*KN/AHiraoka, Fujimaki, et al., 1994gas phase; Entropy change calculated or estimated

(CS2+ bullet Carbon disulfide) + Carbon disulfide = (CS2+ bullet 2Carbon disulfide)

By formula: (CS2+ bullet CS2) + CS2 = (CS2+ bullet 2CS2)

Quantity Value Units Method Reference Comment
Deltar6.5kcal/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase
Deltar4.4kcal/molPIOno, Linn, et al., 1980gas phase
Quantity Value Units Method Reference Comment
Deltar21.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase

(CS2+ bullet 3Carbon disulfide) + Carbon disulfide = (CS2+ bullet 4Carbon disulfide)

By formula: (CS2+ bullet 3CS2) + CS2 = (CS2+ bullet 4CS2)

Quantity Value Units Method Reference Comment
Deltar2.6kcal/molPIOno, Linn, et al., 1980gas phase

CS2+ + Carbonyl sulfide = (CS2+ bullet Carbonyl sulfide)

By formula: CS2+ + COS = (CS2+ bullet COS)

Quantity Value Units Method Reference Comment
Deltar5.8kcal/molPIOno, Osuch, et al., 1981gas phase

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hiraoka, Fujimaki, et al., 1994
Hiraoka, K.; Fujimaki, S.; Aruga, K.; Yamabe, S., Frontier-Controlled Structures of the Gas-Phase A+-(CS2)n Clusters ,A+- = S2+, CS2+, S2-, and CS2-, J. Phys. Chem., 1994, 98, 7, 1802, https://doi.org/10.1021/j100058a014 . [all data]

Meot-Ner (Mautner) and Field, 1977
Meot-Ner (Mautner), M.; Field, F.H., Proton Affinity and Ion - Molecule Clustering in CO2 and CS2. Applications in Martian Ionospheric Chemistry, J. Chem. Phys., 1977, 66, 10, 4527, https://doi.org/10.1063/1.433706 . [all data]

Ono, Linn, et al., 1980
Ono, Y.; Linn, S.H.; Prest, H.F.; Gress, M.E.; Ng, C.Y., Molecular beam photoionization study of carbon disulfide, carbon disulfide dimer and clusters, J. Chem. Phys., 1980, 73, 2523. [all data]

Ono, Osuch, et al., 1981
Ono, Y.; Osuch, E.A.; Ng, C.Y., Molecular beam photoionization study of OCS, (OCS)2, (OCS)3, and OCS.CS2, J. Chem. Phys., 1981, 74, 1645. [all data]


Notes

Go To: Top, Reaction thermochemistry data, References