Diacetylmorphine
- Formula: C21H23NO5
- Molecular weight: 369.4110
- IUPAC Standard InChI: InChI=1S/C21H23NO5/c1-11(23)25-16-6-4-13-10-15-14-5-7-17(26-12(2)24)20-21(14,8-9-22(15)3)18(13)19(16)27-20/h4-7,14-15,17,20H,8-10H2,1-3H3
- IUPAC Standard InChIKey: GVGLGOZIDCSQPN-UHFFFAOYSA-N
- CAS Registry Number: 561-27-3
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Morphinan-3,6-diol, 7,8-didehydro-4,5-epoxy-17-methyl- (5α,6α)-, diacetate (ester); Morphinan-3,6α-diol, 7,8-didehydro-4,5α-epoxy-17-methyl-, diacetate (ester); Acetomorfin; Acetomorphin; Diamorphine; Diaphorm; Eclorion; Eroina; Herolan; Morphacetin; Preza; Morphinan-3,6-diol, 7,8-didehydro-4,5-epoxy-17-methyl- (5α,6α)-, diacetate; Morphinan-3,6-α-diol, 7,8-didehydro-4,5-α-epoxy-17-methyl-, diacetate; Acetomorfine; Acetomorphine; Aspron; BOY; Diacephin; Diacetylmorfin; Diamorfina; Diasetielmorfien; Diasetilmorfin; Diasetylmorfiimi; Diazetylmorphine; 7,8-Dihydro-4,5-α-epoxy-17-methylmorphinan-3,6-α-diol diacetate; Dooje; Eroin; Hairy; Harry; Heroien; Heroiin; Horse; Iroini; Joy powder; Morphine diacetate; SCOT; White stuff; 3,6-Diacetylmorphine; (5α,6α)-7,8-Didehydro-4,5-epoxy-17-methylmorphinan-3,6-diol diacetate (ester); China white; Heroin; Morphine, diacetyl-; 3,6-O-Diacetylmorphine; "H"; Ieroin; Herperal; Diacetylmorphine, HFB; O,O'-diacetylmorphine; Diacetylmorphine (heroin)
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Van Den Dool and Kratz RI, non-polar column, temperature ramp
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
| Column type | Capillary | Capillary | Capillary | Capillary | Packed |
|---|---|---|---|---|---|
| Active phase | DB-1 | Methyl Silicone | DB-1 | SE-30 | SE-30 |
| Column length (m) | 15. | 12. | 15. | 15. | 1.8 |
| Carrier gas | He | He | He | He | N2 |
| Substrate | Chromosorb W | ||||
| Column diameter (mm) | 0.32 | 0.2 | 0.25 | 0.25 | |
| Phase thickness (μm) | 0.25 | 0.33 | 0.25 | 0.25 | |
| Tstart (C) | 120. | 50. | 120. | 100. | 130. |
| Tend (C) | 280. | 300. | 280. | 295. | 290. |
| Heat rate (K/min) | 8. | 20. | 8. | 5. | 8. |
| Initial hold (min) | 1. | 2. | |||
| Final hold (min) | 5. | 3. | 5. | 8. | |
| I | 2602. | 2605.0 | 2602. | 2581. | 2620. |
| Reference | Perrigo, Peel, et al., 1985 | Newton and Foery, 1984 | Perrigo, Ballantyne, et al., 1984 | Anderson and Stafford, 1983 | Perrigo and Peel, 1981 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
References
Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Perrigo, Peel, et al., 1985
Perrigo, B.J.; Peel, H.W.; Ballantyne, D.J.,
Use of Dual-Column Fused-Silica Capillary Gas Chromatography in Combination with Detector Response Factors for Analytical Toxicology.,
J. Chromatogr., 1985, 341, 81-88, https://doi.org/10.1016/S0378-4347(00)84011-6
. [all data]
Newton and Foery, 1984
Newton, B.; Foery, R.F.,
Retention indices and dual capillary gas chromatography for rapid identification of sedative hypnotic drugs in emergency toxicology,
J. Anal. Toxicol., 1984, 8, 3, 129-134, https://doi.org/10.1093/jat/8.3.129
. [all data]
Perrigo, Ballantyne, et al., 1984
Perrigo, B.J.; Ballantyne, D.J.; Peel, H.W.,
Condierations in developing a data base for drugs on a DBI capillary column,
J. Can. Soc. Forensic Sci., 1984, 17, 2, 41-49, https://doi.org/10.1080/00085030.1984.10757360
. [all data]
Anderson and Stafford, 1983
Anderson, W.H.; Stafford, D.T.,
Applications of capillary gas chromatography in routine toxicological analyses,
J. Hi. Res. Chromatogr. Chromatogr. Comm., 1983, 6, 5, 247-254, https://doi.org/10.1002/jhrc.1240060506
. [all data]
Perrigo and Peel, 1981
Perrigo, B.J.; Peel, H.W.,
The use of retention indices and temperature-programmed gas chromatography in analytical toxicology,
J. Chromatogr. Sci., 1981, 19, 5, 219-226, https://doi.org/10.1093/chromsci/19.5.219
. [all data]
Notes
Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, References
- Symbols used in this document:
Tend Final temperature Tstart Initial temperature - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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