D-Fructose, 1,3,4,5,6-pentakis-O-(trimethylsilyl)-, O-methyloxime
- Formula: C22H55NO6Si5
- Molecular weight: 570.1027
- IUPAC Standard InChI: InChI=1S/C22H55NO6Si5/c1-24-23-19(17-25-30(2,3)4)21(28-33(11,12)13)22(29-34(14,15)16)20(27-32(8,9)10)18-26-31(5,6)7/h20-22H,17-18H2,1-16H3
- IUPAC Standard InChIKey: ACDMQGXCXUQPRR-UHFFFAOYSA-N
- CAS Registry Number: 56196-14-6
- Chemical structure:
This structure is also available as a 2d Mol file - Species with the same structure:
- L-(-)-Sorbose, pentakis(trimethylsilyl) ether, methyloxime (anti)
- L-(-)-Sorbose, pentakis(trimethylsilyl) ether, methyloxime (syn)
- D-Psicose, pentakis(trimethylsilyl) ether, methyloxime (syn)
- D-Psicose, pentakis(trimethylsilyl) ether, methyloxime (anti)
- D-(-)-Tagatose, pentakis(trimethylsilyl) ether, methyloxime (anti)
- D-(-)-Tagatose, pentakis(trimethylsilyl) ether, methyloxime (syn)
- D-(-)-Fructose, pentakis(trimethylsilyl) ether, methyloxime (anti)
- D-(-)-Fructose, pentakis(trimethylsilyl) ether, methyloxime (syn)
- Stereoisomers:
- Other names: d-Glucose,o-methyloxime,pentakis(trimethylsilyl) derivative; Fructose, MEOX-5TMS
- Information on this page:
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Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Normal alkane RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | RTx-5 Sil MS | 1875. | Birkemeier and Kopka, 2007 | 30. m/0.25 mm/0.25 μm, Helium; Program: 70 0C (1 min) 1 0C/min -> 76 0C 6.09 0C/min -> 350 0C (1 min) -> 330 0C (10 min) |
References
Go To: Top, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Birkemeier and Kopka, 2007
Birkemeier, C.; Kopka, J.,
Design of metabolite recovery by variations of the metabolite profiling protocol
in Concepts in Plant Metabolomics, Nikolau, B.J.; Wurtele, E.S., ed(s)., Springer, Dordrecht, Netheralnds, 2007, 45-69. [all data]
Notes
Go To: Top, Gas Chromatography, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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